Safety data sheet reference · CAS 108-95-2
Phenol SDS
also: phenol MSDS · safety data sheet · C6H5OH · CAS 108-95-2 · EC 203-632-7 · carbolic acid
Official PDF from supplier
This page is a reference, not the legal document.
CAS number
108-95-2
EC number
203-632-7
CLP Annex VI index
604-001-00-2
Molecular formula
C6H6O
Structural formula
C6H5OH
Molar mass
94.11 g/mol
§ 02 · Hazards identification
Phenol harmonised EU classification
CLP Annex VI · Index 604-001-00-2. A supplier SDS may add self-classified hazards — this is the legal minimum.
Precautionary statements
Codes ending in a colon introduce the action that follows — on a label they are printed as combined statements, such as P305+P351+P338.
§ 03 · Composition and identifiers
Phenol molecular structure
Phenol is a molecular compound. The skeletal formula below is drawn from its PubChem SMILES string, and every value in this section is computed from that structure.
2D skeletal formula · C6H5OH
Functional groups
phenol, aromatic ring
Hybridisation
C sp² ×6 · O sp²
Electron count
36 valence e⁻ · 2 lone pairs
Identifiers from PubChem (NIH, public domain). Structure diagram drawn with RDKit from the SMILES string. Geometry and hybridisation are computed from the connection table, not measured.
§ 04 · First-aid measures
Phenol first aid measures
Call your national emergency number first. These are published first-aid measures, not medical advice, and they do not replace emergency services, a poison control centre or the supplier's safety data sheet.
§4–§6 below reproduce the CAMEO Chemicals entry PHENOL, SOLID. CAMEO publishes response data per product entry, so the entry can describe a solution, a refrigerated liquid or a molten form rather than the pure substance in §9 — check it matches what you are handling.
Signs and Symptoms of Acute Phenol Exposure: Signs and symptoms of acute exposure to phenol may be severe, and range from tachycardia (rapid heart rate) and tachypnea (rapid respiratory rate) to hypotension (low blood pressure), weak pulse, cardiac failure, pulmonary edema, and respiratory arrest. Cardiac arrhythmias may be noted. Weakness, headache, dizziness, tinnitus (ringing in the ears), delirium, and shock are common. Seizures may often be followed by coma. Pallor, profuse sweating, dilated pupils, and a profound drop in body temperature may occur. Gastrointestinal effects may include nausea, abdominal pain, bloody vomitus, and bloody diarrhea. Renal insufficiency may lead to hematuria (bloody urine). Liver damage may also occur. Phenol is corrosive to the skin and mucous membranes. Contact may result in severe and painful burns, which promptly become anesthetized (numb) to touch and pain. Ulceration may follow.
Emergency Life-Support Procedures: Acute exposure to phenol may require decontamination and life support for the victims. Emergency personnel should wear protective clothing appropriate to the type and degree of contamination. Air-purifying or supplied-air respiratory equipment should also be worn, as necessary. Rescue vehicles should carry supplies such as plastic sheeting and disposable plastic bags to assist in preventing spread of contamination.
Inhalation Exposure: 1. Move victims to fresh air. Emergency personnel should avoid self-exposure to phenol. 2. Evaluate vital signs including pulse and respiratory rate, and note any trauma. If no pulse is detected, provide CPR. If not breathing, provide artificial respiration. If breathing is labored, administer oxygen or other respiratory support. 3. Obtain authorization and/or further instructions from the local hospital for administration of an antidote or performance of other invasive procedures. 4. Transport to a health care facility.
Dermal/Eye Exposure: 1. Remove victims from exposure. Emergency personnel should avoid self- exposure to phenol. 2. Evaluate vital signs including pulse and respiratory rate, and note any trauma. If no pulse is detected, provide CPR. If not breathing, provide artificial respiration. If breathing is labored, administer oxygen or other respiratory support. 3. Remove contaminated clothing as soon as possible. 4. If eye exposure has occurred, eyes must be flushed with lukewarm water for at least 15 minutes. 5. Remove phenol from skin with undiluted polyethylene glycol 300 or 400, if available. If not available, use water. Follow polyethylene glycol wash with a water wash. 6. Wash exposed skin areas for at least 15 minutes with large amounts of water. 7. Obtain authorization and/or further instructions from the local hospital for administration of an antidote or performance of other invasive procedures. 8. Transport to a health care facility.
Ingestion Exposure: 1. Evaluate vital signs including pulse and respiratory rate, and note any trauma. If no pulse is detected, provide CPR. If not breathing, provide artificial respiration. If breathing is labored, administer oxygen or other respiratory support. 2. Obtain authorization and/or further instructions from the local hospital for administration of an antidote or performance of other invasive procedures. 3. Immediately give the victims water or milk: children up to 1 year old, 125 mL (4 oz or 1/2 cup); children 1 to 12 years old, 200 mL (6 oz or 3/4 cup); adults, 250 mL (8 oz or 1 cup). Water or milk should be given only if victims are conscious and alert. 4. If a dilute (5% or less) solution has been ingested, vomiting may be induced with syrup of Ipecac. DO NOT induce vomiting if concentration is greater than 5% or unknown. If elapsed time since ingestion of phenol is unknown or suspected to be greater than 30 minutes, do not induce vomiting and proceed to Step 5. Ipecac should not be administered to children under 6 months of age.Warning: Ingestion of phenol may result in sudden onset of seizures or loss of consciousness. Syrup of Ipecac should be administered only if victims are alert, have an active gag-reflex, and show no signs of impending seizure or coma. If ANY uncertainty exists, proceed to Step 5.The following dosages of Ipecac are recommended: children up to 1 year old, 10 mL (1/3 oz); children 1 to 12 years old, 15 mL (1/2 oz); adults, 30 mL (1 oz). Ambulate (walk) the victims and give large quantities of water. If vomiting has not occurred after 15 minutes, Ipecac may be readministered. Continue to ambulate and give water to the victims. If vomiting has not occurred within 15 minutes after second administration of Ipecac, administer activated charcoal. 5. Activated charcoal may be administered if victims are conscious and alert. Use 15 to 30 g (1/2 to 1 oz) for children, 50 to 100 g (1-3/4 to 3-1/2 oz) for adults, with 125 to 250 mL (1/2 to 1 cup) of water. 6. Promote excretion by administering a saline cathartic or sorbitol to conscious and alert victims. Children require 15 to 30 g (1/2 to 1 oz) of cathartic; 50 to 100 g (1-3/4 to 3-1/2 oz) is recommended for adults. 7. Transport to a health care facility.
Source: EPA, 1998 — via CAMEO Chemicals (NOAA), public domain.
§ 05 · Fire-fighting measures
Phenol fire fighting measures
ERG 2024 · GUIDE 153 Substances - Toxic and/or Corrosive (Combustible)ERG guidance is written per response guide, not per substance — Guide 153 covers every material assigned to it, so a few sentences reference other UN numbers in the same group.
Fire and explosion hazard
Flammable vapors when heated. Runoff from fire control water may give off poisonous gases and cause pollution. Mixtures of 9-10% phenol in air are explosive. Avoid aluminum chloride/nitrobenzene mixture, peroxodisulfuric acid, peroxomonosulfuric acid and strong oxidizing agents. Decomposes slowly on air contact. Avoid contact with strong oxidizing agents.
Extinguishing media and tactics
Move container from fire area if it can be done without risk; fight fire from maximum distance; dike fire control water for later disposal, do not scatter the material. Small fires: dry chemical, carbon dioxide, water spray or foam (alcohol); large fires: water spray, fog or foam; use water spray to cool containers in fire area.
Source: EPA, 1998 — via CAMEO Chemicals (NOAA), public domain. Entry: PHENOL, SOLID.
§ 06 · Accidental release measures
Phenol spill and leak response
Containment and clean-up
ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Stop leak if you can do it without risk. Prevent entry into waterways, sewers, basements or confined areas. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. DO NOT GET WATER INSIDE CONTAINERS.
Initial isolation and evacuation
IMMEDIATE PRECAUTIONARY MEASUREIsolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids.
SPILLIncrease the immediate precautionary measure distance, in the downwind direction, as necessary.
FIREIf tank, rail tank car or highway tank is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions.
Source: ERG, 2024 — via CAMEO Chemicals (NOAA), public domain. Entry: PHENOL, SOLID.
§ 07 · Handling and storage
Phenol computed storage compatibility
Derived from CLP Annex VI classification and CAMEO reactive-group data — not copied from a PDF.
↔ Keep separate
Full interactive verdict — reactions, gas release on contact, ADR forms →
§ 08 · Exposure controls
Phenol exposure limits (IDLH)
IDLH
Immediately Dangerous to Life or Health
250 ppm
IDLH from the NIOSH Pocket Guide to Chemical Hazards (CDC, U.S. public domain), via CAMEO Chemicals. Occupational exposure limits — OSHA PEL, NIOSH REL and EU IOELV — are not published on this page yet.
§ 09 · Physical and chemical properties
Phenol physical properties
Fire-relevant values first — flash point and explosion limits decide the storage and ventilation regime.
Flash point
79.4 °C
Explosion limits
1.7 – 8.6 %
LEL / UEL in air, vol.
Autoignition
715 °C
Source: CAMEO Chemicals (NOAA, public domain); per-value source references stored in the database.
§ 10 · Stability and reactivity
Reactive group (CAMEO/NOAA): Phenols and Cresols. Our database documents 17 incompatible and 14 caution reaction-partner groups for phenol — including which combinations release gas on contact. See the per-partner breakdown with gas release →
17
Incompatible
14
Caution
§ 13 · Disposal considerations
Dispose of waste and residues in accordance with local and national regulations — in the EU under the Waste Framework Directive 2008/98/EC. Never discharge to drains or municipal waste; hand contaminated packaging and unused product to an authorised waste-disposal company. The supplier's SDS section 13 lists the applicable waste codes for the specific product.
§ 14 · Transport information
Phenol road transport — ADR 2025
UN number
Proper shipping name
PHENOL, SOLID
Class · PG
6.1 · II
Classification code
T2
Transport category
2
ADR labels
6.1
Hazard ID (Kemler) / UN plate
Top: hazard identification number (Kemler). Bottom: UN number — as carried on the orange plate of the transport unit.
UN number
Proper shipping name
PHENOL, MOLTEN
Class · PG
6.1 · II
Classification code
T1
Transport category
0
ADR labels
6.1
Hazard ID (Kemler) / UN plate
Top: hazard identification number (Kemler). Bottom: UN number — as carried on the orange plate of the transport unit.
UN number
Class · PG
6.1 · II / III
Classification code
T1
Transport category
2
ADR labels
6.1
2 ADR entries under UN 2821
PG II PHENOL SOLUTION
PG III PHENOL SOLUTION
Hazard ID (Kemler) / UN plate
Top: hazard identification number (Kemler). Bottom: UN number — as carried on the orange plate of the transport unit.
Source: UN ADR 2025 (ECE/TRANS/352), Table A. Road (ADR) only — for sea (IMDG) and air (IATA), consult the supplier's SDS §14.
MSDS vs SDS
Phenol MSDS vs SDS: is there a difference?
MSDS (Material Safety Data Sheet) is the older name for the same document. In the US, OSHA's Hazard Communication Standard (2012) adopted the GHS-standardised 16-section Safety Data Sheet; in the EU the format is set by REACH Annex II. So a "phenol MSDS" and a "phenol SDS" refer to the same document — today it is issued as an SDS. Full breakdown of the differences →
Other acute toxics in our database
- (2R,6aS,12aS)-1,2,6,6a,12,12a-hexahydro-2-isopropenyl-8,9-dimethoxychromeno[3,4-b]furo[2,3-h]chromen-6-one, rotenone 83-79-4
- (2S)-2-hydroxy-2-(3-phenoxyphenyl)acetonitrile 61826-76-4
- (4-ammonio-m-tolyl)ethyl(2-hydroxyethyl)ammonium sulphate 25646-77-9
- (Methoxyethyl)mercury chloride 123-88-6
- (RS)-4-[1-(2,3-dimethylphenyl)ethyl]-1H-imidazole 86347-14-0
- [(dimethylsilylene)bis((1,2,3,3a,7a-η)-1H-inden-1-ylidene)dimethyl]hafnium 137390-08-0
- 1-(1,4-Benzodioxan-2-ylcarbonyl)piperazine hydrochloride 70918-74-0
- 1-(3,4-dichlorophenylimino) thiosemicarbazide 5836-73-7
Substance profile
What phenol is
Physical and chemical properties with the conditions each value was measured under, synonyms, formula and the harmonised CLP classification →
Compliance hub
From classification to SDS
The classification above corresponds to Section 2 of a Safety Data Sheet. Learn how a compliant 16-section SDS is structured and authored →
GHS label maker
Build the label for phenol
Pictograms, signal word and H-statements combined into a compliant label layout →
§ 16 · Sources
- Classification: Regulation (EC) No 1272/2008 (CLP), Annex VI
- Transport: UN ADR 2025 (UNECE), Table A
- Reactivity: NOAA CAMEO Chemicals reactive-group matrix (public domain)
- Physical properties: CAMEO Chemicals (NOAA, public domain) — per-value source references stored in the database
- Emergency response (§4–§6): ERG 2024 (PHMSA) · NIOSH Pocket Guide (CDC) · CHRIS (USCG) · NTP · EPA — via CAMEO Chemicals (NOAA), all US federal public domain, reproduced verbatim
- Substance data: PubChem · ECHA
Reference aid only. This page summarises the harmonised EU classification and computed storage guidance — it is not a Safety Data Sheet and does not replace one. Always verify hazards, handling and storage against the supplier's SDS (sections 7 and 10) and local regulations before use. Page updated 2026-08-11.
Frequently asked questions about phenol
Is an MSDS the same as an SDS?
In practice, yes. MSDS (Material Safety Data Sheet) is the older name for the same document. In the US, OSHA's Hazard Communication Standard (2012) adopted the GHS-standardised 16-section Safety Data Sheet; in the EU the SDS format is set by REACH Annex II. A document you find labelled "phenol MSDS" is today issued as an SDS.
What GHS pictograms does phenol require?
Under the harmonised EU classification (CLP Annex VI), phenol carries GHS05 and GHS06 and GHS08 with the signal word "Danger". Hazard statements: H341, H331, H311, H301, H373, H314. A supplier's SDS may add self-classified hazards on top of this harmonised minimum.
Where can I download an official phenol SDS PDF?
From your own supplier — an SDS is issued per product and supplier, so the correct PDF for an inspection is the one matching the product you actually purchased. The supplier links on this page lead to the official SDS libraries of major distributors.
Call emergency services first
112 in the EU · 911 in the US. This screen is published response information, not medical advice, and it does not replace emergency services, a poison centre or the supplier's safety data sheet.
Text below is the CAMEO Chemicals entry PHENOL, SOLID — confirm it matches the form in front of you.
01 · First aid
What to do for the person
Signs and Symptoms of Acute Phenol Exposure: Signs and symptoms of acute exposure to phenol may be severe, and range from tachycardia (rapid heart rate) and tachypnea (rapid respiratory rate) to hypotension (low blood pressure), weak pulse, cardiac failure, pulmonary edema, and respiratory arrest. Cardiac arrhythmias may be noted. Weakness, headache, dizziness, tinnitus (ringing in the ears), delirium, and shock are common. Seizures may often be followed by coma. Pallor, profuse sweating, dilated pupils, and a profound drop in body temperature may occur. Gastrointestinal effects may include nausea, abdominal pain, bloody vomitus, and bloody diarrhea. Renal insufficiency may lead to hematuria (bloody urine). Liver damage may also occur. Phenol is corrosive to the skin and mucous membranes. Contact may result in severe and painful burns, which promptly become anesthetized (numb) to touch and pain. Ulceration may follow.
Emergency Life-Support Procedures: Acute exposure to phenol may require decontamination and life support for the victims. Emergency personnel should wear protective clothing appropriate to the type and degree of contamination. Air-purifying or supplied-air respiratory equipment should also be worn, as necessary. Rescue vehicles should carry supplies such as plastic sheeting and disposable plastic bags to assist in preventing spread of contamination.
Inhalation Exposure: 1. Move victims to fresh air. Emergency personnel should avoid self-exposure to phenol. 2. Evaluate vital signs including pulse and respiratory rate, and note any trauma. If no pulse is detected, provide CPR. If not breathing, provide artificial respiration. If breathing is labored, administer oxygen or other respiratory support. 3. Obtain authorization and/or further instructions from the local hospital for administration of an antidote or performance of other invasive procedures. 4. Transport to a health care facility.
Dermal/Eye Exposure: 1. Remove victims from exposure. Emergency personnel should avoid self- exposure to phenol. 2. Evaluate vital signs including pulse and respiratory rate, and note any trauma. If no pulse is detected, provide CPR. If not breathing, provide artificial respiration. If breathing is labored, administer oxygen or other respiratory support. 3. Remove contaminated clothing as soon as possible. 4. If eye exposure has occurred, eyes must be flushed with lukewarm water for at least 15 minutes. 5. Remove phenol from skin with undiluted polyethylene glycol 300 or 400, if available. If not available, use water. Follow polyethylene glycol wash with a water wash. 6. Wash exposed skin areas for at least 15 minutes with large amounts of water. 7. Obtain authorization and/or further instructions from the local hospital for administration of an antidote or performance of other invasive procedures. 8. Transport to a health care facility.
Ingestion Exposure: 1. Evaluate vital signs including pulse and respiratory rate, and note any trauma. If no pulse is detected, provide CPR. If not breathing, provide artificial respiration. If breathing is labored, administer oxygen or other respiratory support. 2. Obtain authorization and/or further instructions from the local hospital for administration of an antidote or performance of other invasive procedures. 3. Immediately give the victims water or milk: children up to 1 year old, 125 mL (4 oz or 1/2 cup); children 1 to 12 years old, 200 mL (6 oz or 3/4 cup); adults, 250 mL (8 oz or 1 cup). Water or milk should be given only if victims are conscious and alert. 4. If a dilute (5% or less) solution has been ingested, vomiting may be induced with syrup of Ipecac. DO NOT induce vomiting if concentration is greater than 5% or unknown. If elapsed time since ingestion of phenol is unknown or suspected to be greater than 30 minutes, do not induce vomiting and proceed to Step 5. Ipecac should not be administered to children under 6 months of age.Warning: Ingestion of phenol may result in sudden onset of seizures or loss of consciousness. Syrup of Ipecac should be administered only if victims are alert, have an active gag-reflex, and show no signs of impending seizure or coma. If ANY uncertainty exists, proceed to Step 5.The following dosages of Ipecac are recommended: children up to 1 year old, 10 mL (1/3 oz); children 1 to 12 years old, 15 mL (1/2 oz); adults, 30 mL (1 oz). Ambulate (walk) the victims and give large quantities of water. If vomiting has not occurred after 15 minutes, Ipecac may be readministered. Continue to ambulate and give water to the victims. If vomiting has not occurred within 15 minutes after second administration of Ipecac, administer activated charcoal. 5. Activated charcoal may be administered if victims are conscious and alert. Use 15 to 30 g (1/2 to 1 oz) for children, 50 to 100 g (1-3/4 to 3-1/2 oz) for adults, with 125 to 250 mL (1/2 to 1 cup) of water. 6. Promote excretion by administering a saline cathartic or sorbitol to conscious and alert victims. Children require 15 to 30 g (1/2 to 1 oz) of cathartic; 50 to 100 g (1-3/4 to 3-1/2 oz) is recommended for adults. 7. Transport to a health care facility.
02 · Fire
Extinguishing and tactics
Fire and explosion hazard
Flammable vapors when heated. Runoff from fire control water may give off poisonous gases and cause pollution. Mixtures of 9-10% phenol in air are explosive. Avoid aluminum chloride/nitrobenzene mixture, peroxodisulfuric acid, peroxomonosulfuric acid and strong oxidizing agents. Decomposes slowly on air contact. Avoid contact with strong oxidizing agents.
Extinguishing media and tactics
Move container from fire area if it can be done without risk; fight fire from maximum distance; dike fire control water for later disposal, do not scatter the material. Small fires: dry chemical, carbon dioxide, water spray or foam (alcohol); large fires: water spray, fog or foam; use water spray to cool containers in fire area.
03 · Spill
Containment, isolation, evacuation
Containment and clean-up
ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Stop leak if you can do it without risk. Prevent entry into waterways, sewers, basements or confined areas. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. DO NOT GET WATER INSIDE CONTAINERS.
Initial isolation and evacuation
IMMEDIATE PRECAUTIONARY MEASUREIsolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids.
SPILLIncrease the immediate precautionary measure distance, in the downwind direction, as necessary.
FIREIf tank, rail tank car or highway tank is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions.
Sources: ERG 2024 (PHMSA) · NIOSH Pocket Guide (CDC) · CHRIS (USCG) · NTP · EPA — via CAMEO Chemicals (NOAA), public domain. Text reproduced verbatim.