Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

Coumatetralyl

Coumatetralyl is colorless crystals and is odorless.

CAS 5836-29-3 Danger

01 · Identification

What Coumatetralyl is

Coumatetralyl is colorless crystals and is odorless. It melts at 176 °C.

Under the GHS it carries the signal word Danger.

02 · Identifiers

Coumatetralyl identifiers and molecular data

Coumatetralyl CAS number and EC number

CAS number5836-29-3
EC number227-424-0
Index number (CLP Annex VI)607-059-00-7

Other names for Coumatetralyl

  • coumatetralyl (ISO)
  • 4-hydroxy-3-(1,2,3,4-tetrahydro-1-naphthyl)coumarin

03 · GHS classification

Coumatetralyl hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

Coumatetralyl pictograms and signal word

Signal wordDanger

Coumatetralyl hazard class and category

GHS hazard classes Coumatetralyl falls into
Hazard class Category From code Pictogram
Acute toxicity - oral GHS chapter 3.1 Category 1 or 2 H300 GHS06
Acute toxicity - dermal GHS chapter 3.1 Category 3 H311 GHS06
Acute toxicity - inhalation GHS chapter 3.1 Category 1 or 2 H330 GHS06
Specific target organ toxicity - repeated exposure GHS chapter 3.9 Category 1 H372 GHS08
Hazardous to the aquatic environment - chronic GHS chapter 4.1 Category 1 H410 GHS09

Where two values are shown with “or”, the hazard statement is shared by more than one category or by more than one class, and the code alone does not say which. H272, for example, belongs to oxidising liquids and to oxidising solids — the physical state decides. The binding answer for a specific entry is in the CLP Annex VI table itself.

Coumatetralyl hazard statements (H-codes)

Hazard statements assigned to Coumatetralyl
CodeHazard statement
H360D May damage the unborn child.
H330 Fatal if inhaled.
H300 Fatal if swallowed.
H311 Toxic in contact with skin.
H372 Causes damage to organs <or state all organs affected, if known> through prolonged or repeated exposure <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
H410 Very toxic to aquatic life with long lasting effects.

This page lists only the codes assigned to Coumatetralyl. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for Coumatetralyl

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of Coumatetralyl issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

04 · Precautionary statements

Coumatetralyl precautionary statements

CLP Annex VI assigns 14 precautionary statements to Coumatetralyl. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Disposal

What has to happen to the contents and the empty container.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

Coumatetralyl name in 23 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български куматетралил (ISO) 4-хидрокси-3-(1,2,3,4-тетрахидро- 1-нафтил)кумарин
Spanish español cumatetralilo (ISO) 4-hidroxi-3-(1,2,3,4-tetrahidro-1-naftil)cumarina
Czech čeština kumatetralyl (ISO) 4-hydroxy-3-(1,2,3,4-tetrahydro-1-naftyl)-2 H -chromen-2-on
Danish dansk coumatetralyl (ISO) 4-hydroxy-3-(1,2,3,4-tetrahydro-1-naphthyl)coumarin
German Deutsch Coumatetralyl (ISO) 4-Hydroxy-3-(1,2,3,4-tetrahydro-1-naphthyl)cumarin
Estonian eesti kumatetralüül (ISO) 4-hüdroksü-3-(1,2,3,4-tetrahüdro-1-naftüül)kumariin
Greek ελληνικά κουματετραλύλη (ISO) 4-υδροξυ-3-(1,2,3,4-τετραϋδρο-1-ναφθυλο)κουμαρίνη
English English coumatetralyl (ISO) 4-hydroxy-3-(1,2,3,4-tetrahydro-1-naphthyl)coumarin
French français coumatétralyl (ISO) 4-hydroxy-3-(1,2,3,4-tétrahydro-1-naphthyl)coumarin
Croatian hrvatski kumatetralil (ISO) 4-hidroksi-3-(1,2,3,4-tetrahidro-1-naftil)kumarin
Italian italiano coumatetralil (ISO) 4-idrossi-3-(1,2,3,4-tetraidro-1-naftil)coumarina
Latvian latviešu kumatetralils ( ISO ) 4-hidroksi-3-(1,2,3,4-tetrahidro-1-naftil)kumarīns
Lithuanian lietuvių kumatetralilas (ISO) 4-hidroksi-3-(1,2,3,4-tetrahidro-1-naftil)kumarinas
Hungarian magyar kumatetralil (ISO) 4-hidroxi-3-(1,2,3,4-tetrahidro-1-naftil)kumarin
Maltese Malti kumatetralil (ISO) 4-idrossi-3-(1,2,3,4-tetraidro-1-naftil)kumarin
Dutch Nederlands cumatetralyl (ISO) 4-hydroxy-3-(1,2,3,4-tetrahydro-1-naftyl)cumarine
Polish polski kumatetralyl (ISO) 4-hydroksy-3-(1,2,3,4-tetrahydro-1-naftylo)kumaryna
Portuguese português cumatetralilo (ISO) 4-hidroxi-3-(1,2,3,4-tetra-hidro-1-naftil)cumarina
Romanian română cumatetralil (ISO), 4-hidroxi-3-(1,2,3,4-tetrahidro-1-naftil)cumarină
Slovak slovenčina kumatetralyl 4-hydroxy-3-(1,2,3,4-tetrahydro-1-naftyl)-2H-chromén-2-ón
Slovenian slovenščina kumatetralil (ISO) 4-hidroksi-3-(1,2,3,4-tetrahidro-1-naftil)kumarin
Finnish suomi kumatetralyyli (ISO) 4-hydroksi-3-(1,2,3,4-tetrahydro-1-naftyyli)kumariini
Swedish svenska kumatetralyl (ISO) 4-hydroxi-3-(1,2,3,4-tetrahydro-1-naftyl]kumarin

All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

Coumatetralyl GHS label elements

Everything CLP Annex VI fixes for Coumatetralyl, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS08 Health hazard pictogramGHS06 Skull and crossbones pictogramGHS09 Environment pictogram

Danger

Coumatetralyl

  • May damage the unborn child.
  • Fatal if inhaled.
  • Fatal if swallowed.
  • Toxic in contact with skin.
  • Causes damage to organs <or state all organs affected, if known> through prolonged or repeated exposure <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
  • Very toxic to aquatic life with long lasting effects.
  • Do not breathe dust/fume/gas/mist/vapours/spray.
  • Do not eat, drink or smoke when using this product.
  • Use only outdoors or in a well-ventilated area.
  • Avoid release to the environment.
  • Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/
  • IF SWALLOWED:
  • IF ON SKIN:
  • IF INHALED:
  • Immediately call a POISON CENTER/doctor/
  • Get medical advice/attention if you feel unwell.
  • Rinse mouth.
  • Wash with plenty of water/
  • Collect spillage.
  • Dispose of contents/container to

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open Coumatetralyl in the GHS label constructor →

07 · Health hazards

Coumatetralyl health hazards and exposure limits

Coumatetralyl hazard summary

A vitamin K antagonist--causes clotting factor disruption and bleeding; Absorbed through skin; [HSDB] First generation anticoagulant rodenticide; [INCHEM] Registered for use in the EU; Not irritating to skin or eyes of rabbits; Not sensitizing to skin of guinea pigs; No evidence of mutagenic effects; No evidence of teratogenicity in rats or rabbits (although all anti-vitamin K rodenticides classified by this commission May cause harm to the unborn child based on the known human developmental toxicity of Warfarin); The commercial product Racumin® Paste showed potential for skin sensitization in a Magnusson and Kligman study; [eChemPortal: ESIS] See Warfarin.

Source: Haz-Map, Information on Hazardous Chemicals and Occupational Diseases

08 · Physical and chemical properties

Coumatetralyl properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

Coumatetralyl melting point

Property Value Conditions Source
Melting point 176.11 °C (349 °F) CAMEO
174 °C (345.2 °F) range, midpoint shown HSDB
169 °C (336.2 °F) range, midpoint shown HSDB

Coumatetralyl solubility

Property Value Conditions Source
Solubility Soluble in alcohols and acetone; slightly soluble in benzene, toluene, and diethyl ether. HSDB
SOL IN DIL ALKALI & MOST ORG SOLVENTS HSDB
In water, 425 mg/L at 20 °C and pH 7 at 20 °C HSDB

Coumatetralyl vapor pressure

Property Value Conditions Source
Vapor pressure 0.0638 mmHg at 20 °C HSDB

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

09 · Fire and explosion

Coumatetralyl fire and explosion behaviour

These are descriptions rather than measured values, so they are kept out of the table above and quoted here with the source that reported them.

Coumatetralyl fire potential

Not flammable or combustible.

Source: Hazardous Substances Data Bank (HSDB)

10 · Handling and storage

Coumatetralyl storage and handling

Coumatetralyl storage conditions

Keep container tightly closed in a dry and well-ventilated place. Keep in a dry place.

Source: Hazardous Substances Data Bank (HSDB)

Coumatetralyl reactivity

Ketones, such as COUMATETRALYL, are reactive with many acids and bases liberating heat and flammable gases (e.g., H2). The amount of heat may be sufficient to start a fire in the unreacted portion of the ketone. Ketones react with reducing agents such as hydrides, alkali metals, and nitrides to produce flammable gas (H2) and heat. Ketones are incompatible with isocyanates, aldehydes, cyanides, peroxides, and anhydrides. They react violently with aldehydes, HNO3, HNO3 + H2O2, and HClO4.

Source: CAMEO Chemicals

Planning storage for a mix of chemicals? Check Coumatetralyl in the storage compatibility matrix →

11 · Questions

Coumatetralyl — frequently asked questions

What is the CAS number of Coumatetralyl?

The CAS number of Coumatetralyl is 5836-29-3. Its EC number is 227-424-0.

What does a Coumatetralyl label have to show?

Under CLP Annex VI the label for Coumatetralyl carries the pictograms Health hazard, Skull and crossbones and Environment and the signal word is Danger.

Is Coumatetralyl flammable?

CLP Annex VI assigns Coumatetralyl no flammability hazard class. That is not a statement that it cannot burn: the harmonised list only records the hazards that were assessed for it.

Is Coumatetralyl a carcinogen?

CLP Annex VI records no harmonised carcinogenicity classification for Coumatetralyl. Annex VI is a list of agreed classifications, not a list of substances found safe, so this is an absence of a classification rather than a clean bill of health.

What is the melting point of Coumatetralyl?

The melting point reported for Coumatetralyl is 176.11 °C (349 °F) (CAMEO).

How should Coumatetralyl be stored?

Keep container tightly closed in a dry and well-ventilated place. Keep in a dry place. (Hazardous Substances Data Bank (HSDB))

Nearby

Substances next to Coumatetralyl

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