Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

Aldicarb

Aldicarb is crystals from isopropyl ether with a slightly sulfurous odor.

CAS 116-06-3 C7H14N2O2S 190.27 g/mol Danger

01 · Identification

What Aldicarb is

Aldicarb is crystals from isopropyl ether with a slightly sulfurous odor. Its molecular formula is C7H14N2O2S and its molecular weight is 190.27 g/mol. It melts at 100 °C.

Under the GHS it carries the signal word Danger.

02 · Identifiers

Aldicarb identifiers and molecular data

Aldicarb CAS number and EC number

CAS number116-06-3
EC number204-123-2
Index number (CLP Annex VI)006-017-00-X

Aldicarb molecular formula and molecular weight

Molecular formulaC7H14N2O2S
Molecular weight190.27 g/mol

Other names for Aldicarb

  • aldicarb (ISO)
  • 2-methyl-2-(methylthio)propanal-O-(N-methylcarbamoyl)oxime

03 · GHS classification

Aldicarb hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

Aldicarb pictograms and signal word

Signal wordDanger

Aldicarb hazard class and category

GHS hazard classes Aldicarb falls into
Hazard class Category From code Pictogram
Acute toxicity - oral GHS chapter 3.1 Category 1 or 2 H300 GHS06
Acute toxicity - dermal GHS chapter 3.1 Category 3 H311 GHS06
Acute toxicity - inhalation GHS chapter 3.1 Category 1 or 2 H330 GHS06
Hazardous to the aquatic environment - acute GHS chapter 4.1 Category 1 H400 GHS09
Hazardous to the aquatic environment - chronic GHS chapter 4.1 Category 1 H410 GHS09

Where two values are shown with “or”, the hazard statement is shared by more than one category or by more than one class, and the code alone does not say which. H272, for example, belongs to oxidising liquids and to oxidising solids — the physical state decides. The binding answer for a specific entry is in the CLP Annex VI table itself.

Aldicarb hazard statements (H-codes)

Hazard statements assigned to Aldicarb
CodeHazard statement
H330 Fatal if inhaled.
H300 Fatal if swallowed.
H311 Toxic in contact with skin.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.

This page lists only the codes assigned to Aldicarb. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for Aldicarb

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of Aldicarb issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

04 · Precautionary statements

Aldicarb precautionary statements

CLP Annex VI assigns 13 precautionary statements to Aldicarb. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Disposal

What has to happen to the contents and the empty container.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

Aldicarb name in 23 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български алдикарб (ISO) 2-метил-2-(метилтио)пропанал- O -( N -метилкарбамоил)оксим
Spanish español Aldicarb (ISO) 2-metil-2-(metiltio)propanal- O -( N -metilcarbamoil)oxima
Czech čeština aldikarb (ISO) 2-methyl-2-(methylsulfanyl)propanal- O -( N -methylkarbamoyl)oxim
Danish dansk aldicarb (ISO) 2-methyl-2-(methylthio)propionaldehyd- O -(methylcarbamoyl)oxim
German Deutsch Aldicarb (ISO) 2-Methyl-2-(methylthio) propanal- O -( N -methylcarbamoyl)oxim
Estonian eesti aldikarb (ISO) 2-metüül-2-(metüültio)propanaal- O -( N -metüülkarbamoüül)oksiim
Greek ελληνικά aldicarb (αλδικάρβη) (ISO) 2-μεθυλο-2-(μεθυλοθειο)προπαναλ- O -( N -μεθυλοκαρβαμοϋλ)οξίμη
English English aldicarb (ISO) 2-methyl-2-(methylthio)propanal- O -( N -methylcarbamoyl)oxime
French français aldicarbe (ISO) 2-méthyl-2-(méthylthio)propanal- O -( N -méthylcarbamoyl)oxime
Croatian hrvatski aldikarb (ISO) 2-metil-2-(metiltio)propanal- O -( N -metil-karbamoil)oksim
Italian italiano aldicarb (ISO) 2-metil-2-(metiltio) propanal O-[(metilamino)carbonil] ossima
Latvian latviešu aldikarbs (ISO) 2-metil-2-(metiltio)propanāl- O -( N -metilkarbamoil)oksīms
Lithuanian lietuvių aldikarbas (ISO) 2-metil-2-(metiltio)propanal-O-(N-metilkarbamoil)oksimas
Hungarian magyar aldikarb (ISO) 2-metil-2-(metiltio)propanal- O -( N -metilkarbamoil)oxim
Maltese Malti aldikarb (ISO) 2-metil-2-(metiltijo)propanal-O-(N-metilkarbamoil)ossima
Dutch Nederlands aldicarb (ISO) 2-methyl-2-(methylthio)propanal- O -( N -methylcarbamoyl)oxim
Polish polski aldikarb (ISO) O-(metylokarbamoilo)oksym 2-metylo-2-(metylosulfanylo)propanalu
Portuguese português aldicarbe (ISO) O -( N -metilcarbamoil)oxima de 2-metil-2-(metiltio)propanal
Romanian română aldicarb (ISO) 2-metil-2-(metiltio)propanal- O -( N -metilcarbamoil)oximă
Slovak slovenčina aldikarb (ISO) 2-metyl-2-(metylsulfanyl)propanál- O -( N -metylkarbamoyl)oxím
Slovenian slovenščina aldikarb (ISO) 2-metil-2-(metiltio)propanal- O -( N -metilkarbamoil)oksim
Finnish suomi aldikarbi (ISO) 2-metyyli-2-(metyylitio)propanaali- O -( N -metyylikarbamoyyli)oksiimi
Swedish svenska aldikarb (ISO) 2-metyl-2-(metyltio)propanal- O -( N -metylkarbamoyl)oxim

All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

Aldicarb GHS label elements

Everything CLP Annex VI fixes for Aldicarb, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS06 Skull and crossbones pictogramGHS09 Environment pictogram

Danger

Aldicarb

  • Fatal if inhaled.
  • Fatal if swallowed.
  • Toxic in contact with skin.
  • Very toxic to aquatic life.
  • Very toxic to aquatic life with long lasting effects.
  • Do not breathe dust/fume/gas/mist/vapours/spray.
  • Do not eat, drink or smoke when using this product.
  • Use only outdoors or in a well-ventilated area.
  • Avoid release to the environment.
  • Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/
  • IF SWALLOWED:
  • IF ON SKIN:
  • IF INHALED:
  • Immediately call a POISON CENTER/doctor/
  • Rinse mouth.
  • Wash with plenty of water/
  • Collect spillage.
  • Dispose of contents/container to

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open Aldicarb in the GHS label constructor →

07 · Health hazards

Aldicarb health hazards and exposure limits

Aldicarb carcinogenicity classification

IARC classification Group 3 — Not classifiable as to its carcinogenicity to humans
IARC monographs Volume 53: (1991) Occupational Exposures in Insecticide Application, and Some Pesticides

Studied by the US National Toxicology Program: TR-136: Bioassay of Aldicarb for Possible Carcinogenicity (CASRN 116-06-3) (1979 )

Evaluation: No data were available from studies in humans. There is inadequate evidence for the carcinogenicity of aldicarb in experimental animals. Overall evaluation: Aldicarb is not classifiable as to its carcinogenicity to humans (Group 3).

Source: Hazardous Substances Data Bank (HSDB)

Cancer Classification: Group E Evidence of Non-carcinogenicity for Humans

Source: Hazardous Substances Data Bank (HSDB)

An IARC group and a CLP classification answer different questions. IARC judges whether the evidence for cancer in humans is strong enough; CLP Annex VI is the legally binding EU classification. A substance can carry one and not the other.

08 · Physical and chemical properties

Aldicarb properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

Aldicarb boiling point

Property Value Conditions Source
Boiling point Decomposes (NTP, 1992) decomposes CAMEO
decomposes decomposes OSHA

Aldicarb melting point

Property Value Conditions Source
Melting point 100 °C (212 °F) ICSC
99 °C (210.2 °F) DOE PAC
99.5 °C (211.1 °F) range, midpoint shown HSDB

Aldicarb density

Property Value Conditions Source
Density 1.195 g/cm³ OSHA
1.195 g/cm³ at 25 °C HSDB

Aldicarb solubility

Property Value Conditions Source
Solubility Sparingly soluble in certain organic solvents, most soluble in chloroform and acetone HSDB
Aldicarb solubilities (expressed as %) at various temperatures. HSDB
Table: Percent Solubility [Table#3193] HSDB

Aldicarb vapor pressure

Property Value Conditions Source
Vapor pressure 0.000029 mmHg at 20 °C HSDB
1e-7 mmHg at 20 °C DOE PAC
0.00007501 mmHg at 25 °C ICSC

Aldicarb corrosivity

Property Value Conditions Source
Corrosivity Non-corrosive to common metals and plastics HSDB

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

09 · Fire and explosion

Aldicarb fire and explosion behaviour

These are descriptions rather than measured values, so they are kept out of the table above and quoted here with the source that reported them.

Aldicarb fire potential

Aldicarb is ... considered a negligible fire hazard. It is non-flammable and is difficult to ignite, but may burn if exposed to flames. Aldicarb should be kept away from open flames.

Source: Hazardous Substances Data Bank (HSDB)

10 · Handling and storage

Aldicarb storage and handling

Aldicarb safe storage

Provision to contain effluent from fire extinguishing. Separated from food and feedstuffs.

Source: ILO-WHO International Chemical Safety Cards (ICSCs)

Aldicarb storage conditions

Store aldicarb indoors in an isolated, well-ventilated, clean, dry, cool area (not above 46 °C). Store away from incompatible substances, such as highly alkaline materials. Aldicarb should be stored in a manner that will preclude mixing with water, because the resultant solution may be seriously hazardous. Do not store near food, animal feed, or other items intended for human or animal consumption. Make certain that the storage area is inaccessible to children.

Source: Hazardous Substances Data Bank (HSDB)

Aldicarb incompatible materials

Incompatible with alkaline materials.

Source: Hazardous Substances Data Bank (HSDB)

Aldicarb reactivity

ALDICARB is a carbamate ester. This chemical decomposes at temperatures greater than 212 °F. This chemical is incompatible with highly alkaline substances. It is rapidly converted by oxidizing agents. (NTP, 1992)

Source: CAMEO Chemicals

Planning storage for a mix of chemicals? Check Aldicarb in the storage compatibility matrix →

11 · Questions

Aldicarb — frequently asked questions

What is the CAS number of Aldicarb?

The CAS number of Aldicarb is 116-06-3. Its EC number is 204-123-2.

What is the chemical formula of Aldicarb?

The molecular formula of Aldicarb is C7H14N2O2S and its molecular weight is 190.27 g/mol.

What does a Aldicarb label have to show?

Under CLP Annex VI the label for Aldicarb carries the pictograms Skull and crossbones and Environment and the signal word is Danger.

Is Aldicarb flammable?

CLP Annex VI assigns Aldicarb no flammability hazard class. That is not a statement that it cannot burn: the harmonised list only records the hazards that were assessed for it.

Is Aldicarb a carcinogen?

CLP Annex VI records no harmonised carcinogenicity classification for Aldicarb. Annex VI is a list of agreed classifications, not a list of substances found safe, so this is an absence of a classification rather than a clean bill of health. IARC places it in Group 3: not classifiable as to its carcinogenicity to humans.

What is the boiling point of Aldicarb?

The boiling point reported for Aldicarb is Decomposes (NTP, 1992), decomposes (CAMEO).

What is the melting point of Aldicarb?

The melting point reported for Aldicarb is 100 °C (212 °F) (ICSC).

How should Aldicarb be stored?

Store aldicarb indoors in an isolated, well-ventilated, clean, dry, cool area (not above 46 °C). Store away from incompatible substances, such as highly alkaline materials. Aldicarb should be stored in a manner that will preclude mixing with water, because the resultant solution may be seriously hazardous. Do not store near food, animal feed, or other items intended for human or animal consumption. Make certain that the storage area is inaccessible to children. (Hazardous Substances Data Bank (HSDB))

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