Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

1,2-Benzisothiazol-3(2H)-one

1,2-Benzisothiazol-3(2H)-one is an off-white to yellowish solid.

CAS 2634-33-5 C7H5NOS 151.19 g/mol Danger

01 · Identification

What 1,2-Benzisothiazol-3(2H)-one is

1,2-Benzisothiazol-3(2H)-one is an off-white to yellowish solid. Its molecular formula is C7H5NOS and its molecular weight is 151.19 g/mol. It boils at 328 °C, melts at 157 °C.

Under the GHS it carries the signal word Danger.

02 · Identifiers

1,2-Benzisothiazol-3(2H)-one identifiers and molecular data

1,2-Benzisothiazol-3(2H)-one CAS number and EC number

CAS number2634-33-5
EC number220-120-9
Index number (CLP Annex VI)613-088-00-6

1,2-Benzisothiazol-3(2H)-one molecular formula and molecular weight

Molecular formulaC7H5NOS
Molecular weight151.19 g/mol

Other names for 1,2-Benzisothiazol-3(2H)-one

  • 1,2-benzisothiazolin-3-one

03 · GHS classification

1,2-Benzisothiazol-3(2H)-one hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

1,2-Benzisothiazol-3(2H)-one pictograms and signal word

Signal wordDanger

1,2-Benzisothiazol-3(2H)-one hazard class and category

GHS hazard classes 1,2-Benzisothiazol-3(2H)-o… falls into
Hazard class Category From code Pictogram
Acute toxicity - oral GHS chapter 3.1 Category 4 H302 GHS07
Acute toxicity - inhalation GHS chapter 3.1 Category 1 or 2 H330 GHS06
Skin corrosion/irritation GHS chapter 3.2 Category 2 H315 GHS07
Serious eye damage/eye irritation GHS chapter 3.3 Category 1 H318 GHS05
Skin sensitisation GHS chapter 3.4 Category 1 or 1A or 1B H317 GHS07
Hazardous to the aquatic environment - acute GHS chapter 4.1 Category 1 H400 GHS09
Hazardous to the aquatic environment - chronic GHS chapter 4.1 Category 1 H410 GHS09

Where two values are shown with “or”, the hazard statement is shared by more than one category or by more than one class, and the code alone does not say which. H272, for example, belongs to oxidising liquids and to oxidising solids — the physical state decides. The binding answer for a specific entry is in the CLP Annex VI table itself.

1,2-Benzisothiazol-3(2H)-one hazard statements (H-codes)

Hazard statements assigned to 1,2-Benzisothiazol-3(2H)-o…
CodeHazard statement
H330 Fatal if inhaled.
H302 Harmful if swallowed.
H315 Causes skin irritation.
H318 Causes serious eye damage.
H317 May cause an allergic skin reaction.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.

This page lists only the codes assigned to 1,2-Benzisothiazol-3(2H)-o…. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for 1,2-Benzisothiazol-3(2H)-o…

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of 1,2-Benzisothiazol-3(2… issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

04 · Precautionary statements

1,2-Benzisothiazol-3(2H)-one precautionary statements

CLP Annex VI assigns 22 precautionary statements to 1,2-Benzisothiazol-3(2H)-o…. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Disposal

What has to happen to the contents and the empty container.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

1,2-Benzisothiazol-3(2H)-one name in 23 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български 1,2-бензизотиазол-3(2 H )-он 1,2-бензизотиазолин-3-он
Spanish español 1,2-Bencisotiazol-3(2 H )-ona 1,2-bencisotiazolin-3-ona
Czech čeština 1,2-benzisothiazol-3(2 H )-on 1,2-benzisothiazolin-3-on
Danish dansk 1,2-benzisothiazol-3(2H)-on 1,2-benzisothiazolin-3-on
German Deutsch 1,2-Benzisothiazol-3(2H)-on 1,2-Benzisothiazolin-3-on
Estonian eesti 1,2-bensisotiasool-3(2 H )-oon 1,2-bensisotiasoliin-3-oon
Greek ελληνικά 1,2-βενζοϊσοθειαζολ-3(2H)-όνη 1,2-βενζοϊσοθειαζολιν-3-όνη
English English 1,2-benzisothiazol-3(2H)-one 1,2-benzisothiazolin-3-one
French français 1,2-benzisothiazol-3(2H)-one 1,2-benzisothiazolin-3-one
Croatian hrvatski 1,2-benzizotiazol-3(2 H )-on 1,2-benzizotiazolin-3-on
Italian italiano 1,2-benzisotiazol-3(2H)-one 1,2-benzisotiazolin-3-one
Latvian latviešu 1,2-benzizotiazol-3(2 H )-ons 1,2-benzizotiazolīn-3-ons
Lithuanian lietuvių 1,2-benzizotiazol-3(2H)-onas 1,2-benzizotiazolin-3-onas
Hungarian magyar 1,2-benzizotiazol-3(2H)-on 1,2-benzizotiazolin-3-on
Maltese Malti 1,2-benżisotijażol-3(2 H )-on 1,2-benzisotijażolin-3-on
Dutch Nederlands 1,2-benzisothiazool-3(2 H )-on 1,2-benzisothiazoline-3-on
Polish polski 1,2-benzoizotiazol-3(2H)-on 1,2-benzoizotiazolin-3-on
Portuguese português 1,2-benzisotiazol-3(2 H )-ona 1,2-benzisotiazolin-3-ona
Romanian română 1,2-benzizotiazol-3(2H)-onă 1,2-benzisotiazolin-3-onă
Slovak slovenčina 1,2-benzizotiazol-3(2 H )-ón 1,2-benzizotiazolín-3-ón
Slovenian slovenščina 1,2-benzizotiazol-3(2H)-on 1,2-benzizotiazolin-3-on
Finnish suomi 1,2-bentsisotiatsol-3(2H)-oni 1,2-bentsisotiatsolin-3-oni
Swedish svenska 1,2-bensisotiazol-3(2H)-on 1,2-bensisotiazolin-3-on

All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

1,2-Benzisothiazol-3(2H)-one GHS label elements

Everything CLP Annex VI fixes for 1,2-Benzisothiazol-3(2H)-o…, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS06 Skull and crossbones pictogramGHS05 Corrosion pictogramGHS09 Environment pictogram

Danger

1,2-Benzisothiazol-3(2H)-one

  • Fatal if inhaled.
  • Harmful if swallowed.
  • Causes skin irritation.
  • Causes serious eye damage.
  • May cause an allergic skin reaction.
  • Very toxic to aquatic life.
  • Very toxic to aquatic life with long lasting effects.
  • Do not breathe dust/fume/gas/mist/vapours/spray.
  • Avoid breathing dust/fume/gas/mist/vapours/spray.
  • Wash thoroughly after handling.
  • Do not eat, drink or smoke when using this product.
  • Use only outdoors or in a well-ventilated area.
  • Contaminated work clothing should not be allowed out of the workplace.
  • Avoid release to the environment.
  • Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/
  • IF SWALLOWED:
  • IF ON SKIN:
  • IF INHALED:
  • IF IN EYES:
  • Immediately call a POISON CENTER/doctor/
  • Call a POISON CENTER/doctor/ if you feel unwell.
  • Get medical advice/attention.
  • Rinse mouth.
  • If skin irritation occurs:
  • If skin irritation or rash occurs:
  • Remove contact lenses, if present and easy to do. Continue rinsing.
  • Wash with plenty of water/
  • Collect spillage.
  • Dispose of contents/container to

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open 1,2-Benzisothiazol-3(2H)-o… in the GHS label constructor →

07 · Health hazards

1,2-Benzisothiazol-3(2H)-one health hazards and exposure limits

1,2-Benzisothiazol-3(2H)-one hazard summary

Allergic contact dermatitis reported in workers using this preservative, mainly in manufacturing industries (paint, paper, rubber, and air fresheners); [Kanerva, p. 1755] Occupational asthma reported in a chemical worker; [Malo] See ISOTHIAZOLINONES.

Source: Haz-Map, Information on Hazardous Chemicals and Occupational Diseases

08 · Physical and chemical properties

1,2-Benzisothiazol-3(2H)-one properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

1,2-Benzisothiazol-3(2H)-one boiling point

Property Value Conditions Source
Boiling point 327.6 °C (621.7 °F) HSDB

1,2-Benzisothiazol-3(2H)-one melting point

Property Value Conditions Source
Melting point 156.6 °C (313.9 °F) HSDB
157.5 °C (315.5 °F) range, midpoint shown HMDB

1,2-Benzisothiazol-3(2H)-one density

Property Value Conditions Source
Density 1.483 g/cm³ at 20 °C HSDB

1,2-Benzisothiazol-3(2H)-one solubility

Property Value Conditions Source
Solubility In water, 1.1 g/L at 20 °C; 0.938 g/L at 20 °C and pH 4.8; 1.288 g/L at 20 deg and pH 6.7; 1.651 g/L at 20 °C at pH 9.1; 1.198 g/L at 30 °C pH 4.8 at 20 °C HSDB
21.7 [ug/mL] (The mean of the results at pH 7.4) Sanford-Burnham Center for Chemical Genomics

1,2-Benzisothiazol-3(2H)-one vapor pressure

Property Value Conditions Source
Vapor pressure 0.00000278 mmHg at 25 °C HSDB

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

09 · Handling and storage

1,2-Benzisothiazol-3(2H)-one storage and handling

1,2-Benzisothiazol-3(2H)-one storage conditions

Conditions for safe storage, including any incompatibilities: Keep container tightly closed in a dry and well-ventilated place. Storage class (TRGS 510): Non Combustible Solids.

Source: Hazardous Substances Data Bank (HSDB)

1,2-Benzisothiazol-3(2H)-one incompatible materials

Incompatible materials: Strong oxidizing agents.

Source: Hazardous Substances Data Bank (HSDB)

Planning storage for a mix of chemicals? Check 1,2-Benzisothiazol-3(2H)… in the storage compatibility matrix →

10 · Questions

1,2-Benzisothiazol-3(2H)-one — frequently asked questions

What is the CAS number of 1,2-Benzisothiazol-3(2H)-one?

The CAS number of 1,2-Benzisothiazol-3(2H)-one is 2634-33-5. Its EC number is 220-120-9.

What is the chemical formula of 1,2-Benzisothiazol-3(2H)-one?

The molecular formula of 1,2-Benzisothiazol-3(2H)-one is C7H5NOS and its molecular weight is 151.19 g/mol.

What does a 1,2-Benzisothiazol-3(2H)-one label have to show?

Under CLP Annex VI the label for 1,2-Benzisothiazol-3(2H)-one carries the pictograms Skull and crossbones, Corrosion and Environment and the signal word is Danger.

Is 1,2-Benzisothiazol-3(2H)-one flammable?

CLP Annex VI assigns 1,2-Benzisothiazol-3(2H)-one no flammability hazard class. That is not a statement that it cannot burn: the harmonised list only records the hazards that were assessed for it.

Is 1,2-Benzisothiazol-3(2H)-one a carcinogen?

CLP Annex VI records no harmonised carcinogenicity classification for 1,2-Benzisothiazol-3(2H)-one. Annex VI is a list of agreed classifications, not a list of substances found safe, so this is an absence of a classification rather than a clean bill of health.

What is the boiling point of 1,2-Benzisothiazol-3(2H)-one?

The boiling point reported for 1,2-Benzisothiazol-3(2H)-one is 327.6 °C (621.7 °F) (HSDB).

What is the melting point of 1,2-Benzisothiazol-3(2H)-one?

The melting point reported for 1,2-Benzisothiazol-3(2H)-one is 156.6 °C (313.9 °F) (HSDB).

How should 1,2-Benzisothiazol-3(2H)-one be stored?

Conditions for safe storage, including any incompatibilities: Keep container tightly closed in a dry and well-ventilated place. Storage class (TRGS 510): Non Combustible Solids. (Hazardous Substances Data Bank (HSDB))

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