Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

Uranium

Uranium is a silver-white, malleable, ductile, lustrous solid.

CAS 7440-61-1 U 238.029 g/mol Danger

01 · Identification

What Uranium is

Uranium is a silver-white, malleable, ductile, lustrous solid. Its molecular formula is U and its molecular weight is 238.029 g/mol. It boils at 4131 °C, melts at 1135 °C.

Under the GHS it carries the signal word Danger. It is classed as flammable agents - 3rd degree.

02 · Identifiers

Uranium identifiers and molecular data

Uranium CAS number and EC number

CAS number7440-61-1
EC number231-170-6
Index number (CLP Annex VI)092-001-00-8

Uranium molecular formula and molecular weight

Molecular formulaU
Molecular weight238.029 g/mol
Chemical class Flammable agents - 3rd degree

03 · GHS classification

Uranium hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

Uranium pictograms and signal word

Signal wordDanger

Uranium hazard class and category

GHS hazard classes Uranium falls into
Hazard class Category From code Pictogram
Acute toxicity - oral GHS chapter 3.1 Category 1 or 2 H300 GHS06
Acute toxicity - inhalation GHS chapter 3.1 Category 1 or 2 H330 GHS06
Specific target organ toxicity - repeated exposure GHS chapter 3.9 Category 2 H373 GHS08
Hazardous to the aquatic environment - chronic GHS chapter 4.1 Category 4 H413

Where two values are shown with “or”, the hazard statement is shared by more than one category or by more than one class, and the code alone does not say which. H272, for example, belongs to oxidising liquids and to oxidising solids — the physical state decides. The binding answer for a specific entry is in the CLP Annex VI table itself.

Uranium hazard statements (H-codes)

Hazard statements assigned to Uranium
CodeHazard statement
H330 Fatal if inhaled.
H300 Fatal if swallowed.
H373 May cause damage to organs <or state all organs affected, if known> through prolonged or repeated exposure <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
H413 May cause long lasting harmful effects to aquatic life.

This page lists only the codes assigned to Uranium. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for Uranium

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of Uranium issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

04 · Precautionary statements

Uranium precautionary statements

CLP Annex VI assigns 10 precautionary statements to Uranium. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Disposal

What has to happen to the contents and the empty container.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

Uranium name in 23 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български уран
Spanish español Uranio
Czech čeština uran
Danish dansk uran
German Deutsch Uran
Estonian eesti uraan
Greek ελληνικά ουράνιο
English English uranium
French français uranium
Croatian hrvatski uranij
Italian italiano uranio
Latvian latviešu urāns
Lithuanian lietuvių uranas
Hungarian magyar urán
Maltese Malti uranju
Dutch Nederlands uraan
Polish polski uran
Portuguese português urânio
Romanian română uraniu
Slovak slovenčina urán
Slovenian slovenščina uran
Finnish suomi uraani
Swedish svenska uran

All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

Uranium GHS label elements

Everything CLP Annex VI fixes for Uranium, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS06 Skull and crossbones pictogramGHS08 Health hazard pictogram

Danger

Uranium

  • Fatal if inhaled.
  • Fatal if swallowed.
  • May cause damage to organs <or state all organs affected, if known> through prolonged or repeated exposure <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
  • May cause long lasting harmful effects to aquatic life.
  • Do not breathe dust/fume/gas/mist/vapours/spray.
  • Do not eat, drink or smoke when using this product.
  • Use only outdoors or in a well-ventilated area.
  • Avoid release to the environment.
  • IF SWALLOWED:
  • IF INHALED:
  • Immediately call a POISON CENTER/doctor/
  • Get medical advice/attention if you feel unwell.
  • Rinse mouth.
  • Dispose of contents/container to

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open Uranium in the GHS label constructor →

07 · Health hazards

Uranium health hazards and exposure limits

Uranium hazard summary

Uranium is a common naturally occurring and radioactive substance. It is a normal part of rocks, soil, air, and water, and it occurs in nature in the form of minerals "" but never as a metal. Uranium metal is silver-colored with a gray surface and is nearly as strong as steel. Natural uranium is a mixture of three types or isotopes called U-234/234U, U-235/235U and U-238/238U. All three are the same chemical, but they have different radioactive properties.Typical concentrations in soil are a few parts per million ppm. Some rocks contain high enough mineral concentrations of uranium to be mined. The rocks are taken to a chemical plant where the uranium is taken out and made into uranium chemicals or metal. The remaining sand is called mill tailings. Tailings are rich in the chemicals and radioactive materials that were not removed, such as radium and thorium.One of the radioactive properties of uranium is half-life, or the time it takes for half of the isotope to give off its radiation and change into another substance. The half-lives are very long around 200,000 years for234U, 700 million years for235U, and 5 billion years for238U. This is why uranium still exists in nature and has not all decayed away.The isotope235U is useful as a fuel in powerplants and weapons. To make fuel, natural uranium is separated into two portions. The fuel portion has more235U than normal and is called enriched uranium. The leftover portion with less235U than normal is called depleted uranium, or DU. Natural, depleted, and enriched uranium are chemically identical. Du is the least radioactive and enriched uranium the most.

Source: Agency for Toxic Substances and Disease Registry (ATSDR)

Uranium carcinogenicity classification

IARC classification Group 1 — Carcinogenic to humans
IARC monographs Volume 78: (2001) Ionizing Radiation, Part 2: Some Internally Deposited Radionuclides

An IARC group and a CLP classification answer different questions. IARC judges whether the evidence for cancer in humans is strong enough; CLP Annex VI is the legally binding EU classification. A substance can carry one and not the other.

Uranium occupational exposure limits

US occupational exposure limits reported for Uranium. PEL is enforceable (OSHA), REL is a recommendation (NIOSH), IDLH is the concentration at which escape becomes impossible without injury.
Limit Value Source
PEL 0.05 [mg/m3], as U (sol. compds), 0.25 mg/m3, as U (insol. compds) Haz-Map, Information on Hazardous Chemicals and Occupational Diseases
PEL 0.25 mg/m³ Occupational Safety and Health Administration (OSHA)
PEL 0.05 mg/m³ Occupational Safety and Health Administration (OSHA)
REL 0.2 mg/m³ Occupational Safety and Health Administration (OSHA)
REL 0.6 mg/m³ Occupational Safety and Health Administration (OSHA)
REL 0.05 mg/m³ Occupational Safety and Health Administration (OSHA)
IDLH 10.0 [mg/m3], as U Haz-Map, Information on Hazardous Chemicals and Occupational Diseases
IDLH 10 mg/cu m; NIOSH considers uranium (insoluble compounds, as U) to be a potential occupational carcinogen. /Uranium (insoluble compounds, as U)/ Hazardous Substances Data Bank (HSDB)
IDLH 10 mg/m³ Occupational Safety and Health Administration (OSHA)

These are United States values. The European Union sets its own indicative and binding limits, and the figure that applies at a given workplace is the one in the local regulation — not the one shown here.

08 · Physical and chemical properties

Uranium properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

Uranium boiling point

Property Value Conditions Source
Boiling point 4131 °C (7467.8 °F) HSDB
3813 °C (6895 °F) NIOSH
4131 °C (7468 °F) OSHA

Uranium melting point

Property Value Conditions Source
Melting point 1135 °C (2075 °F) HSDB
1147 °C (2097 °F) NIOSH

Uranium density

Property Value Conditions Source
Density 19.1 g/cm³ HSDB
19.05 g/cm³ metal NIOSH
19.1 g/cm³ at 25 °C DOE PAC

Uranium solubility

Property Value Conditions Source
Solubility Insol in water, alkalis, alcohol; soluble in acids HSDB
Insoluble NIOSH

Uranium vapor pressure

Property Value Conditions Source
Vapor pressure 0 mmHg approx NIOSH
0 mmHg at 20 °C HSDB

Uranium autoignition temperature

Property Value Conditions Source
Autoignition temperature 20 °C (68 °F) cloud HSDB

Uranium lower explosive limit (LEL)

Property Value Conditions Source
Lower explosive limit (LEL) Minimum explosive concn 60 g/cu m for dust HSDB
A dust cloud of uranium metal dust may ignite explosively at ordinary temperatures. HSDB
Uranium is pyrophoric ... HSDB

Uranium vapor density

Property Value Conditions Source
Vapor density 19.05 (air = 1) metal OSHA

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

09 · Fire and explosion

Uranium fire and explosion behaviour

These are descriptions rather than measured values, so they are kept out of the table above and quoted here with the source that reported them.

Uranium fire potential

A very dangerous fire hazard in the form of a solid or dust when exposed to heat or flame.

Source: Hazardous Substances Data Bank (HSDB)

Solubility

Rapidly soluble in aqueous HCl. Non-oxidizing acids, such as sulfuric, phosphoric and hydrofluoric /acid/, react only very slowly with uranium; nitric acid dissolves massive uranium at a moderate rate.

Source: HSDB

10 · Handling and storage

Uranium storage and handling

Uranium storage conditions

Finely divided uranium metal is highly reactive or pyrophoric, capable of igniting spontaneously. This type of material should be handled and stored in a manner that minimizes fire potential. Typically, machining chips are stored under water or machining oil in open storage containers so that any H2 generated does not accumulate.

Source: Hazardous Substances Data Bank (HSDB)

Uranium incompatible materials

Uranium reacts with incandescence with hot selenium or sulfur (boiling).

Source: Hazardous Substances Data Bank (HSDB)

Planning storage for a mix of chemicals? Check Uranium in the storage compatibility matrix →

11 · Questions

Uranium — frequently asked questions

What is the CAS number of Uranium?

The CAS number of Uranium is 7440-61-1. Its EC number is 231-170-6.

What is the chemical formula of Uranium?

The molecular formula of Uranium is U and its molecular weight is 238.029 g/mol.

What does a Uranium label have to show?

Under CLP Annex VI the label for Uranium carries the pictograms Skull and crossbones and Health hazard and the signal word is Danger.

Is Uranium flammable?

CLP Annex VI assigns Uranium no flammability hazard class. That is not a statement that it cannot burn: the harmonised list only records the hazards that were assessed for it.

Is Uranium a carcinogen?

CLP Annex VI records no harmonised carcinogenicity classification for Uranium. Annex VI is a list of agreed classifications, not a list of substances found safe, so this is an absence of a classification rather than a clean bill of health. IARC places it in Group 1: carcinogenic to humans.

What is the exposure limit for Uranium?

The US occupational exposure limit reported for Uranium is 0.05 [mg/m3], as U (sol. compds), 0.25 mg/m3, as U (insol. compds) (Haz-Map, Information on Hazardous Chemicals and Occupational Diseases). Limits differ by country: the EU sets its own indicative and binding values, and the figure that applies at a given workplace is the one in the local regulation.

What is the boiling point of Uranium?

The boiling point reported for Uranium is 4131 °C (7467.8 °F) (HSDB).

What is the melting point of Uranium?

The melting point reported for Uranium is 1135 °C (2075 °F) (HSDB).

How should Uranium be stored?

Finely divided uranium metal is highly reactive or pyrophoric, capable of igniting spontaneously. This type of material should be handled and stored in a manner that minimizes fire potential. Typically, machining chips are stored under water or machining oil in open storage containers so that any H2 generated does not accumulate. (Hazardous Substances Data Bank (HSDB))

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