Substance profile
Bendiocarb
Bendiocarb is a white powder and is odorless.
01 · Identification
What Bendiocarb is
Bendiocarb is a white powder and is odorless. Its molecular formula is C11H13NO4 and its molecular weight is 223.22 g/mol. It melts at 130 °C.
Under the GHS it carries the signal word Danger.
02 · Identifiers
Bendiocarb identifiers and molecular data
Bendiocarb CAS number and EC number
Bendiocarb molecular formula and molecular weight
Other names for Bendiocarb
- bendiocarb (ISO)
- 2,2-dimethyl-1,3-benzodioxol-4-yl N-methylcarbamate
- 2,2-dimethyl-1,3-benzodioxol-4-yl methylcarbamate
03 · GHS classification
Bendiocarb hazard classification
Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.
Bendiocarb pictograms and signal word
Bendiocarb hazard class and category
| Hazard class | Category | From code | Pictogram |
|---|---|---|---|
| Acute toxicity - oral GHS chapter 3.1 | Category 1 or 2 | H300 | GHS06 |
| Acute toxicity - dermal GHS chapter 3.1 | Category 3 | H311 | GHS06 |
| Acute toxicity - inhalation GHS chapter 3.1 | Category 3 | H331 | GHS06 |
| Hazardous to the aquatic environment - acute GHS chapter 4.1 | Category 1 | H400 | GHS09 |
| Hazardous to the aquatic environment - chronic GHS chapter 4.1 | Category 1 | H410 | GHS09 |
Where two values are shown with “or”, the hazard statement is shared by more than one category or by more than one class, and the code alone does not say which. H272, for example, belongs to oxidising liquids and to oxidising solids — the physical state decides. The binding answer for a specific entry is in the CLP Annex VI table itself.
Bendiocarb hazard statements (H-codes)
| Code | Hazard statement |
|---|---|
| H300 | Fatal if swallowed. |
| H331 | Toxic if inhaled. |
| H311 | Toxic in contact with skin. |
| H400 | Very toxic to aquatic life. |
| H410 | Very toxic to aquatic life with long lasting effects. |
This page lists only the codes assigned to Bendiocarb. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.
Safety Data Sheet
Getting an SDS for Bendiocarb
A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of Bendiocarb issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.
04 · Precautionary statements
Bendiocarb precautionary statements
CLP Annex VI assigns 13 precautionary statements to Bendiocarb. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.
Prevention
What to do before and during handling so the hazard never happens.
Response
What to do once exposure, spillage or fire has already happened.
Disposal
What has to happen to the contents and the empty container.
Reading the notation. … is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.
05 · Names in the regulation
Bendiocarb name in 23 EU languages
CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.
| Language | Name in CLP Annex VI Part 3 |
|---|---|
| Bulgarian български | бендиокарб (ISO) 2,2-диметил-1,3-бензодиоксол-4-илов N -метилкарбамат2,2-диметил-1,3-бензодиоксол-4-илов метилкарбамат |
| Spanish español | Bendiocarb (ISO) N-metilcarbamato de 2,2-dimetil-1,3-benzodioxol-4-ilometilcarbamato de 2,2-dimetil-1,3-benzodioxol-4-ilo |
| Czech čeština | bendiokarb (ISO) 2,2-dimethyl-1,3-benzodioxol-4-yl- N -methylkarbamát2,2-dimethyl-1,3-benzodioxol-4-yl-methylkarbamát |
| Danish dansk | bendiocarb (ISO) 2,2-dimethyl-1,3-benzodioxol-4-yl-N-methylcarbamat 2,2-dimethyl-1,3-benzodioxol-4-ylmethylcarbamat |
| German Deutsch | Bendiocarb (ISO) 2,2-Dimethyl-1,3-benzodioxol-4-yl- N -methylcarbamat2,2-Dimethyl-1,3-benzodioxol-4-yl-methylcarbamat |
| Estonian eesti | bendiokarb (ISO) 2,2-dimetüül-1,3-bensodioksool-4-üül- N -metüülkarbamaat2,2-dimetüül-1,3-bensodioksool-4-üül-metüülkarbamaat |
| Greek ελληνικά | bendiocarb (βενδιοκάρβη) (ISO) N-μεθυλοκαρβαμιδικό 2,2-διμεθυλο-1,3-βενζοδιοξολ-4-ύλιομεθυλοκαρβαμιδικό 2,2-διμεθυλο-1,3-βενζοδιοξολ-4-ύλιο |
| English English | bendiocarb (ISO) 2,2-dimethyl-1,3-benzodioxol-4-yl N-methylcarbamate2,2-dimethyl-1,3-benzodioxol-4-yl methylcarbamate |
| French français | bendiocarbe (ISO) N-méthylcarbamate de 2,2 diméthyl-1,3-benzodioxol-4-yleméthylcarbamate de 2,2 diméthyl-1,3-benzodioxol-4-yle |
| Croatian hrvatski | bendiokarb (ISO) 2,2-dimetil-1,3-benzodioksol-4-il N -metil-karbamat2,2-dimetil-1,3-benzodioksol-4-il metil-karbamat |
| Italian italiano | bendiocarb (ISO) N -metilcarbammato di 2,2-dimetil-1,3-benzodiossol-4-ilemetilcarbammato di 2,2-dimetil-1,3-benzodiossol-4-ile |
| Latvian latviešu | bendiokarbs (ISO) 2,2-dimetil-1,3-benzdioksol-4-il- N -metilkarbamāts2,2-dimetil-1,3-benzdioksol-4-ilmetilkarbamāts |
| Lithuanian lietuvių | bendiokarbas (ISO) 2,2-dimetil-1,3-benzodioksol-4-il N-metilkarbamatas2,2-dimetil-1,3-benzodioksol-4-il metilkarbamatas |
| Hungarian magyar | bendiokarb (ISO) 2,2-dimetil-1,3-benzodioxol-4-il- N -metilkarbamát2,2-dimetil-1,3-benzodioxol-4-il metilkarbamát |
| Maltese Malti | bendjokarb (ISO) 2,2-dimetil-1,3-benżodiossol-4-il metilkarbamat |
| Dutch Nederlands | bendiocarb (ISO) 2,2-dimethyl-1,3-benzodioxol-4-yl-N-methylcarbamaat2,2-dimethyl-1,3-benzodioxol-4-yl-methylcarbamaat |
| Polish polski | bendiokarb (ISO) metylokarbaminian 2,2-dimetylobenzo-1,3-dioksol-4-ilu |
| Portuguese português | Bendiocarbe (ISO) N -metilcarbamato de 2-2-dimetil-1,3-benzodioxol-4-ilometilcarbamato de 2-2-dimetil-1,3-benzodioxol-4-ilo |
| Romanian română | bendiocarb (ISO) 2,2-dimetil-1,3-benzodioxol-4-il N-metilcarbamat2,2-dimetil-1,3-benzodioxol-4-il metilcarbamat |
| Slovak slovenčina | bendiokarb (ISO) O -(2,2-dimetyl-1,3-benzodioxol-4-yl)- N -metylkarbamát(2,2-dimetyl-1,3-benzodioxol-4-yl)-metylkarbamát |
| Slovenian slovenščina | bendiokarb (ISO) 2,2-dimetil-1,3-benzodioksol-4-il N-metilkarbamat2,2-dimetil-1,3-benzodioksol-4-il metilkarbamat |
| Finnish suomi | bendiokarbi (ISO) 2,2-dimetyyli–bentsodioksol-4-yyli-N-metyylikarbamaatti2,2-dimetyyli-1,3-bentsodioksol-4-yylimetyylikarbamaatti |
| Swedish svenska | bendiocarb (ISO) 2,2-dimethyl-1,3-benzodioxol-4-yl N-methylcarbamate2,2-dimethyl-1,3-benzodioxol-4-yl methylcarbamate |
All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.
06 · Label elements
Bendiocarb GHS label elements
Everything CLP Annex VI fixes for Bendiocarb, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.
Danger
Bendiocarb
- Fatal if swallowed.
- Toxic if inhaled.
- Toxic in contact with skin.
- Very toxic to aquatic life.
- Very toxic to aquatic life with long lasting effects.
- Do not breathe dust/fume/gas/mist/vapours/spray.
- Do not eat, drink or smoke when using this product.
- Use only outdoors or in a well-ventilated area.
- Avoid release to the environment.
- Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/…
- IF SWALLOWED:
- IF ON SKIN:
- IF INHALED:
- Immediately call a POISON CENTER/doctor/…
- Rinse mouth.
- Wash with plenty of water/…
- Collect spillage.
- Dispose of contents/container to …
Supplier name, address and telephone number· Product identifier·Nominal quantity
Need this as an actual label? Open Bendiocarb in the GHS label constructor →
07 · Health hazards
Bendiocarb health hazards and exposure limits
Bendiocarb carcinogenicity classification
Cancer Classification: Group E Evidence of Non-carcinogenicity for Humans
Source: Hazardous Substances Data Bank (HSDB)
An IARC group and a CLP classification answer different questions. IARC judges whether the evidence for cancer in humans is strong enough; CLP Annex VI is the legally binding EU classification. A substance can carry one and not the other.
08 · Physical and chemical properties
Bendiocarb properties
Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.
Bendiocarb melting point
| Property | Value | Conditions | Source |
|---|---|---|---|
| Melting point | 129.6 °C (265.3 °F) | HSDB | |
| 129.44 °C (265 °F) | OSHA |
Bendiocarb density
| Property | Value | Conditions | Source |
|---|---|---|---|
| Density | 1.25 g/cm³ | at 20 °C | HSDB |
Bendiocarb solubility
| Property | Value | Conditions | Source |
|---|---|---|---|
| Solubility | 200 g/kg acetone; 100 g/kg dichloromethane; 200 g/kg dioxane; 40 g/kg benzene; 10 g/kg ethanol | HSDB | |
| 350 ppm in hexane | HSDB | ||
| In water, 260 mg/L at 25 °C | at 25 °C | HSDB |
Bendiocarb vapor pressure
| Property | Value | Conditions | Source |
|---|---|---|---|
| Vapor pressure | 0.000005 mmHg | OSHA | |
| 34500 mmHg | at 25 °C | HSDB | |
| 0.0000345 mmHg | Haz-Map |
Bendiocarb vapor density
| Property | Value | Conditions | Source |
|---|---|---|---|
| Vapor density | 1.25 (air = 1) | OSHA |
Bendiocarb corrosivity
| Property | Value | Conditions | Source |
|---|---|---|---|
| Corrosivity | Lack of corrosive properties | HSDB |
Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.
09 · Handling and storage
Bendiocarb storage and handling
Bendiocarb storage conditions
Do not store near food or feed. Remove or cover all food before application; protect food preparing equipment, surfaces, and eating utensils from contamination during application.
Source: Hazardous Substances Data Bank (HSDB)
Bendiocarb reactivity
BENDIOCARB is a carbamate ester. Carbamates are chemically similar to, but more reactive than amides. Like amides they form polymers such as polyurethane resins. Carbamates are incompatible with strong acids and bases, and especially incompatible with strong reducing agents such as hydrides. Flammable gaseous hydrogen is produced by the combination of active metals or nitrides with carbamates. Strongly oxidizing acids, peroxides, and hydroperoxides are incompatible with carbamates.
Source: CAMEO Chemicals
Planning storage for a mix of chemicals? Check Bendiocarb in the storage compatibility matrix →
10 · Questions
Bendiocarb — frequently asked questions
What is the CAS number of Bendiocarb?
The CAS number of Bendiocarb is 22781-23-3. Its EC number is 245-216-8.
What is the chemical formula of Bendiocarb?
The molecular formula of Bendiocarb is C11H13NO4 and its molecular weight is 223.22 g/mol.
What does a Bendiocarb label have to show?
Under CLP Annex VI the label for Bendiocarb carries the pictograms Skull and crossbones and Environment and the signal word is Danger.
Is Bendiocarb flammable?
CLP Annex VI assigns Bendiocarb no flammability hazard class. That is not a statement that it cannot burn: the harmonised list only records the hazards that were assessed for it.
Is Bendiocarb a carcinogen?
CLP Annex VI records no harmonised carcinogenicity classification for Bendiocarb. Annex VI is a list of agreed classifications, not a list of substances found safe, so this is an absence of a classification rather than a clean bill of health.
What is the melting point of Bendiocarb?
The melting point reported for Bendiocarb is 129.6 °C (265.3 °F) (HSDB).
How should Bendiocarb be stored?
Do not store near food or feed. Remove or cover all food before application; protect food preparing equipment, surfaces, and eating utensils from contamination during application. (Hazardous Substances Data Bank (HSDB))
Nearby
Substances next to Bendiocarb
Keep going: substances starting with B, or search the whole database by name, CAS number, pictogram or signal word.