Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

1,2-bis(2-methoxyethoxy)ethane

1,2-bis(2-methoxyethoxy)ethane: triethylene glycol dimethyl ether is a clear colorless liquid with a mild ethereal odor.

CAS 112-49-2 C8H18O4 178.23 g/mol Danger

01 · Identification

What 1,2-bis(2-methoxyethoxy)ethane is

1,2-bis(2-methoxyethoxy)ethane: triethylene glycol dimethyl ether is a clear colorless liquid with a mild ethereal odor. Its molecular formula is C8H18O4 and its molecular weight is 178.23 g/mol. It boils at 216 °C, melts at -45 °C.

Under the GHS it carries the signal word Danger.

02 · Identifiers

1,2-bis(2-methoxyethoxy)ethane identifiers and molecular data

1,2-bis(2-methoxyethoxy)ethane CAS number and EC number

CAS number112-49-2
EC number203-977-3
Index number (CLP Annex VI)603-176-00-2

1,2-bis(2-methoxyethoxy)ethane molecular formula and molecular weight

Molecular formulaC8H18O4
Molecular weight178.23 g/mol

Other names for 1,2-bis(2-methoxyethoxy)ethane

  • TEGDME
  • triethylene glycol dimethyl ether
  • triglyme

03 · GHS classification

1,2-bis(2-methoxyethoxy)ethane hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

1,2-bis(2-methoxyethoxy)ethane pictograms and signal word

Signal wordDanger

1,2-bis(2-methoxyethoxy)ethane hazard statements (H-codes)

Hazard statements assigned to 1,2-bis(2-methoxyethoxy)et…
CodeHazard statement
H360Df May damage the unborn child. Suspected of damaging fertility.

1,2-bis(2-methoxyethoxy)ethane supplemental EU statements (EUH)

EU-specific statements assigned to 1,2-bis(2-methoxyethoxy)et…. They exist only in CLP and have no counterpart in UN GHS.
CodeStatement
EUH019 May form explosive peroxides.

This page lists only the codes assigned to 1,2-bis(2-methoxyethoxy)et…. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for 1,2-bis(2-methoxyethoxy)et…

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of 1,2-bis(2-methoxyethox… issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

04 · Precautionary statements

1,2-bis(2-methoxyethoxy)ethane precautionary statements

CLP Annex VI assigns 4 precautionary statements to 1,2-bis(2-methoxyethoxy)et…. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Response

What to do once exposure, spillage or fire has already happened.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

1,2-bis(2-methoxyethoxy)ethane name in 23 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български 1,2-бис(2-метоксиетокси)етан TEGDMEдиметилов етер на триетиленгликолатриглим
Spanish español 1,2-Bis(2-metoxietoxi)etano TEGDMEéter dimetílico de trietilenglicoltriglimo
Czech čeština 1,2-bis(2-methoxyethoxy)ethan TEGDMEtriethylenglykoldimethylethertriglym
Danish dansk 1,2-bis(2-methoxyethoxy)ethan TEGDMEtriethylenglycoldimethylethertriglym
German Deutsch 1,2-Bis(2-methoxyethoxy)ethan TEGDMETriethylenglycoldimethyletherTriglyme
Estonian eesti 1,2-bis(2-metoksüetoksü)etaan TEGDMEtrietüleenglükooli dimetüüleetertriglüüm
Greek ελληνικά 1,2-δις(2-μεθοξυαιθοξυ)αιθάνιο TEGDMEτριαιθυλενογλυκολοδιμεθυλαιθέραςτριγλύμη
English English 1,2-bis(2-methoxyethoxy)ethane TEGDMEtriethylene glycol dimethyl ethertriglyme
French français 1,2-bis(2-méthoxyéthoxy)éthane TEGDMEéther diméthylique du triéthylène glycoltriglyme
Croatian hrvatski 1,2-bis(2-metoksietoksi)etan TEGDMEtrietilen-glikol-dimetil-etertriglim
Italian italiano 1,2-bis(2-metossietossi)etano TEGDMEtrietilenglicol dimetileteretriglyme
Latvian latviešu 1,2-bis(2-metoksietoksi)etāns TEGDMEtrietilēnglikola dimetilēteristriglīms
Lithuanian lietuvių 1,2-bis(2-metoksietoksi)etanas TEGDMEtrietilenglikolio dimetileteristriglimas
Hungarian magyar 1,2-bisz(2-metoxietoxi)etán TEGDMEtrietilén-glikol-dimetil-étertriglim
Maltese Malti 1,2-bis(2-metossietossi)etan TEGDME eter tad-dimetil tal-glikol tat-trietilentriglim
Dutch Nederlands 1,2-bis(2-methoxyethoxy)ethaan TEGDMEtriëthyleenglycoldimethylethertriglyme
Polish polski 1,2-bis(2-metoksyetoksy)etan TEGDMEeter dimetylowy glikolu trietylenowego
Portuguese português 1,2-bis(2-metoxietoxi)etano TEGDMEéter dimetílico de trietilenoglicoltriglima
Romanian română 1,2-bis(2-metoxietoxi)etan TEGDMEeter dimetilic al trietilen-glicoluluitriglim
Slovak slovenčina 1,2-bis(2-metoxyetoxy)etán TEGDMEtrietylénglykol-dimetylétertriglym
Slovenian slovenščina 1,2-bis(2-metoksietoksi)etan TEGDMEtrietilen glikol dimetil etertriglim
Finnish suomi 1,2-bis(2-metoksietoksi)etaani tegdmetrietyleeniglykolin dimetyylieetteritriglyymi
Swedish svenska 1,2-bis(2-metoxietoxi)etan TEGDMEtrietylenglykoldimetyletertriglym

All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

1,2-bis(2-methoxyethoxy)ethane GHS label elements

Everything CLP Annex VI fixes for 1,2-bis(2-methoxyethoxy)et…, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS08 Health hazard pictogram

Danger

1,2-bis(2-methoxyethoxy)ethane

  • May damage the unborn child. Suspected of damaging fertility.
  • May form explosive peroxides.
  • Obtain special instructions before use.
  • Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/
  • IF exposed or concerned:
  • Get medical advice/attention.

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open 1,2-bis(2-methoxyethoxy)et… in the GHS label constructor →

07 · Health hazards

1,2-bis(2-methoxyethoxy)ethane health hazards and exposure limits

1,2-bis(2-methoxyethoxy)ethane hazard summary

May have adverse effects on human reproduction, based on animal studies; [ICSC] Labeled as May impair fertility and May cause harm to the unborn child by EU regulations; [Glycol Ethers Online] Prolonged contact with air can form explosive peroxides; [CAMEO] A skin and eye irritant; [NTP] May form explosive peroxides; An irritant; May cause impaired fertility and fetal toxicity; [Alfa Aesar MSDS] See Monoglyme.

Source: Haz-Map, Information on Hazardous Chemicals and Occupational Diseases

08 · Physical and chemical properties

1,2-bis(2-methoxyethoxy)ethane properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

1,2-bis(2-methoxyethoxy)ethane boiling point

Property Value Conditions Source
Boiling point 216.11 °C (421 °F) at 760 mmHg CAMEO
216 °C (420.8 °F) ICSC
216 °C (420.8 °F) at 760 mmHg DOE PAC

1,2-bis(2-methoxyethoxy)ethane melting point

Property Value Conditions Source
Melting point -45 °C (-49 °F) CAMEO

1,2-bis(2-methoxyethoxy)ethane density

Property Value Conditions Source
Density 0.99 g/cm³ ICSC
0.99 g/cm³ at 20 °C CAMEO
0.986 g/cm³ at 25 °C DOE PAC

1,2-bis(2-methoxyethoxy)ethane solubility

Property Value Conditions Source
Solubility Solubility in water: miscible ICSC
greater than or equal to 100 mg/mL at 70 °F (NTP, 1992) at 21.11 °C CAMEO

1,2-bis(2-methoxyethoxy)ethane vapor pressure

Property Value Conditions Source
Vapor pressure 0.9 mmHg at 20 °C CAMEO
0.9001 mmHg at 20 °C ICSC
0.04 mmHg Haz-Map

1,2-bis(2-methoxyethoxy)ethane flash point

Property Value Conditions Source
Flash point 111.11 °C (232 °F) CAMEO
111 °C (231.8 °F) ICSC

1,2-bis(2-methoxyethoxy)ethane autoignition temperature

Property Value Conditions Source
Autoignition temperature 630 °C (1166 °F) CAMEO

1,2-bis(2-methoxyethoxy)ethane vapor density

Property Value Conditions Source
Vapor density 4.7 (air = 1) CAMEO
6.14 (air = 1) ICSC

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

09 · Handling and storage

1,2-bis(2-methoxyethoxy)ethane storage and handling

1,2-bis(2-methoxyethoxy)ethane safe storage

Separated from strong oxidants.

Source: ILO-WHO International Chemical Safety Cards (ICSCs)

1,2-bis(2-methoxyethoxy)ethane reactivity

TRIETHYLENE GLYCOL DIMETHYL ETHER forms explosive peroxides on prolonged exposure to air. Its decomposition products may be sensitive to shock. The bulk chemical is stable for 2 weeks at temperatures up to 140 °F when protected from light. This chemical is incompatible with strong oxidizers. It is also incompatible with strong acids. It may react with peroxides, oxygen, nitric acid and sulfuric acid. (NTP, 1992).

Source: CAMEO Chemicals

Planning storage for a mix of chemicals? Check 1,2-bis(2-methoxyethoxy)e… in the storage compatibility matrix →

10 · Questions

1,2-bis(2-methoxyethoxy)ethane — frequently asked questions

What is the CAS number of 1,2-bis(2-methoxyethoxy)ethane?

The CAS number of 1,2-bis(2-methoxyethoxy)ethane is 112-49-2. Its EC number is 203-977-3.

What is the chemical formula of 1,2-bis(2-methoxyethoxy)ethane?

The molecular formula of 1,2-bis(2-methoxyethoxy)ethane is C8H18O4 and its molecular weight is 178.23 g/mol.

What does a 1,2-bis(2-methoxyethoxy)ethane label have to show?

Under CLP Annex VI the label for 1,2-bis(2-methoxyethoxy)ethane carries the pictogram Health hazard and the signal word is Danger.

Is 1,2-bis(2-methoxyethoxy)ethane flammable?

CLP Annex VI assigns 1,2-bis(2-methoxyethoxy)ethane no flammability hazard class. That is not a statement that it cannot burn: the harmonised list only records the hazards that were assessed for it. The flash point reported for it is 111.11 °C (232 °F) (CAMEO).

Is 1,2-bis(2-methoxyethoxy)ethane a carcinogen?

CLP Annex VI records no harmonised carcinogenicity classification for 1,2-bis(2-methoxyethoxy)ethane. Annex VI is a list of agreed classifications, not a list of substances found safe, so this is an absence of a classification rather than a clean bill of health.

What is the boiling point of 1,2-bis(2-methoxyethoxy)ethane?

The boiling point reported for 1,2-bis(2-methoxyethoxy)ethane is 216.11 °C (421 °F), at 760 mmHg (CAMEO).

What is the melting point of 1,2-bis(2-methoxyethoxy)ethane?

The melting point reported for 1,2-bis(2-methoxyethoxy)ethane is -45 °C (-49 °F) (CAMEO).

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