Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

2,2-dibromo-2-cyanoacetamide

2,2-dibromo-2-cyanoacetamide is a white to "off white" crystalline solid with a mild "medicinal antiseptic" odor.

CAS 10222-01-2 Danger

01 · Identification

What 2,2-dibromo-2-cyanoacetamide is

2,2-dibromo-2-cyanoacetamide is a white to "off white" crystalline solid with a mild "medicinal antiseptic" odor. It boils at 190 °C, melts at 125 °C.

Under the GHS it carries the signal word Danger.

02 · Identifiers

2,2-dibromo-2-cyanoacetamide identifiers and molecular data

2,2-dibromo-2-cyanoacetamide CAS number and EC number

CAS number10222-01-2
EC number233-539-7
Index number (CLP Annex VI)607-747-00-7

Other names for 2,2-dibromo-2-cyanoacetamide

  • [DBNPA]

03 · GHS classification

2,2-dibromo-2-cyanoacetamide hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

2,2-dibromo-2-cyanoacetamide pictograms and signal word

Signal wordDanger

2,2-dibromo-2-cyanoacetamide hazard class and category

GHS hazard classes 2,2-dibromo-2-cyanoacetami… falls into
Hazard class Category From code Pictogram
Acute toxicity - oral GHS chapter 3.1 Category 3 H301 GHS06
Acute toxicity - inhalation GHS chapter 3.1 Category 1 or 2 H330 GHS06
Skin corrosion/irritation GHS chapter 3.2 Category 2 H315 GHS07
Serious eye damage/eye irritation GHS chapter 3.3 Category 1 H318 GHS05
Skin sensitisation GHS chapter 3.4 Category 1 or 1A or 1B H317 GHS07
Specific target organ toxicity - repeated exposure GHS chapter 3.9 Category 1 H372 GHS08
Hazardous to the aquatic environment - acute GHS chapter 4.1 Category 1 H400 GHS09
Hazardous to the aquatic environment - chronic GHS chapter 4.1 Category 1 H410 GHS09

Where two values are shown with “or”, the hazard statement is shared by more than one category or by more than one class, and the code alone does not say which. H272, for example, belongs to oxidising liquids and to oxidising solids — the physical state decides. The binding answer for a specific entry is in the CLP Annex VI table itself.

2,2-dibromo-2-cyanoacetamide hazard statements (H-codes)

Hazard statements assigned to 2,2-dibromo-2-cyanoacetami…
CodeHazard statement
H330 Fatal if inhaled.
H301 Toxic if swallowed.
H372 Causes damage to organs <or state all organs affected, if known> through prolonged or repeated exposure <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
H315 Causes skin irritation.
H318 Causes serious eye damage.
H317 May cause an allergic skin reaction.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.

This page lists only the codes assigned to 2,2-dibromo-2-cyanoacetami…. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for 2,2-dibromo-2-cyanoacetami…

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of 2,2-dibromo-2-cyanoace… issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

04 · Precautionary statements

2,2-dibromo-2-cyanoacetamide precautionary statements

CLP Annex VI assigns 22 precautionary statements to 2,2-dibromo-2-cyanoacetami…. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Disposal

What has to happen to the contents and the empty container.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

2,2-dibromo-2-cyanoacetamide name in 23 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български 2,2-дибромо-2-цианоацетамид
Spanish español 2,2-Dibromo-2-cianoacetamida
Czech čeština 2,2-dibrom-2-kyanoacetamid
Danish dansk 2,2-dibrom-2-cyanacetamid
German Deutsch 2,2-Dibrom-2-cyanacetamid
Estonian eesti 2,2-dibromo-2-tsüanoatseetamiid (DBNPA)
Greek ελληνικά 2,2-διβρωμο-2-κυανακεταμίδιο
English English 2,2-dibromo-2-cyanoacetamide
French français 2,2-dibromo-2-cyanoacétamide
Croatian hrvatski 2,2-dibromo-2-cianoacetamid
Italian italiano 2,2-dibromo-2-cianoacetammide
Latvian latviešu 2,2-dibrom-2-ciānacetamīds
Lithuanian lietuvių 2,2-dibrom-2-cianacetamidas
Hungarian magyar 2,2-dibróm-2-cianoacetamid
Maltese Malti 2,2-dibromo-2-ċjanoaċetammid
Dutch Nederlands 2,2-dibroom-2-cyaanaceetamide
Polish polski 2,2-dibromo-2-cyjanoacetamid
Portuguese português 2,2-dibromo-2-cianoacetamida
Romanian română 2,2-dibromo-2-cianoacetamidă
Slovak slovenčina 2,2-dibróm-2-kyanoacetamid
Slovenian slovenščina 2,2-dibromo-2-cianoacetamid
Finnish suomi 2,2-dibromi-2-syaaniasetamidi
Swedish svenska 2,2-dibrom-2-cyanoacetamid

All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

2,2-dibromo-2-cyanoacetamide GHS label elements

Everything CLP Annex VI fixes for 2,2-dibromo-2-cyanoacetami…, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS06 Skull and crossbones pictogramGHS08 Health hazard pictogramGHS05 Corrosion pictogramGHS09 Environment pictogram

Danger

2,2-dibromo-2-cyanoacetamide

  • Fatal if inhaled.
  • Toxic if swallowed.
  • Causes damage to organs <or state all organs affected, if known> through prolonged or repeated exposure <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
  • Causes skin irritation.
  • Causes serious eye damage.
  • May cause an allergic skin reaction.
  • Very toxic to aquatic life.
  • Very toxic to aquatic life with long lasting effects.
  • Do not breathe dust/fume/gas/mist/vapours/spray.
  • Avoid breathing dust/fume/gas/mist/vapours/spray.
  • Wash thoroughly after handling.
  • Do not eat, drink or smoke when using this product.
  • Use only outdoors or in a well-ventilated area.
  • Contaminated work clothing should not be allowed out of the workplace.
  • Avoid release to the environment.
  • Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/
  • IF SWALLOWED:
  • IF ON SKIN:
  • IF INHALED:
  • IF IN EYES:
  • Immediately call a POISON CENTER/doctor/
  • Get medical advice/attention.
  • Get medical advice/attention if you feel unwell.
  • Rinse mouth.
  • If skin irritation occurs:
  • If skin irritation or rash occurs:
  • Remove contact lenses, if present and easy to do. Continue rinsing.
  • Wash with plenty of water/
  • Collect spillage.
  • Dispose of contents/container to

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open 2,2-dibromo-2-cyanoacetami… in the GHS label constructor →

07 · Health hazards

2,2-dibromo-2-cyanoacetamide health hazards and exposure limits

2,2-dibromo-2-cyanoacetamide hazard summary

Poisonous by ingestion or IV route; A strong skin and eye irritant; Emits bromine and nitrogen oxides when heated; [Sax] Several human incidents reported to EPA after spills or misuse: eye, nose, throat, and respiratory tract irritation; [HSDB] DBNPA is a skin sensitizer; It is teratogenic in rabbits; It may cause eye and respiratory tract irritation; [EPA REDs] Danger of skin sensitization; [MAK] A corrosive substance that can cause injury to the skin, eyes, and respiratory tract; Inhalation may cause chemical pneumonitis and pulmonary edema; May cause skin sensitization; [MSDSonline]

Source: Haz-Map, Information on Hazardous Chemicals and Occupational Diseases

08 · Physical and chemical properties

2,2-dibromo-2-cyanoacetamide properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

2,2-dibromo-2-cyanoacetamide boiling point

Property Value Conditions Source
Boiling point 190 °C (374 °F) decomposes HSDB

2,2-dibromo-2-cyanoacetamide melting point

Property Value Conditions Source
Melting point 124.5 °C (256.1 °F) range, midpoint shown HSDB
126 °C (258.8 °F) HMDB

2,2-dibromo-2-cyanoacetamide solubility

Property Value Conditions Source
Solubility In water, 1.5 g/100 mL (15,000 mg/L) HSDB
In acetone, 35 g/100 mL; in ethanol, 25 g/100mL HSDB
0.82 mg/L @ 25 °C (exp) at 25 °C HMDB

2,2-dibromo-2-cyanoacetamide vapor pressure

Property Value Conditions Source
Vapor pressure 0.0009 mmHg at 25 °C HSDB
0.0009 mmHg Haz-Map

2,2-dibromo-2-cyanoacetamide lower explosive limit (LEL)

Property Value Conditions Source
Lower explosive limit (LEL) Non-explosive, non-combustible. HSDB

2,2-dibromo-2-cyanoacetamide corrosivity

Property Value Conditions Source
Corrosivity Corrosive to mild steel, iron and aluminum HSDB

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

09 · Handling and storage

2,2-dibromo-2-cyanoacetamide storage and handling

2,2-dibromo-2-cyanoacetamide incompatible materials

Incompatible with bases, reducing substances & nucleophiles.

Source: Hazardous Substances Data Bank (HSDB)

2,2-dibromo-2-cyanoacetamide reactivity

2,2-DIBROMO-3-NITRILOPROPIONAMIDE is incompatible with bases, metals, oxidizing agents, acids. Dangerous gases may accumulate as a result of ignition and fire.

Source: CAMEO Chemicals

Planning storage for a mix of chemicals? Check 2,2-dibromo-2-cyanoacetam… in the storage compatibility matrix →

10 · Questions

2,2-dibromo-2-cyanoacetamide — frequently asked questions

What is the CAS number of 2,2-dibromo-2-cyanoacetamide?

The CAS number of 2,2-dibromo-2-cyanoacetamide is 10222-01-2. Its EC number is 233-539-7.

What does a 2,2-dibromo-2-cyanoacetamide label have to show?

Under CLP Annex VI the label for 2,2-dibromo-2-cyanoacetamide carries the pictograms Skull and crossbones, Health hazard, Corrosion and Environment and the signal word is Danger.

Is 2,2-dibromo-2-cyanoacetamide flammable?

CLP Annex VI assigns 2,2-dibromo-2-cyanoacetamide no flammability hazard class. That is not a statement that it cannot burn: the harmonised list only records the hazards that were assessed for it.

Is 2,2-dibromo-2-cyanoacetamide a carcinogen?

CLP Annex VI records no harmonised carcinogenicity classification for 2,2-dibromo-2-cyanoacetamide. Annex VI is a list of agreed classifications, not a list of substances found safe, so this is an absence of a classification rather than a clean bill of health.

What is the boiling point of 2,2-dibromo-2-cyanoacetamide?

The boiling point reported for 2,2-dibromo-2-cyanoacetamide is 190 °C (374 °F), decomposes (HSDB).

What is the melting point of 2,2-dibromo-2-cyanoacetamide?

The melting point reported for 2,2-dibromo-2-cyanoacetamide is 124.5 °C (256.1 °F), range, midpoint shown (HSDB).

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