Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

Butocarboxim

Butocarboxim is a pale brown, viscous liquid (tech.).

CAS 34681-10-2 C7H14N2O2S 190.27 g/mol Danger

01 · Identification

What Butocarboxim is

Butocarboxim is a pale brown, viscous liquid (tech.). Its molecular formula is C7H14N2O2S and its molecular weight is 190.27 g/mol. It melts at 37 °C, is soluble in water.

Under the GHS it carries the signal word Danger.

02 · Identifiers

Butocarboxim identifiers and molecular data

Butocarboxim CAS number and EC number

CAS number34681-10-2
EC number252-139-3
Index number (CLP Annex VI)006-083-00-X

Butocarboxim molecular formula and molecular weight

Molecular formulaC7H14N2O2S
Molecular weight190.27 g/mol

Other names for Butocarboxim

  • butocarboxim (ISO)
  • 3-(methylthio)-2-butanone O-[(methylamino)carbonyl]oxime

03 · GHS classification

Butocarboxim hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

Butocarboxim pictograms and signal word

Signal wordDanger

Butocarboxim hazard class and category

GHS hazard classes Butocarboxim falls into
Hazard class Category From code Pictogram
Flammable liquids GHS chapter 2.6 Category 3 H226 GHS02
Acute toxicity - oral GHS chapter 3.1 Category 3 H301 GHS06
Acute toxicity - dermal GHS chapter 3.1 Category 3 H311 GHS06
Acute toxicity - inhalation GHS chapter 3.1 Category 3 H331 GHS06
Serious eye damage/eye irritation GHS chapter 3.3 Category 2A H319 GHS07
Hazardous to the aquatic environment - acute GHS chapter 4.1 Category 1 H400 GHS09
Hazardous to the aquatic environment - chronic GHS chapter 4.1 Category 1 H410 GHS09

Butocarboxim hazard statements (H-codes)

Hazard statements assigned to Butocarboxim
CodeHazard statement
H226 Flammable liquid and vapour.
H331 Toxic if inhaled.
H311 Toxic in contact with skin.
H301 Toxic if swallowed.
H319 Causes serious eye irritation.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.

This page lists only the codes assigned to Butocarboxim. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for Butocarboxim

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of Butocarboxim issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

04 · Precautionary statements

Butocarboxim precautionary statements

CLP Annex VI assigns 23 precautionary statements to Butocarboxim. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Storage

How the container has to be kept between uses.

Disposal

What has to happen to the contents and the empty container.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

Butocarboxim name in 23 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български бутокарбоксим (ISO) 3-(метилтио)-2-бутанон- О -[(метиламино)карбонил]оксим
Spanish español Butocarboxim (ISO) 3-(metiltio)-2-butanona- O -[(metilamino)carbonil]oxima
Czech čeština butokarboxim (ISO) 3-(methylsulfanyl)butan-2-on-oxim- O -( N -methylkarbamát)
Danish dansk butocarboxim (ISO 3-(methylthio)-2-butanon O- [(methylamino)carbonyl]oxim
German Deutsch Butocarboxim (ISO) 3-(Methylthio)-2-butanon- O -[(methylamino)carbonyl]oxim
Estonian eesti butokarboksiim (ISO) 3-(metüültio)-2-butanoon- O -[(metüülamino)karbonüül]oksiim
Greek ελληνικά butocarboxim (βουτοκαρβοξίμη) (ISO) 3-(μεθυλοθειο)-2-βουτανονο- Ο -[(μεθυλαμινο)καρβονυλ]οξίμη
English English butocarboxim (ISO) 3-(methylthio)-2-butanone O -[(methylamino)carbonyl]oxime
French français butocarboxime (ISO) 3-(méthylthio)-2-butanone- O -[(méthylamino)carbonyl]oxime
Croatian hrvatski butokarboksim (ISO) 3-(metiltio)-2-butanon- O -[(metilamino)karbonil]oksim
Italian italiano butocarbossim (ISO) O -[(metilammino)carbonil]oxime di 3-(metiltio)-2-butanone
Latvian latviešu butokarboksīms (ISO) 3-(metiltio)-2-butanon- O -[(metilamino)karbonil]oksīms
Lithuanian lietuvių butokarboksimas (ISO) 3-(metiltio)-2-butanon- O -[(metilamino)karbonil]oksimas
Hungarian magyar butokarboxim (ISO) 3-(metiltio)-2-butanon- O -[(metilamino)karbonil]oxim
Maltese Malti butokarbossim (ISO) O -[(metilamino)karbonil]ossim ta’ 3-(metiltijo)-2-butanon
Dutch Nederlands butocarboxim (ISO) 3-(methylthio)-2-butanon- O -[(methylamino)carbonyl]oxim
Polish polski butokarboksym (ISO) O -[(metyloamino)karbonylo]oksym 3-(metylosulfanylo)butan-2-onuO -metylokarbamoilooksym 3-(metylotio)butanonu
Portuguese português butocarboxime (ISO) O -[(metilamino)carbonil]oxima de 3-(metitio)-2-butanona
Romanian română butocarboxim (ISO) 3-(metiltio)-2-butanon- O - [(metilamino)carbonil]oximă]
Slovak slovenčina butokarboxím (ISO) 3-(metylsulfanyl)butanón- O -(metylkarbamoyl)oxím
Slovenian slovenščina butokarboksim (ISO) 3-(metiltio)-2-butanon O -[(metilamino)karbonil]oksim
Finnish suomi butokarboksiimi (ISO) 3-(metyylitio)-2-butanoni- O -[(metyyliamino)karbonyyli]oksiimi
Swedish svenska butokarboxim (ISO) 3-(metyltio)-2-butanon- O -[(metylamino)karbonyl]oxim

All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

Butocarboxim GHS label elements

Everything CLP Annex VI fixes for Butocarboxim, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS02 Flame pictogramGHS06 Skull and crossbones pictogramGHS09 Environment pictogram

Danger

Butocarboxim

  • Flammable liquid and vapour.
  • Toxic if inhaled.
  • Toxic in contact with skin.
  • Toxic if swallowed.
  • Causes serious eye irritation.
  • Very toxic to aquatic life.
  • Very toxic to aquatic life with long lasting effects.
  • Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
  • Keep container tightly closed.
  • Use explosion-proof [electrical/ventilating/lighting/…] equipment.
  • Use only non-sparking tools.
  • Do not breathe dust/fume/gas/mist/vapours/spray.
  • Wash thoroughly after handling.
  • Do not eat, drink or smoke when using this product.
  • Use only outdoors or in a well-ventilated area.
  • Avoid release to the environment.
  • Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/
  • IF SWALLOWED:
  • IF ON SKIN:
  • IF INHALED:
  • IF IN EYES:
  • Immediately call a POISON CENTER/doctor/
  • Get medical advice/attention.
  • Rinse mouth.
  • If eye irritation persists:
  • Remove contact lenses, if present and easy to do. Continue rinsing.
  • Wash with plenty of water/
  • Collect spillage.
  • Store in a well-ventilated place.
  • Dispose of contents/container to

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open Butocarboxim in the GHS label constructor →

07 · Health hazards

Butocarboxim health hazards and exposure limits

Butocarboxim hazard summary

A mild skin and moderate eye irritant; No effects observed on fertility, growth rate, or mortality and no evidence of carcinogenicity or mutagenicity in two year feeding study with rats at highest dose (300 mg/kg diet); [HSDB] An eye irritant; [eChemPortal: ESIS] See CARBAMATE INSECTICIDES.

Source: Haz-Map, Information on Hazardous Chemicals and Occupational Diseases

08 · Physical and chemical properties

Butocarboxim properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

Butocarboxim melting point

Property Value Conditions Source
Melting point 37 °C (98.6 °F) HSDB

Butocarboxim density

Property Value Conditions Source
Density 1.12 g/cm³ at 20 °C HSDB

Butocarboxim solubility

Property Value Conditions Source
Solubility Soluble in most organic solvents. HSDB
Completely miscible with aromatic hydrocarbons, esters, and ketones. Low solubility in aliphatic hydrocarbons (11 g/l) and carbon tetrachloride. HSDB
In water, 35 g/l @ 20 °C at 20 °C HSDB

Butocarboxim vapor pressure

Property Value Conditions Source
Vapor pressure 0.0000795 mmHg at 20 °C HSDB
0.0000795 mmHg Haz-Map

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

09 · Questions

Butocarboxim — frequently asked questions

What is the CAS number of Butocarboxim?

The CAS number of Butocarboxim is 34681-10-2. Its EC number is 252-139-3.

What is the chemical formula of Butocarboxim?

The molecular formula of Butocarboxim is C7H14N2O2S and its molecular weight is 190.27 g/mol.

What does a Butocarboxim label have to show?

Under CLP Annex VI the label for Butocarboxim carries the pictograms Flame, Skull and crossbones and Environment and the signal word is Danger.

Is Butocarboxim flammable?

Yes. CLP Annex VI assigns Butocarboxim H226 — flammable liquid and vapour.

Is Butocarboxim a carcinogen?

CLP Annex VI records no harmonised carcinogenicity classification for Butocarboxim. Annex VI is a list of agreed classifications, not a list of substances found safe, so this is an absence of a classification rather than a clean bill of health.

What is the melting point of Butocarboxim?

The melting point reported for Butocarboxim is 37 °C (98.6 °F) (HSDB).

How should Butocarboxim be stored?

CLP Annex VI assigns Butocarboxim the storage statement P403.

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