Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

Carbophenothion

Carbophenothion is a colorless liq with a mercaptan-like odor.

CAS 786-19-6 Danger

01 · Identification

What Carbophenothion is

Carbophenothion is a colorless liq with a mercaptan-like odor. It is miscible with water.

Under the GHS it carries the signal word Danger.

02 · Identifiers

Carbophenothion identifiers and molecular data

Carbophenothion CAS number and EC number

CAS number786-19-6
EC number212-324-1
Index number (CLP Annex VI)015-044-00-6

Other names for Carbophenothion

  • carbophenothion (ISO)
  • 4-chlorophenylthiomethyl O,O-diethyl phosphorodithioate

03 · GHS classification

Carbophenothion hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

Carbophenothion pictograms and signal word

Signal wordDanger

Carbophenothion hazard class and category

GHS hazard classes Carbophenothion falls into
Hazard class Category From code Pictogram
Acute toxicity - oral GHS chapter 3.1 Category 3 H301 GHS06
Acute toxicity - dermal GHS chapter 3.1 Category 3 H311 GHS06
Hazardous to the aquatic environment - acute GHS chapter 4.1 Category 1 H400 GHS09
Hazardous to the aquatic environment - chronic GHS chapter 4.1 Category 1 H410 GHS09

Carbophenothion hazard statements (H-codes)

Hazard statements assigned to Carbophenothion
CodeHazard statement
H311 Toxic in contact with skin.
H301 Toxic if swallowed.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.

This page lists only the codes assigned to Carbophenothion. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for Carbophenothion

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of Carbophenothion issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

04 · Precautionary statements

Carbophenothion precautionary statements

CLP Annex VI assigns 10 precautionary statements to Carbophenothion. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Disposal

What has to happen to the contents and the empty container.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

Carbophenothion name in 23 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български карбофенотион (ISO) 4-хлорофенилтиометилов O, O -диетилов фосфородитиоат
Spanish español Carbofenotión (ISO) fosforoditioato de 4-clorofeniltiometilo y O, O -dietilo
Czech čeština karbofenothion (ISO) S -[(4-chlorfenyl)sulfanyl]methyl- O, O -diethyl-fosforodithioát
Danish dansk carbophenothion (ISO) 4-chlorphenylthiomethyl- O, O- diethyldithiophosphat
German Deutsch Carbophenothion (ISO) 4-Chlorphenylthiomethyl- O, O- diethylphosphorodithioat
Estonian eesti karbofenotioon (ISO) 4-klorofenüültiometüül- O , O -dietüülfosforoditioaat
Greek ελληνικά carbophenothion (καρβοφαινοθείο) (ISO) διθειοφωσφορικό 4-χλωροφαινυλοθειομεθύλιο O, O -διαιθύλιο
English English carbophenothion (ISO) 4-chlorophenylthiomethyl O, O -diethyl phosphorodithioate
French français carbophénothion (ISO) phosphorodithioate de 4-chlorophénylthiométhyle et de O, O -diéthyle
Croatian hrvatski karbofenotion (ISO) 4-klorfenil-tiometil- O, O -dietil-fosforoditioat
Italian italiano carbofenotion (ISO) ditiofosfato di 4-clorofeniltiometile e O, O-dietile
Latvian latviešu karbofenotions (ISO) 4-hlorfeniltiometil- O, O -dietilfosforditioāts
Lithuanian lietuvių karbofenotionas (ISO) 4-chlorfeniltiometil- O, O -dietilditiofosfatas
Hungarian magyar karbofenotion (ISO) 4-klórfeniltiometil- O, O - dietil-ditiofoszfát
Maltese Malti karbofenotijon (ISO) fosforoditijoat ta’ O, O -dietil ta’ 4-klorofeniltijometil
Dutch Nederlands carbofenothion (ISO) 4-chloorfenylthiomethyl- O , O -diëthyldithiofosfaat
Polish polski karbofenotion (ISO) ditiofosforan S-(4-chlorofenylosulfanylo)metylu- O, O -dietylu
Portuguese português carbofenotião (ISO) ditiofosfato de 4-clorofeniltiometilo e de O , O -dietilo
Romanian română carbofenotion (ISO) ditiofosfat de 4-clorofeniltiometil și de O, O -dietil
Slovak slovenčina karbofenotión (ISO) O, O -dietyl- S -{[(4- chlórfenyl)sulfanyl]metyl}-fosforoditioát
Slovenian slovenščina karbofenotion (ISO) 4-klorofeniltiometil O, O -dietil fosforoditioat
Finnish suomi karbofenotioni (ISO) 4-kloorifenyylitiometyyli- O, O -dietyylifosforoditioaatti
Swedish svenska karbofenotion (ISO) 4-klorfenyltiometyl)- O, O -dietylfosforditioat

All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

Carbophenothion GHS label elements

Everything CLP Annex VI fixes for Carbophenothion, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS06 Skull and crossbones pictogramGHS09 Environment pictogram

Danger

Carbophenothion

  • Toxic in contact with skin.
  • Toxic if swallowed.
  • Very toxic to aquatic life.
  • Very toxic to aquatic life with long lasting effects.
  • Do not eat, drink or smoke when using this product.
  • Avoid release to the environment.
  • Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/
  • IF SWALLOWED:
  • IF ON SKIN:
  • Immediately call a POISON CENTER/doctor/
  • Rinse mouth.
  • Wash with plenty of water/
  • Collect spillage.
  • Dispose of contents/container to

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open Carbophenothion in the GHS label constructor →

07 · Health hazards

Carbophenothion health hazards and exposure limits

Carbophenothion hazard summary

May be absorbed through skin; A cholinesterase inhibitor; [ICSC] In an epidemic involving 19 sugar cane workers, the route of exposure appeared to be inhalation or skin absorption (possibly both); Animal feeding studies showed depression of cholinesterase activity but no gross or microscopic pathology; [HSDB] A highly toxic cholinesterase inhibitor (estimated lethal oral dose of 0.6 g for 70 kg person); [CAMEO] Effects in a three-generation feeding study with rats at 20 ppm include reduced pup weight, increase in stillbirths, and fewer pups alive at weaning; Examination of stillborn pups was negative for teratogenicity; Effects in a 2 year feeding study with rats at the highest dose level (80 ppm) include an increase in adrenal weight; No increase in incidence of neoplasm was observed; [INCHEM JMPR] The average of two baseline respective cholinesterase activity determinations three days apart, with no exposures to enzyme inhibiting pesticides for at least 30 days, is recommended for each worker prior to exposure to cholinesterase inhibitors because of large inter-individual differences in published baseline values. To be established at least once a year. Removal from workplace exposures is recommended until the cholinesterase activity returns to within 20% of baseline. [TLVs and BEIs]

Source: Haz-Map, Information on Hazardous Chemicals and Occupational Diseases

08 · Physical and chemical properties

Carbophenothion properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

Carbophenothion boiling point

Property Value Conditions Source
Boiling point 82 °C (179.6 °F) at 0.01 mmHg (reduced pressure) HSDB
82.22 °C (180 °F) at 0.01 mmHg (reduced pressure) CAMEO
82 °C (179.6 °F) at 0.0097508 mmHg (reduced pressure) ICSC

Carbophenothion density

Property Value Conditions Source
Density 1.285 g/cm³ at 20 °C, TECHNICAL HSDB
1.271 g/cm³ at 25 °C HSDB

Carbophenothion solubility

Property Value Conditions Source
Solubility Miscible with vegetable oils and most org solvents HSDB
SOL IN KEROSENE, XYLENE, ALCOHOLS, KETONES, & ESTERS HSDB
In water, 0.63 mg/l @ 20 °C at 20 °C HSDB

Carbophenothion vapor pressure

Property Value Conditions Source
Vapor pressure 3e-7 mmHg at 20 °C HSDB

Carbophenothion vapor density

Property Value Conditions Source
Vapor density 11.8 (air = 1) ICSC

Carbophenothion corrosivity

Property Value Conditions Source
Corrosivity NON-CORROSIVE HSDB

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

09 · Handling and storage

Carbophenothion storage and handling

Carbophenothion safe storage

Provision to contain effluent from fire extinguishing. Separated from food and feedstuffs. Keep in a well-ventilated room.

Source: ILO-WHO International Chemical Safety Cards (ICSCs)

Carbophenothion reactivity

CARBOPHENOTHION is a halogenated organophosphate derivative. Organophosphates are susceptible to formation of highly toxic and flammable phosphine gas in the presence of strong reducing agents such as hydrides. Partial oxidation by oxidizing agents may result in the release of toxic phosphorus oxides.

Source: CAMEO Chemicals

Planning storage for a mix of chemicals? Check Carbophenothion in the storage compatibility matrix →

10 · Questions

Carbophenothion — frequently asked questions

What is the CAS number of Carbophenothion?

The CAS number of Carbophenothion is 786-19-6. Its EC number is 212-324-1.

What does a Carbophenothion label have to show?

Under CLP Annex VI the label for Carbophenothion carries the pictograms Skull and crossbones and Environment and the signal word is Danger.

Is Carbophenothion flammable?

CLP Annex VI assigns Carbophenothion no flammability hazard class. That is not a statement that it cannot burn: the harmonised list only records the hazards that were assessed for it.

Is Carbophenothion a carcinogen?

CLP Annex VI records no harmonised carcinogenicity classification for Carbophenothion. Annex VI is a list of agreed classifications, not a list of substances found safe, so this is an absence of a classification rather than a clean bill of health.

What is the boiling point of Carbophenothion?

The boiling point reported for Carbophenothion is 82 °C (179.6 °F), at 0.01 mmHg (reduced pressure) (HSDB).

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