Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

Aldrin

Aldrin is colorless needles with a mild chemical odor.

CAS 309-00-2 C12H8Cl6 364.9 g/mol Danger

01 · Identification

What Aldrin is

Aldrin is colorless needles with a mild chemical odor. Its molecular formula is C12H8Cl6 and its molecular weight is 364.9 g/mol. It boils at 145 °C, melts at 104 °C.

Under the GHS it carries the signal word Danger. It is classed as carcinogens.

02 · Identifiers

Aldrin identifiers and molecular data

Aldrin CAS number and EC number

CAS number309-00-2
EC number206-215-8
Index number (CLP Annex VI)602-048-00-3

Aldrin molecular formula and molecular weight

Molecular formulaC12H8Cl6
Molecular weight364.9 g/mol
Chemical class Carcinogens

Other names for Aldrin

  • aldrin (ISO)

03 · GHS classification

Aldrin hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

Aldrin pictograms and signal word

Signal wordDanger

Aldrin hazard class and category

GHS hazard classes Aldrin falls into
Hazard class Category From code Pictogram
Acute toxicity - oral GHS chapter 3.1 Category 3 H301 GHS06
Acute toxicity - dermal GHS chapter 3.1 Category 3 H311 GHS06
Carcinogenicity GHS chapter 3.6 Category 2 H351 GHS08
Specific target organ toxicity - repeated exposure GHS chapter 3.9 Category 1 H372 GHS08
Hazardous to the aquatic environment - acute GHS chapter 4.1 Category 1 H400 GHS09
Hazardous to the aquatic environment - chronic GHS chapter 4.1 Category 1 H410 GHS09

Aldrin hazard statements (H-codes)

Hazard statements assigned to Aldrin
CodeHazard statement
H351 Suspected of causing cancer <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
H311 Toxic in contact with skin.
H301 Toxic if swallowed.
H372 Causes damage to organs <or state all organs affected, if known> through prolonged or repeated exposure <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.

This page lists only the codes assigned to Aldrin. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for Aldrin

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of Aldrin issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

04 · Precautionary statements

Aldrin precautionary statements

CLP Annex VI assigns 15 precautionary statements to Aldrin. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Disposal

What has to happen to the contents and the empty container.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

Aldrin name in 23 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български алдрин (ISO)
Spanish español Aldrina (ISO)
Czech čeština aldrin (ISO)
Danish dansk aldrin (ISO)
German Deutsch Aldrin (ISO)
Estonian eesti aldriin (ISO)
Greek ελληνικά aldrin (αλδρίνη) (ISO)
English English aldrin (ISO)
French français aldrine (ISO)
Croatian hrvatski aldrin (ISO)
Italian italiano aldrin (ISO)
Latvian latviešu aldrīns (ISO)
Lithuanian lietuvių aldrinas (ISO)
Hungarian magyar aldrin (ISO)
Maltese Malti aldrin (ISO)
Dutch Nederlands aldrin (ISO)
Polish polski aldryna (ISO)
Portuguese português aldrina (ISO)
Romanian română aldrin (ISO)
Slovak slovenčina aldrín (ISO)
Slovenian slovenščina aldrin (ISO)
Finnish suomi aldriini (ISO)
Swedish svenska aldrin (ISO)

All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

Aldrin GHS label elements

Everything CLP Annex VI fixes for Aldrin, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS06 Skull and crossbones pictogramGHS08 Health hazard pictogramGHS09 Environment pictogram

Danger

Aldrin

  • Suspected of causing cancer <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
  • Toxic in contact with skin.
  • Toxic if swallowed.
  • Causes damage to organs <or state all organs affected, if known> through prolonged or repeated exposure <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
  • Very toxic to aquatic life.
  • Very toxic to aquatic life with long lasting effects.
  • Obtain special instructions before use.
  • Do not breathe dust/fume/gas/mist/vapours/spray.
  • Do not eat, drink or smoke when using this product.
  • Avoid release to the environment.
  • Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/
  • IF SWALLOWED:
  • IF ON SKIN:
  • IF exposed or concerned:
  • Immediately call a POISON CENTER/doctor/
  • Get medical advice/attention.
  • Get medical advice/attention if you feel unwell.
  • Rinse mouth.
  • Wash with plenty of water/
  • Collect spillage.
  • Dispose of contents/container to

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open Aldrin in the GHS label constructor →

07 · Health hazards

Aldrin health hazards and exposure limits

Aldrin hazard summary

Not currently registered or used in the USA, Aldrin converts to dieldrin in the body and in the environment. High-dose animal studies show that organochlorine insecticides can cause liver injury. [LaDou, p. 593] No evidence of hepatic injury in humans as the result of environmental contamination. [Zimmerman, p. 414] See ATSDR ToxProfiles.

Source: Haz-Map, Information on Hazardous Chemicals and Occupational Diseases

Aldrin carcinogenicity classification

Studied by the US National Toxicology Program: TR-021: Bioassays of Aldrin and Dieldrin for Possible Carcinogenicity (CASRN 309-00-2) (CASRN 60-57-1) (1978 )

Inadequate evidence of carcinogenicity in humans. Limited evidence of carcinogenicity in animals. OVERALL EVALUATION: Group 3: The agent is not classifiable as to its carcinogenicity to humans.

Source: Hazardous Substances Data Bank (HSDB)

Cancer Classification: Group B2 Probable Human Carcinogen

Source: Hazardous Substances Data Bank (HSDB)

An IARC group and a CLP classification answer different questions. IARC judges whether the evidence for cancer in humans is strong enough; CLP Annex VI is the legally binding EU classification. A substance can carry one and not the other.

Aldrin occupational exposure limits

US occupational exposure limits reported for Aldrin. PEL is enforceable (OSHA), REL is a recommendation (NIOSH), IDLH is the concentration at which escape becomes impossible without injury.
Limit Value Source
PEL 0.25 [mg/m3] Haz-Map, Information on Hazardous Chemicals and Occupational Diseases
PEL 0.25 mg/m³ Occupational Safety and Health Administration (OSHA)
PEL TWA 0.25 mg/m3 [skin] The National Institute for Occupational Safety and Health (NIOSH)
REL Ca TWA 0.25 mg/m3 [skin] See Appendix A The National Institute for Occupational Safety and Health (NIOSH)
IDLH 25 mg/m3 ; A potential occupational carcinogen. [From NPG: Aldrin] (NIOSH, 2024) CAMEO Chemicals
IDLH 25 mg/m3 ; A potential occupational carcinogen. (NIOSH, 2024) CAMEO Chemicals
IDLH 25.0 [mg/m3] Haz-Map, Information on Hazardous Chemicals and Occupational Diseases

These are United States values. The European Union sets its own indicative and binding limits, and the figure that applies at a given workplace is the one in the local regulation — not the one shown here.

08 · Physical and chemical properties

Aldrin properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

Aldrin boiling point

Property Value Conditions Source
Boiling point 145 °C (293 °F) at 760 mmHg DOE PAC
145 °C (293 °F) at 2 mmHg (reduced pressure) HSDB
145 °C (293 °F) at 2.02517 mmHg (reduced pressure) ICSC

Aldrin melting point

Property Value Conditions Source
Melting point 104 °C (219.2 °F) HSDB
103.89 °C (219 °F) NIOSH

Aldrin density

Property Value Conditions Source
Density 1.6 g/cm³ NIOSH
1.6 g/cm³ at 20 °C, solid HSDB
1.7 g/cm³ at 20 °C CAMEO

Aldrin solubility

Property Value Conditions Source
Solubility Sol in aromatics, esters, ketones, paraffins and halogenated solvents. HSDB
Sol in ethanol, ether, and acetone. HSDB
0.027 MG/L IN WATER AT 27 °C; > 600 G/L AT 27 °C IN ACETONE, BENZENE, XYLENE at 27 °C HSDB

Aldrin vapor pressure

Property Value Conditions Source
Vapor pressure 0.00008 mmHg NIOSH
0.00012 mmHg at 25 °C HSDB
0.000006 mmHg at 25 °C CAMEO

Aldrin flash point

Property Value Conditions Source
Flash point Approximately 150F or higher (EPA, 1998) CAMEO

Aldrin lower explosive limit (LEL)

Property Value Conditions Source
Lower explosive limit (LEL) Noncombustible Solid, but may be dissolved in flammable liquids. NIOSH

Aldrin corrosivity

Property Value Conditions Source
Corrosivity NONCORROSIVE TO STEEL, BRASS, MONEL, COPPER, NICKEL, ALUMINUM HSDB
Corrosive to metals, owing to the slow formation of hydrogen chloride during storage. HSDB

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

09 · Handling and storage

Aldrin storage and handling

Aldrin safe storage

Provision to contain effluent from fire extinguishing. Separated from food and feedstuffs and incompatible materials. See Chemical Dangers. Well closed. Keep in a well-ventilated room. Store in an area without drain or sewer access.

Source: ILO-WHO International Chemical Safety Cards (ICSCs)

Aldrin storage conditions

Protect containers against physical damage. Store in well-ventilated, cool, dark place separated from sources of ignition. Outdoor or detached storage is preferred.

Source: Hazardous Substances Data Bank (HSDB)

Aldrin incompatible materials

Concentrated mineral acids, active metals, acid catalysts, acid oxidizing agents, phenol.

Source: Hazardous Substances Data Bank (HSDB)

Aldrin reactivity

ALDRIN, LIQUID is a chlorinated diene. May be sensitive to prolonged exposure to light. Stable to heat and in the presence of inorganic and organic bases. Stable with hydrated metal chlorides and mild acids. Reacts with concentrated acids and phenols in the presence of oxidizing agents. Can react with acid catalysts, acid oxidizing agents and active metals (NTP, 1992).

Source: CAMEO Chemicals

Planning storage for a mix of chemicals? Check Aldrin in the storage compatibility matrix →

10 · Questions

Aldrin — frequently asked questions

What is the CAS number of Aldrin?

The CAS number of Aldrin is 309-00-2. Its EC number is 206-215-8.

What is the chemical formula of Aldrin?

The molecular formula of Aldrin is C12H8Cl6 and its molecular weight is 364.9 g/mol.

What does a Aldrin label have to show?

Under CLP Annex VI the label for Aldrin carries the pictograms Skull and crossbones, Health hazard and Environment and the signal word is Danger.

Is Aldrin flammable?

CLP Annex VI assigns Aldrin no flammability hazard class. That is not a statement that it cannot burn: the harmonised list only records the hazards that were assessed for it. The flash point reported for it is Approximately 150F or higher (EPA, 1998) (CAMEO).

Is Aldrin a carcinogen?

CLP Annex VI assigns Aldrin H351 — suspected of causing cancer. That is category 2: the evidence points that way but is not conclusive.

What is the exposure limit for Aldrin?

The US occupational exposure limit reported for Aldrin is 0.25 [mg/m3] (Haz-Map, Information on Hazardous Chemicals and Occupational Diseases). Limits differ by country: the EU sets its own indicative and binding values, and the figure that applies at a given workplace is the one in the local regulation.

What is the boiling point of Aldrin?

The boiling point reported for Aldrin is 145 °C (293 °F), at 760 mmHg (DOE PAC).

What is the melting point of Aldrin?

The melting point reported for Aldrin is 104 °C (219.2 °F) (HSDB).

How should Aldrin be stored?

Protect containers against physical damage. Store in well-ventilated, cool, dark place separated from sources of ignition. Outdoor or detached storage is preferred. (Hazardous Substances Data Bank (HSDB))

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