Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

Lithium Bis(Trifluoromethanesulfonyl)Imide

Lithium Bis(Trifluoromethanesulfonyl)Imide: liquid.

CAS 90076-65-6 C2HF6LiNO4S2 288.1 g/mol Danger

01 · Identification

What Lithium Bis(Trifluoromethanesu… is

Lithium Bis(Trifluoromethanesulfonyl)Imide: liquid. Its molecular formula is C2HF6LiNO4S2 and its molecular weight is 288.1 g/mol.

Under the GHS it carries the signal word Danger.

02 · Identifiers

Lithium Bis(Trifluoromethanesu… identifiers and molecular data

Lithium Bis(Trifluoromethanesu… CAS number and EC number

CAS number90076-65-6
EC number415-300-0
Index number (CLP Annex VI)616-124-00-9

Lithium Bis(Trifluoromethanesu… molecular formula and molecular weight

Molecular formulaC2HF6LiNO4S2
Molecular weight288.1 g/mol

Other names for Lithium Bis(Trifluoromethanesu…

  • lithium bis(trifluoromethylsulfonyl)imide

03 · GHS classification

Lithium Bis(Trifluoromethanesu… hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

Lithium Bis(Trifluoromethanesu… pictograms and signal word

Signal wordDanger

Lithium Bis(Trifluoromethanesu… hazard class and category

GHS hazard classes Lithium Bis(Trifluorometha… falls into
Hazard class Category From code Pictogram
Acute toxicity - oral GHS chapter 3.1 Category 3 H301 GHS06
Acute toxicity - dermal GHS chapter 3.1 Category 3 H311 GHS06
Skin corrosion/irritation GHS chapter 3.2 Category 1A or 1B or 1C H314 GHS05
Specific target organ toxicity - repeated exposure GHS chapter 3.9 Category 2 H373 GHS08
Hazardous to the aquatic environment - chronic GHS chapter 4.1 Category 3 H412

Where two values are shown with “or”, the hazard statement is shared by more than one category or by more than one class, and the code alone does not say which. H272, for example, belongs to oxidising liquids and to oxidising solids — the physical state decides. The binding answer for a specific entry is in the CLP Annex VI table itself.

Lithium Bis(Trifluoromethanesu… hazard statements (H-codes)

Hazard statements assigned to Lithium Bis(Trifluorometha…
CodeHazard statement
H311 Toxic in contact with skin.
H301 Toxic if swallowed.
H373 May cause damage to organs <or state all organs affected, if known> through prolonged or repeated exposure <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
H314 Causes severe skin burns and eye damage.
H412 Harmful to aquatic life with long lasting effects.

This page lists only the codes assigned to Lithium Bis(Trifluorometha…. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for Lithium Bis(Trifluorometha…

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of Lithium Bis(Trifluorom… issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

04 · Precautionary statements

Lithium Bis(Trifluoromethanesu… precautionary statements

CLP Annex VI assigns 12 precautionary statements to Lithium Bis(Trifluorometha…. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Disposal

What has to happen to the contents and the empty container.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

Lithium Bis(Trifluoromethanesu… name in 23 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български литиев бис(трифлуорометилсулфонил)имид
Spanish español Bis(trifluorometilsulfonil)imida de litio
Czech čeština lithium-bis(trifluormethansulfonyl)imid
Danish dansk lithium-bis(trifluormethylsulfonyl)imid
German Deutsch Lithiumbis(trifluormethylsulfonyl)imid
Estonian eesti liitiumbis(trifluorometüülsulfonüül)imiid
Greek ελληνικά άλας του δις(τριφθoρoμεθυλoσoυλφoνυλ)ιμιδίου με λίθιο
English English lithium bis(trifluoromethylsulfonyl)imide
French français bis(trifluorométhylsulfonyl)imide de lithium
Croatian hrvatski litijev bis(trifluormetilsulfonil)imid
Italian italiano bis(trifluorometilsolfonil)immide di litio
Latvian latviešu litija bis(trifluormetilsulfonil)imīds
Lithuanian lietuvių ličio bis(trifluormetilsulfonil)imidas
Hungarian magyar lítium-bisz(trifluormetilszulfonil)imid
Maltese Malti litju bis(trifluworometilsulfonil)imide
Dutch Nederlands lithiumbis(trifluormethylsulfonyl)imide
Polish polski bis(trifluorometylosulfonylo)imid, sól litowa
Portuguese português bis(trifluorometilsulfonil)imida de lítio
Romanian română bis(trifluorometilsulfonil)-imidă de litiu
Slovak slovenčina bis(trifluórmetánsulfonyl)azanid lítny
Slovenian slovenščina litijev bis(trifluorometilsulfonil)imid
Finnish suomi litiumbis(trifluorimetyylisulfonyyli)imidi
Swedish svenska litiumbis(trifluormetylsulfonyl)imid

All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

Lithium Bis(Trifluoromethanesu… GHS label elements

Everything CLP Annex VI fixes for Lithium Bis(Trifluorometha…, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS06 Skull and crossbones pictogramGHS05 Corrosion pictogramGHS08 Health hazard pictogram

Danger

Lithium Bis(Trifluoromethanesu…

  • Toxic in contact with skin.
  • Toxic if swallowed.
  • May cause damage to organs <or state all organs affected, if known> through prolonged or repeated exposure <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
  • Causes severe skin burns and eye damage.
  • Harmful to aquatic life with long lasting effects.
  • Do not breathe dust/fume/gas/mist/vapours/spray.
  • Do not eat, drink or smoke when using this product.
  • Avoid release to the environment.
  • Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/
  • IF SWALLOWED:
  • IF ON SKIN:
  • Immediately call a POISON CENTER/doctor/
  • Get medical advice/attention if you feel unwell.
  • Rinse mouth.
  • Do NOT induce vomiting.
  • Wash with plenty of water/
  • Dispose of contents/container to

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open Lithium Bis(Trifluorometha… in the GHS label constructor →

07 · Health hazards

Lithium Bis(Trifluoromethanesu… health hazards and exposure limits

Lithium Bis(Trifluoromethanesu… hazard summary

Causes burns; [3M MSDS] See Lithium.

Source: Haz-Map, Information on Hazardous Chemicals and Occupational Diseases

08 · Questions

Lithium Bis(Trifluoromethanesu… — frequently asked questions

What is the CAS number of Lithium Bis(Trifluoromethanesu…?

The CAS number of Lithium Bis(Trifluoromethanesu… is 90076-65-6. Its EC number is 415-300-0.

What is the chemical formula of Lithium Bis(Trifluoromethanesu…?

The molecular formula of Lithium Bis(Trifluoromethanesu… is C2HF6LiNO4S2 and its molecular weight is 288.1 g/mol.

What does a Lithium Bis(Trifluoromethanesu… label have to show?

Under CLP Annex VI the label for Lithium Bis(Trifluoromethanesu… carries the pictograms Skull and crossbones, Corrosion and Health hazard and the signal word is Danger.

Is Lithium Bis(Trifluoromethanesu… flammable?

CLP Annex VI assigns Lithium Bis(Trifluoromethanesu… no flammability hazard class. That is not a statement that it cannot burn: the harmonised list only records the hazards that were assessed for it.

Is Lithium Bis(Trifluoromethanesu… a carcinogen?

CLP Annex VI records no harmonised carcinogenicity classification for Lithium Bis(Trifluoromethanesu…. Annex VI is a list of agreed classifications, not a list of substances found safe, so this is an absence of a classification rather than a clean bill of health.

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