Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

2-Thiophenecarboxylic acid, 3-(isocyanatosulfonyl)-, methyl ester

2-Thiophenecarboxylic acid, 3-(isocyanatosulfonyl)-, methyl ester: CBI; Liquid.

CAS 79277-18-2 C7H5NO5S2 247.3 g/mol Danger

01 · Identification

What 2-Thiophenecarboxylic acid… is

2-Thiophenecarboxylic acid, 3-(isocyanatosulfonyl)-, methyl ester: CBI; Liquid. Its molecular formula is C7H5NO5S2 and its molecular weight is 247.3 g/mol.

Under the GHS it carries the signal word Danger.

02 · Identifiers

2-Thiophenecarboxylic acid… identifiers and molecular data

2-Thiophenecarboxylic acid… CAS number and EC number

CAS number79277-18-2
EC number410-550-7
Index number (CLP Annex VI)615-022-00-1

2-Thiophenecarboxylic acid… molecular formula and molecular weight

Molecular formulaC7H5NO5S2
Molecular weight247.3 g/mol

Other names for 2-Thiophenecarboxylic acid…

  • methyl 3-isocyanatosulfonyl-2-thiophene-carboxylate

03 · GHS classification

2-Thiophenecarboxylic acid… hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

2-Thiophenecarboxylic acid… pictograms and signal word

Signal wordDanger

2-Thiophenecarboxylic acid… hazard class and category

GHS hazard classes 2-Thiophenecarboxylic… falls into
Hazard class Category From code Pictogram
Respiratory sensitisation GHS chapter 3.4 Category 1 or 1A or 1B H334 GHS08
Skin sensitisation GHS chapter 3.4 Category 1 or 1A or 1B H317 GHS07
Specific target organ toxicity - repeated exposure GHS chapter 3.9 Category 2 H373 GHS08

Where two values are shown with “or”, the hazard statement is shared by more than one category or by more than one class, and the code alone does not say which. H272, for example, belongs to oxidising liquids and to oxidising solids — the physical state decides. The binding answer for a specific entry is in the CLP Annex VI table itself.

2-Thiophenecarboxylic acid… hazard statements (H-codes)

Hazard statements assigned to 2-Thiophenecarboxylic…
CodeHazard statement
H373 May cause damage to organs <or state all organs affected, if known> through prolonged or repeated exposure <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H317 May cause an allergic skin reaction.

2-Thiophenecarboxylic acid… supplemental EU statements (EUH)

EU-specific statements assigned to 2-Thiophenecarboxylic…. They exist only in CLP and have no counterpart in UN GHS.
CodeStatement
EUH014 Reacts violently with water.

This page lists only the codes assigned to 2-Thiophenecarboxylic…. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for 2-Thiophenecarboxylic…

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of 2-Thiophenecarboxylic… issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

04 · Precautionary statements

2-Thiophenecarboxylic acid… precautionary statements

CLP Annex VI assigns 8 precautionary statements to 2-Thiophenecarboxylic…. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

2-Thiophenecarboxylic acid… name in 23 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български метилов 3-изоцианатосулфонил-2-тиофенкарбоксилат
Spanish español 3-Isocianatosulfonil-2-tiofeno-carboxilato de metilo
Czech čeština methyl-3-(isokyanatosulfonyl)thiofen-2-karboxylát
Danish dansk methyl-3-isocyanatosulfonyl-2-thiophencarboxylat
German Deutsch Methyl-3-sulfonylisocyanat-2-thiophencarboxylat
Estonian eesti metüül-3-isotsüanatosulfonüül-2-tiofeenkarboksülaat
Greek ελληνικά 3-ισoκυανoσoυλφoνυλo-2-θειoφαινoκαρβoξυλικό μεθύλιo 3-ισoκυανoσoυλφoνυλo-2-θειoφαινoκαρβoξυλικός μεθυλεστέρας
English English methyl 3-isocyanatosulfonyl-2-thiophene-carboxylate
French français 3-isocyanatosulfonyl-2-thiophène-carboxylate de méthyle
Croatian hrvatski metil 3-izocijanatosulfonil-2-tiofen-karboksilat
Italian italiano 3-isocianatosolfonil-2-tiofen-carbossilato di metile
Latvian latviešu metil-3-izocianatosulfonil-2-tiofēn-karboksilāts
Lithuanian lietuvių metil-3-izocianatosulfonil-2-tiofenkarboksilatas
Hungarian magyar metil-3-izocianátoszulfonil-2-tiofénkarboxilát
Maltese Malti metil 3-isoċjanatosulfonil-2-tiofen-karbossilat
Dutch Nederlands methyl-3-isocyanatosulfonyl-2-thiofeencarboxylaat
Polish polski 3-(izocyjanianosulfonylo)tiofeno-2-karboksylan metylu
Portuguese português 3-isocianatossulfonil-2-tiofenocarboxilato de metilo
Romanian română 3-izocianatosulfonil-2-tiofen-carboxilat de metil
Slovak slovenčina O -metyl-3-(izokyanátosulfonyl)tiofén-2-karboxylát
Slovenian slovenščina metil 3-izocianatosulfonil-2-tiofen-karboksilat
Finnish suomi metyyli-3-isosyanaattosulfonyyli-2-tiofeenikarboksylaatti
Swedish svenska metyl-3-isocyanatosulfonyl-2-tiofenkarboxylat

All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

2-Thiophenecarboxylic acid… GHS label elements

Everything CLP Annex VI fixes for 2-Thiophenecarboxylic…, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS08 Health hazard pictogram

Danger

2-Thiophenecarboxylic acid…

  • May cause damage to organs <or state all organs affected, if known> through prolonged or repeated exposure <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
  • May cause allergy or asthma symptoms or breathing difficulties if inhaled.
  • May cause an allergic skin reaction.
  • Reacts violently with water.
  • Do not breathe dust/fume/gas/mist/vapours/spray.
  • Avoid breathing dust/fume/gas/mist/vapours/spray.
  • Do not eat, drink or smoke when using this product.
  • Contaminated work clothing should not be allowed out of the workplace.
  • Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/
  • Get medical advice/attention.
  • Get medical advice/attention if you feel unwell.
  • If skin irritation or rash occurs:

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open 2-Thiophenecarboxylic… in the GHS label constructor →

07 · Questions

2-Thiophenecarboxylic acid… — frequently asked questions

What is the CAS number of 2-Thiophenecarboxylic acid…?

The CAS number of 2-Thiophenecarboxylic acid… is 79277-18-2. Its EC number is 410-550-7.

What is the chemical formula of 2-Thiophenecarboxylic acid…?

The molecular formula of 2-Thiophenecarboxylic acid… is C7H5NO5S2 and its molecular weight is 247.3 g/mol.

What does a 2-Thiophenecarboxylic acid… label have to show?

Under CLP Annex VI the label for 2-Thiophenecarboxylic acid… carries the pictogram Health hazard and the signal word is Danger.

Is 2-Thiophenecarboxylic acid… flammable?

CLP Annex VI assigns 2-Thiophenecarboxylic acid… no flammability hazard class. That is not a statement that it cannot burn: the harmonised list only records the hazards that were assessed for it.

Is 2-Thiophenecarboxylic acid… a carcinogen?

CLP Annex VI records no harmonised carcinogenicity classification for 2-Thiophenecarboxylic acid…. Annex VI is a list of agreed classifications, not a list of substances found safe, so this is an absence of a classification rather than a clean bill of health.

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