Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

2-aminopropane

2-aminopropane is a colorless liquid with an ammonia odor.

CAS 75-31-0 C3H9N 59.11 g/mol Danger

01 · Identification

What 2-aminopropane is

2-aminopropane is a colorless liquid with an ammonia odor. Its molecular formula is C3H9N and its molecular weight is 59.11 g/mol. It boils at 31.8 °C, melts at -95.1 °C.

Under the GHS it carries the signal word Danger. It is classed as flammable agents - 4th degree.

02 · Identifiers

2-aminopropane identifiers and molecular data

2-aminopropane CAS number and EC number

CAS number75-31-0
EC number200-860-9
Index number (CLP Annex VI)612-007-00-1

2-aminopropane molecular formula and molecular weight

Molecular formulaC3H9N
Molecular weight59.11 g/mol
Chemical class Flammable agents - 4th degree

Other names for 2-aminopropane

  • isopropylamine

03 · GHS classification

2-aminopropane hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

2-aminopropane pictograms and signal word

Signal wordDanger

2-aminopropane hazard class and category

GHS hazard classes 2-aminopropane falls into
Hazard class Category From code Pictogram
Flammable liquids GHS chapter 2.6 Category 1 H224 GHS02
Skin corrosion/irritation GHS chapter 3.2 Category 2 H315 GHS07
Serious eye damage/eye irritation GHS chapter 3.3 Category 2A H319 GHS07
Specific target organ toxicity - single exposure GHS chapter 3.8 Category 3 H335 GHS07

2-aminopropane hazard statements (H-codes)

Hazard statements assigned to 2-aminopropane
CodeHazard statement
H224 Extremely flammable liquid and vapour.
H335 May cause respiratory irritation.
H315 Causes skin irritation.
H319 Causes serious eye irritation.

This page lists only the codes assigned to 2-aminopropane. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for 2-aminopropane

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of 2-aminopropane issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

04 · Precautionary statements

2-aminopropane precautionary statements

CLP Annex VI assigns 14 precautionary statements to 2-aminopropane. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Storage

How the container has to be kept between uses.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

2-aminopropane name in 23 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български 2-аминопропан изопропиламин
Spanish español 2-Aminopropano isopropilamina
Czech čeština 2-aminopropan isopropylamin
Danish dansk 2-propanamin isopropylamin
German Deutsch 2-Aminopropan Isopropylamin
Estonian eesti 2-aminopropaan isopropüülamiin
Greek ελληνικά 2-αμινοπροπάνιο ισοπρoπυλαμίνη
English English 2-aminopropane isopropylamine
French français 2-aminopropane isopropylamine
Croatian hrvatski 2-aminopropan izopropilamin
Italian italiano 2-amino-propano isopropilamina
Latvian latviešu 2-aminopropāns izopropilamīns
Lithuanian lietuvių 2-aminopropanas izopropilaminas
Hungarian magyar 2-aminopropán izopropilamin
Maltese Malti 2-amminopropan isopropilammina
Dutch Nederlands 2-aminopropaan isopropylamine
Polish polski propano-2-amina izopropyloamina
Portuguese português 2-aminopropano isopropilamina
Romanian română 2-aminopropan izopropilamină
Slovak slovenčina propán-2-amín izopropylamín
Slovenian slovenščina 2-aminopropan izopropilamin
Finnish suomi isopropyyliamiini 2-aminopropaani
Swedish svenska 2-aminopropan isopropylamin

All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

2-aminopropane GHS label elements

Everything CLP Annex VI fixes for 2-aminopropane, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS02 Flame pictogramGHS07 Exclamation mark pictogram

Danger

2-aminopropane

  • Extremely flammable liquid and vapour.
  • May cause respiratory irritation.
  • Causes skin irritation.
  • Causes serious eye irritation.
  • Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
  • Keep container tightly closed.
  • Use explosion-proof [electrical/ventilating/lighting/…] equipment.
  • Use only non-sparking tools.
  • Wash thoroughly after handling.
  • Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/
  • IF ON SKIN:
  • IF IN EYES:
  • Get medical advice/attention.
  • If skin irritation occurs:
  • If eye irritation persists:
  • Remove contact lenses, if present and easy to do. Continue rinsing.
  • Wash with plenty of water/
  • Store in a well-ventilated place.

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open 2-aminopropane in the GHS label constructor →

07 · Health hazards

2-aminopropane health hazards and exposure limits

2-aminopropane occupational exposure limits

US occupational exposure limits reported for 2-aminopropane. PEL is enforceable (OSHA), REL is a recommendation (NIOSH), IDLH is the concentration at which escape becomes impossible without injury.
Limit Value Source
PEL 5.0 [ppm] Haz-Map, Information on Hazardous Chemicals and Occupational Diseases
PEL 5 ppm (12 mg/m³) Occupational Safety and Health Administration (OSHA)
PEL TWA 5 ppm (12 mg/m3) See Appendix G The National Institute for Occupational Safety and Health (NIOSH)
IDLH 750 ppm (NIOSH, 2024) CAMEO Chemicals
IDLH 750.0 [ppm] Haz-Map, Information on Hazardous Chemicals and Occupational Diseases
IDLH 750 ppm Hazardous Substances Data Bank (HSDB)

These are United States values. The European Union sets its own indicative and binding limits, and the figure that applies at a given workplace is the one in the local regulation — not the one shown here.

08 · Physical and chemical properties

2-aminopropane properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

2-aminopropane boiling point

Property Value Conditions Source
Boiling point 31.8 °C (89.2 °F) HSDB
32.78 °C (91 °F) NIOSH
32.39 °C (90.3 °F) at 760 mmHg CAMEO

2-aminopropane melting point

Property Value Conditions Source
Melting point -95.12 °C (-139.2 °F) HSDB
-101.11 °C (-150 °F) NIOSH

2-aminopropane density

Property Value Conditions Source
Density 0.69 g/cm³ NIOSH
0.6891 g/cm³ at 20 °C HSDB
0.683 g/cm³ at 20 °C HSDB

2-aminopropane solubility

Property Value Conditions Source
Solubility Miscible with water HSDB
Miscible with ethanol, ether; very soluble in acetone; soluble in benzene, chloroform HSDB
In water, 1X10+6 mg/L at 20 °C at 20 °C, miscible HSDB

2-aminopropane vapor pressure

Property Value Conditions Source
Vapor pressure 460 mmHg NIOSH
940.94 mmHg CAMEO
579.6 mmHg at 25 °C HSDB

2-aminopropane flash point

Property Value Conditions Source
Flash point -18 °C (-0.4 °F) HSDB
-37.22 °C (-35 °F) HSDB

2-aminopropane autoignition temperature

Property Value Conditions Source
Autoignition temperature 402.22 °C (756 °F) HSDB
355 °C (671 °F) ICSC

2-aminopropane lower explosive limit (LEL)

Property Value Conditions Source
Lower explosive limit (LEL) 2 % by volume HSDB

2-aminopropane upper explosive limit (UEL)

Property Value Conditions Source
Upper explosive limit (UEL) 10.4 % by volume HSDB

2-aminopropane vapor density

Property Value Conditions Source
Vapor density 2.04 (air = 1) HSDB
2 (air = 1) ICSC

2-aminopropane odor threshold

Property Value Conditions Source
Odor threshold 0.504 mg/cu m (Odor low) 480 mg/cu m (Odor high) HSDB
Odor Threshold Low: 0.21 [ppm] Haz-Map
Odor Threshold High: 0.7 [ppm] Haz-Map

2-aminopropane critical temperature and pressure

Property Value Conditions Source
Critical temperature and pressure 199.05 °C (390.3 °F) HSDB

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

09 · Fire and explosion

2-aminopropane fire and explosion behaviour

These are descriptions rather than measured values, so they are kept out of the table above and quoted here with the source that reported them.

2-aminopropane fire potential

Flammable liquid.

Source: Hazardous Substances Data Bank (HSDB)

10 · Handling and storage

2-aminopropane storage and handling

2-aminopropane safe storage

Well closed. Fireproof. Provision to contain effluent from fire extinguishing. Separated from food and feedstuffs. See Chemical Dangers. Store in an area without drain or sewer access.

Source: ILO-WHO International Chemical Safety Cards (ICSCs)

2-aminopropane storage conditions

Well closed. Fireproof. Provision to contain effluent from fire extinguishing. Separated from food and feedstuffs. See Chemical Dangers. Store in an area without drain or sewer access.

Source: Hazardous Substances Data Bank (HSDB)

2-aminopropane incompatible materials

Incompatible materials: Oxidizing agents.

Source: Hazardous Substances Data Bank (HSDB)

2-aminopropane reactivity

ISOPROPYLAMINE is a colorless, alkaline liquid, very volatile, moderately toxic, highly flammable. Dangerous fire hazard when exposed to heat, flame, sparks, or strong oxidizers. When heated to decomposition it emits toxic fumes of oxides of nitrogen [M. K.]. A mixture of isopropylamine and perchloryl fluoride resulted in an uncontrolled oxidation and/or explosion, [J. Org. Chem., 1980, 45, 4036]. The reaction of 1-chloro-2,3-epoxypropane and the amine and most probably other nitrogen bases, yields a violent exotherm, [Chem. & Ind., 1971, 994].

Source: CAMEO Chemicals

Planning storage for a mix of chemicals? Check 2-aminopropane in the storage compatibility matrix →

11 · Transport

2-aminopropane UN number and transport classification

Transport classification is a separate system from the GHS classification above. It decides how a package is marked and how a load may be carried; it does not follow from the workplace label, and the workplace label does not follow from it. The entries below are linked by CAS number, never by name.

2-aminopropane under UN 1221 — shipping name, class and packing group

Europe · ADR 2025, Table A

Proper shipping name (3.1.2) Class Classification code PG Labels (column 5)
ISOPROPYLAMINE 3 FC I
  • ADR label model 3 — Flammable liquid
  • ADR label model 8 — Corrosive substance
3, 8

Source: ADR 2025, Table A of Chapter 3.2 · ECE/TRANS/352 Vol. I (UNECE). Class 3 is “Flammable liquids” (ADR 2.1.1.1).

Proper shipping name (column 2) Class or division PG Labels (column 6)
Isopropylamine 3 I
  • US DOT FLAMMABLE LIQUID label (§172.419)
  • US DOT CORROSIVE label (§172.442)
3, 8

Source: 49 CFR 172.101 Hazardous Materials Table · eCFR, revision 2026-08-03. Class 3 is “Flammable and combustible liquid” (49 CFR 173.2).

Full UN 1221 entry — special provisions, packing instructions, quantity limits and the orange plate →

12 · Questions

2-aminopropane — frequently asked questions

What is the CAS number of 2-aminopropane?

The CAS number of 2-aminopropane is 75-31-0. Its EC number is 200-860-9.

What is the chemical formula of 2-aminopropane?

The molecular formula of 2-aminopropane is C3H9N and its molecular weight is 59.11 g/mol.

What does a 2-aminopropane label have to show?

Under CLP Annex VI the label for 2-aminopropane carries the pictograms Flame and Exclamation mark and the signal word is Danger.

Is 2-aminopropane flammable?

Yes. CLP Annex VI assigns 2-aminopropane H224 — extremely flammable liquid and vapour. The flash point reported for it is -18 °C (-0.4 °F) (HSDB).

Is 2-aminopropane a carcinogen?

CLP Annex VI records no harmonised carcinogenicity classification for 2-aminopropane. Annex VI is a list of agreed classifications, not a list of substances found safe, so this is an absence of a classification rather than a clean bill of health.

What is the exposure limit for 2-aminopropane?

The US occupational exposure limit reported for 2-aminopropane is 5.0 [ppm] (Haz-Map, Information on Hazardous Chemicals and Occupational Diseases). Limits differ by country: the EU sets its own indicative and binding values, and the figure that applies at a given workplace is the one in the local regulation.

What is the boiling point of 2-aminopropane?

The boiling point reported for 2-aminopropane is 31.8 °C (89.2 °F) (HSDB).

What is the melting point of 2-aminopropane?

The melting point reported for 2-aminopropane is -95.12 °C (-139.2 °F) (HSDB).

How should 2-aminopropane be stored?

CLP Annex VI assigns 2-aminopropane the storage statement P403. Well closed. Fireproof. Provision to contain effluent from fire extinguishing. Separated from food and feedstuffs. See Chemical Dangers. Store in an area without drain or sewer access. (Hazardous Substances Data Bank (HSDB))

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