Health hazard · Acute toxicity - dermal
H311 — Toxic in contact with skin
Health hazard statements describe what the substance does to a person exposed to it. 200 substances with a harmonised EU classification carry this code.
01 · Wording
What H311 says
Toxic in contact with skin.
CLP Annex III · Health hazards
Acute toxicity - dermal GHS chapter 3.1
Category 3 · pictogram GHS06 (skull and crossbones) · signal word Danger
Unchanged since 2009.
Present in every UN GHS edition from Rev.3 (2009) to Rev.11 (2025), with the same wording throughout.
Nine editions of the UN model text, 86 hazard statements, 19 of which ever moved. Read the full story in what changed in UN GHS Rev.11.
02 · Languages
H311 in the 24 official EU languages
A label put on the market in an EU country must carry the wording of that country's own language version of CLP — not a translation of the English one. These 24 lines are quoted from the consolidated regulation, Annex III, and are the text to print.
| Language | Official wording of H311 |
|---|---|
| BG български Bulgarian | Токсичен при контакт с кожата. |
| ES español Spanish | Tóxico en contacto con la piel. |
| CS čeština Czech | Toxický při styku s kůží. |
| DA dansk Danish | Giftig ved hudkontakt. |
| DE Deutsch German | Giftig bei Hautkontakt. |
| ET eesti Estonian | Nahale sattumisel mürgine. |
| EL ελληνικά Greek | Τοξικό σε επαφή με το δέρμα. |
| EN English English | Toxic in contact with skin. |
| FR français French | Toxique par contact cutané. |
| GA Gaeilge Irish | Tocsaineach i dteagmháil leis an gcraiceann. |
| HR hrvatski Croatian | Otrovno u dodiru s kožom. |
| IT italiano Italian | Tossico per contatto con la pelle. |
| LV latviešu Latvian | Toksisks, ja nonāk saskarē ar ādu. |
| LT lietuvių Lithuanian | Toksiška susilietus su oda. |
| HU magyar Hungarian | Bőrrel érintkezve mérgező. |
| MT Malti Maltese | Tossiku meta jmiss mal-ġilda. |
| NL Nederlands Dutch | Giftig bij contact met de huid. |
| PL polski Polish | Działa toksycznie w kontakcie ze skórą. |
| PT português Portuguese | Tóxico em contacto com a pele. |
| RO română Romanian | Toxic în contact cu pielea. |
| SK slovenčina Slovak | Toxický pri kontakte s pokožkou. |
| SL slovenščina Slovenian | Strupeno v stiku s kožo. |
| FI suomi Finnish | Myrkyllistä joutuessaan iholle. |
| SV svenska Swedish | Giftigt vid hudkontakt. |
Source: CELEX:02008R1272-20260501, Annex III. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic. Irish is one of the 24 official languages and its H and P texts are printed inside the multilingual Annex tables, but no consolidated CLP has ever been published in Irish — which is why an Irish-primary label cannot be built here.
03 · Legal status
Where H311 is current
GHS is a United Nations model text, revised every two years, and each jurisdiction adopts a revision on its own timetable. A code can be legally current in one system and deleted in another — that is normal, not an error.
| Jurisdiction | Basis | Status of H311 |
|---|---|---|
| EU CLP | Regulation (EC) 1272/2008 CLP Annex IV, Part 2 (consolidated) | Current |
| US OSHA HazCom | 29 CFR 1910.1200 Appendix C UN GHS Rev.7 (final rule of 20 May 2024) | Current |
| US HazCom 2012 | legacy · GHS Rev.3 UN GHS Rev.3, Annex 3 | Current |
| UN GHS | Rev.11 (2025) UN GHS Rev.11, Annex 3 | Current |
Currently in force under: EU CLP, US OSHA HazCom, US HazCom 2012, UN GHS. Sources: EU CLP · US OSHA HazCom · US HazCom 2012 · UN GHS
04 · On a label
H311 also appears combined
CLP Annex III defines combined hazard statements as single label elements. H311 is a component of 3 of them — this is how you will actually see it printed. The combinations have no pages of their own: a plus sign in a URL has to be encoded and breaks in other people's links and in analytics.
| Code | Combined statement |
|---|---|
| H301+H311 | Toxic if swallowed or in contact with skin. CLP verbatim: Toxic if swallowed or in contact with skin |
| H311+H331 | Toxic in contact with skin or if inhaled. CLP verbatim: Toxic in contact with skin or if inhaled |
| H301+H311+H331 | Toxic if swallowed, in contact with skin or if inhaled. CLP verbatim: Toxic if swallowed, in contact with skin or if inhaled |
05 · Substances
Substances carrying H311
Every entry whose harmonised CLP Annex VI classification includes this hazard statement. Substances with a reference page here open on this site; the rest open on ghssymbols.com. Of these, 14 are group entries such as “salts of picric acid” or “beryllium compounds” — Annex VI gives them no CAS number, so they are listed by Index No and have no page of their own.
- 1-(1,4-Benzodioxan-2-ylcarbonyl)piperazine… CAS 70918-74-0
- 1-chloro-2,3-epoxypropane CAS 106-89-8
- 1-Chloro-4-nitrobenzene CAS 100-00-5
- 1,1-Dichloro-1-nitroethane CAS 594-72-9
- 1,2-Dibromoethane CAS 106-93-4
- 1,2-dihydroxybenzene CAS 120-80-9
- 1,2-Dimethylhydrazine CAS 540-73-8
- 1,3-dichloropropene [1] (Z)-1,3-dichloropropene [2] CAS 542-75-6
- 1,4-Diaminobenzene dihydrochloride CAS 624-18-0
- 1,4-Dichloro-2-butene CAS 764-41-0
- 2-(2-butoxyethoxy)ethyl thiocyanate CAS 112-56-1
- 2-Bromo-2-nitropropanol CAS 24403-04-1
- 2-Chloro-3-(trifluoromethyl)pyridine CAS 65753-47-1
- 2-Chloro-5-chloromethylthiazole CAS 105827-91-6
- 2-ethoxyaniline CAS 94-70-2
- 2-hydroxy-1-methylethylacrylate [1]… CAS 2918-23-2
- 2-Hydroxyethyl acrylate CAS 818-61-1
- 2-Methoxyaniline CAS 90-04-0
- 2,2-Dichloroethenyl 2-(ethylsulfinyl)ethyl methyl… CAS 7076-53-1
- 2,2-dimethyltrimethylene diacrylate CAS 2223-82-7
- 2,2'-bioxirane CAS 1464-53-5
- 2,2'-dimethyl-4,4'-methylenebis(cyclohexylamine) CAS 6864-37-5
- 2,2'-methylenebis-(3,4,6-trichlorophenol) CAS 70-30-4
- 2,3-Dibromo-1-propanol CAS 96-13-9
- 2,3-dinitrophenol [1] 2,5-dinitrophenol [2]… CAS 66-56-8
- 2,3-Dinitrotoluene CAS 602-01-7
- 2,3-epoxypropyl acrylate CAS 106-90-1
- 2,3-epoxypropyl methacrylate CAS 106-91-2
- 2,4-Dichlorophenol CAS 120-83-2
- 2,4-Dinitrophenol CAS 51-28-5
- 2,4-dinitrotoluene [1] dinitrotoluene [2] CAS 121-14-2
- 2,4,5-trimethylaniline [1] 2,4,5-trimethylaniline… CAS 137-17-7
- 2,4,6-trinitrophenol CAS 88-89-1
- 2,4,6-Trinitrotoluene CAS 118-96-7
- 2,5-Dinitrotoluene CAS 619-15-8
- 2,6-Dinitrotoluene CAS 606-20-2
- 3-chloro-6-cyano-bicyclo(2,2,1)heptan-2-one-O-(N-methyl… CAS 15271-41-7
- 3-methylpyrazol-5-yl-dimethylcarbamate CAS 2532-43-6
- 3,3'-iminodi(propylamine) CAS 56-18-8
- 3,4-Dichloroaniline CAS 95-76-1
- 3,4-Dinitrotoluene CAS 610-39-9
- 3,4-xylenol [1] 2,5-xylenol [2] 2,4-xylenol [3]… CAS 95-65-8
- 3,5-Dinitrotoluene CAS 618-85-9
- 3,5-xylenol CAS 108-68-9
- 4-chloro-o-toluidine [1] 4-chloro-o-toluidine… CAS 95-69-2
- 4-Chloroaniline CAS 106-47-8
- 4-Methylpyridine CAS 108-89-4
- 4-Nitrotoluene CAS 99-99-0
- 4,4'-oxydianiline and its salts CAS 101-80-4
- 5-nitro-o-toluidine [1] 5-nitro-o-toluidine… CAS 99-55-8
- Acrolein CAS 107-02-8
- Acrylonitrile CAS 107-13-1
- Aldicarb CAS 116-06-3
- Aldrin CAS 309-00-2
- alkali fluorosilicates(Na) [1] alkali… CAS 16893-85-9
- Allyl Alcohol CAS 107-18-6
- Allyl methacrylate CAS 96-05-9
- Allylamine CAS 107-11-9
- Aluminum Phosphide CAS 20859-73-8
- Aminocarb CAS 2032-59-9
- Ammonium fluoride CAS 12125-01-8
- aniline CAS 62-53-3
- Antimony trifluoride CAS 7783-56-4
- Azinphos-Ethyl CAS 2642-71-9
- Azinphos-Methyl CAS 86-50-0
- Bendiocarb CAS 22781-23-3
- bis(2-dimethylaminoethyl)(methyl)amine CAS 3030-47-5
- Bis(Chloromethyl) Ether CAS 542-88-1
- Bromoacetic Acid CAS 79-08-3
- Bufencarb CAS 8065-36-9
- Butocarboxim CAS 34681-10-2
- butyraldehyde oxime CAS 110-69-0
- Butyronitrile CAS 109-74-0
- Calcium phosphide CAS 1305-99-3
- carbon tetrachloride CAS 56-23-5
- Carbophenothion CAS 786-19-6
- Chlordecone CAS 143-50-0
- Chlorfenvinphos CAS 470-90-6
- Chloroacetaldehyde CAS 107-20-0
- Chloroacetic Acid CAS 79-11-8
- Chloroacetonitrile CAS 107-14-2
- Chloroacetyl chloride CAS 79-04-9
- chloroanilines, with exception of those specified… Index No 612-010-00-8
- chlorodinitrobenzene Index No 610-003-00-4
- Chlorthiophos I CAS 21923-23-9
- chromium trioxide CAS 1333-82-0
- Coumatetralyl CAS 5836-29-3
- crotonaldehyde CAS 4170-30-3
- Crotoxyphos CAS 7700-17-6
- Cyanamide CAS 420-04-2
- Cyanthoate CAS 3734-95-0
- Decarbofuran CAS 1563-67-3
- Demephion-O CAS 682-80-4
- Demephion-S CAS 2587-90-8
- Demeton-S-methyl CAS 919-86-8
- Dialifor CAS 10311-84-9
- Dibutylamine CAS 111-92-2
- Dichlorvos CAS 62-73-7
- Dicrotophos CAS 141-66-2
- Dicyclohexylcarbodiimide CAS 538-75-0
- Diethylene glycol diacrylate CAS 4074-88-8
- Dimethyltin dichloride CAS 753-73-1
- Dinex CAS 131-89-5
- dinitrophenol (reaction mass of isomers) [1] 2,4(or… CAS 25550-58-7
- Dinosam CAS 4097-36-3
- Dinoseb CAS 88-85-7
- Dinoterb CAS 1420-07-1
- dioxabenzofos (ISO) CAS 3811-49-2
- Dioxathion CAS 78-34-2
- Diphenylamine CAS 122-39-4
- dipropyl 6,7-methylenedioxy-1,2,3,4-tetrahydro-3-methyl… CAS 83-59-0
- disodium sulfide CAS 1313-82-2
- Emamectin Benzoate CAS 155569-91-8
- Endothion CAS 2778-04-3
- Endrin CAS 72-20-8
- ergocalciferol (ISO) CAS 50-14-6
- Ethephon CAS 16672-87-0
- Ethyl chloroacetate CAS 105-39-5
- Fentin acetate CAS 900-95-8
- fentin hydroxide (ISO) CAS 76-87-9
- Fipronil CAS 120068-37-3
- Fluoroacetamide CAS 640-19-7
- Heptachlor CAS 76-44-8
- Hexachlorocyclopentadiene CAS 77-47-4
- hydrazine CAS 302-01-2
- Hydroxylamine, O-ethyl- CAS 624-86-2
- Hydroxylammonium nitrate CAS 13465-08-2
- Isazofos CAS 42509-80-8
- Isofenphos CAS 25311-71-1
- Isothioate CAS 36614-38-7
- Isoxathion CAS 18854-01-8
- Kelevan CAS 4234-79-1
- Lithium Bis(Trifluoromethanesulfonyl)Imide CAS 90076-65-6
- m-bis(2,3-epoxypropoxy)benzene CAS 101-90-6
- m-cresol [1] o-cresol [2] p-cresol [3] mix-cresol [4] CAS 108-39-4
- M-Phenylenediamine CAS 108-45-2
- M-phenylenediamine dihydrochloride CAS 541-69-5
- m-Toluidine CAS 108-44-1
- Magnesium phosphide CAS 12057-74-8
- Malononitrile CAS 109-77-3
- Mecarbam CAS 2595-54-2
- Mercury cyanide oxide (Hg2(CN)2O) CAS 1335-31-5
- mercury difulminate CAS 628-86-4
- Methacrylonitrile CAS 126-98-7
- Methamidophos CAS 10265-92-6
- methanol CAS 67-56-1
- Methyl Isocyanate CAS 624-83-9
- Methyl Parathion CAS 298-00-0
- Methylisothiazolinone CAS 2682-20-4
- Monocrotophos CAS 6923-22-4
- Morphothion CAS 144-41-2
- N-Ethylaniline CAS 103-69-5
- N-methyl-N-2,4,6-tetranitroaniline CAS 479-45-8
- N-methyl-o-toluidine [1] N-methyl-m-toluidine [2]… CAS 611-21-2
- N-Methylaniline CAS 100-61-8
- N,N-bis(3-aminopropyl)methylamine CAS 105-83-9
- N,N-Diethylaniline CAS 91-66-7
- N,N-dimethyl-m-toluidine CAS 121-72-2
- N,N-Dimethylaniline CAS 121-69-7
- N,N-dimethylbenzene-1,3-diamine [1]… CAS 2836-04-6
- nitrobenzene CAS 98-95-3
- nitrotoluidines, with the exception of those specified… Index No 612-025-00-X
- o-nitroaniline [1] m-nitroaniline [2] p-nitroaniline… CAS 88-74-4
- O,O-Dimethyl S-[2-(propane-2-sulfinyl)ethyl]… CAS 2635-50-9
- octhilinone (ISO) CAS 26530-20-1
- Oxydemeton-methyl CAS 301-12-2
- Oxydisulfoton CAS 2497-07-6
- P-Phenylenediamine CAS 106-50-3
- p-toluidine CAS 106-49-0
- paraquat dichloride CAS 1910-42-5
- Parathion CAS 56-38-2
- Pentachlorophenol CAS 87-86-5
- Phenkapton CAS 2275-14-1
- phenol CAS 108-95-2
- phenylhydrazine [1] phenylhydrazinium chloride [2]… CAS 100-63-0
- Phenyltrimethylammonium chloride CAS 138-24-9
- Phosphamidon CAS 13171-21-6
- Piperidine CAS 110-89-4
- Potassium Fluoride CAS 7789-23-3
- prop-2-yn-1-ol CAS 107-19-7
- Propylene Oxide CAS 75-56-9
- Pyridine-2-thiol 1-oxide, sodium salt Index No 613-344-00-7
- R-1-chloro-2,3-epoxypropane CAS 51594-55-9
- reaction products of paraformaldehyde and… Index No 612-290-00-1
- S-(chlorophenylthiomethyl) O,O-dimethylphosphorodithioa… CAS 953-17-3
- salts and esters of dinex Index No 609-029-00-9
- salts and esters of dinosam Index No 609-034-00-6
- salts and esters of dinoseb, with the exception of… Index No 609-026-00-2
- salts and esters of dinoterb Index No 609-031-00-X
- salts of aniline Index No 612-009-00-2
- salts of hydrazine Index No 007-014-00-6
- salts of picric acid Index No 609-010-00-5
- sodium pentachlorophenolate [1] potassium… CAS 131-52-2
- sodium salt of DNOC CAS 2312-76-7
- Thioglycolic Acid CAS 68-11-1
- Trichloroacetonitrile CAS 545-06-2
- Trichloronate CAS 327-98-0
- Triethylamine CAS 121-44-8
- tripropyltin compounds, with the exception of those… Index No 050-007-00-8
- xylidines with the exception of those specified… Index No 612-027-00-0
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All hazard statements
The full list of H-codes with the jurisdiction switch lives on the hazard statements hub. For what to do about the hazard, see precautionary statements (P-codes).
Wording quoted from the regulation named above. Substance counts come from harmonised classifications in CLP Annex VI — the statements on a real product also depend on the supplier's own classification. Always check the supplier safety data sheet.