Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

Benzo(E)Pyrene

Benzo(E)Pyrene is prisms or plates from benzene.

CAS 192-97-2 Danger

01 · Identification

What Benzo(E)Pyrene is

Benzo(E)Pyrene is prisms or plates from benzene. It boils at 492 °C, melts at 179 °C.

Under the GHS it carries the signal word Danger.

02 · Identifiers

Benzo(E)Pyrene identifiers and molecular data

Benzo(E)Pyrene CAS number and EC number

CAS number192-97-2
EC number205-892-7
Index number (CLP Annex VI)601-049-00-6

Other names for Benzo(E)Pyrene

  • benzo[e]pyrene

03 · GHS classification

Benzo(E)Pyrene hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

Benzo(E)Pyrene pictograms and signal word

Signal wordDanger

Benzo(E)Pyrene hazard class and category

GHS hazard classes Benzo(E)Pyrene falls into
Hazard class Category From code Pictogram
Carcinogenicity GHS chapter 3.6 Category 1A or 1B H350 GHS08
Hazardous to the aquatic environment - acute GHS chapter 4.1 Category 1 H400 GHS09
Hazardous to the aquatic environment - chronic GHS chapter 4.1 Category 1 H410 GHS09

Where two values are shown with “or”, the hazard statement is shared by more than one category or by more than one class, and the code alone does not say which. H272, for example, belongs to oxidising liquids and to oxidising solids — the physical state decides. The binding answer for a specific entry is in the CLP Annex VI table itself.

Benzo(E)Pyrene hazard statements (H-codes)

Hazard statements assigned to Benzo(E)Pyrene
CodeHazard statement
H350 May cause cancer <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.

This page lists only the codes assigned to Benzo(E)Pyrene. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for Benzo(E)Pyrene

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of Benzo(E)Pyrene issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

04 · Precautionary statements

Benzo(E)Pyrene precautionary statements

CLP Annex VI assigns 7 precautionary statements to Benzo(E)Pyrene. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Response

What to do once exposure, spillage or fire has already happened.

Disposal

What has to happen to the contents and the empty container.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

Benzo(E)Pyrene name in 23 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български бензо[ e ]пирен
Spanish español Benzo[ e ]pireno
Czech čeština benzo[ e ]pyren
Danish dansk benzo[ e ]pyren
German Deutsch Benzo[ e ]pyren
Estonian eesti benso[ e ]püreen
Greek ελληνικά βενζο[ e ]πυρένιο
English English benzo[ e ]pyrene
French français benzo[ e ]pyrène
Croatian hrvatski benzo[ e ]piren
Italian italiano crisene
Latvian latviešu benzo[ e ]pirēns
Lithuanian lietuvių benz[ e ]pirenas
Hungarian magyar benzo[ e ]pirén
Maltese Malti benżo[ e ]piren
Dutch Nederlands benzo[ e ]pyreen
Polish polski benzo[e]piren
Portuguese português benzo[ e ]pireno
Romanian română benzo[ e ]piren
Slovak slovenčina benzo[ e ]pyrén
Slovenian slovenščina benzo[ e ]piren
Finnish suomi bentso[ e ]pyreeni
Swedish svenska benso[ e ]pyren

All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

Benzo(E)Pyrene GHS label elements

Everything CLP Annex VI fixes for Benzo(E)Pyrene, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS08 Health hazard pictogramGHS09 Environment pictogram

Danger

Benzo(E)Pyrene

  • May cause cancer <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
  • Very toxic to aquatic life.
  • Very toxic to aquatic life with long lasting effects.
  • Obtain special instructions before use.
  • Avoid release to the environment.
  • Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/
  • IF exposed or concerned:
  • Get medical advice/attention.
  • Collect spillage.
  • Dispose of contents/container to

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open Benzo(E)Pyrene in the GHS label constructor →

07 · Health hazards

Benzo(E)Pyrene health hazards and exposure limits

Benzo(E)Pyrene hazard summary

May cause irritation; [MSDSonline] See POLYCYCLIC AROMATIC HYDROCARBONS.

Source: Haz-Map, Information on Hazardous Chemicals and Occupational Diseases

Benzo(E)Pyrene carcinogenicity classification

IARC classification Group 3 — Not classifiable as to its carcinogenicity to humans
IARC monographs Volume 92: (2010) Some Non-heterocyclic Polycyclic Aromatic Hydrocarbons and Some Related Exposures

OVERALL EVALUATION: Group 3: The agent is not classifiable as to its carcinogenicity to humans.

Source: Hazardous Substances Data Bank (HSDB)

An IARC group and a CLP classification answer different questions. IARC judges whether the evidence for cancer in humans is strong enough; CLP Annex VI is the legally binding EU classification. A substance can carry one and not the other.

Benzo(E)Pyrene occupational exposure limits

US occupational exposure limits reported for Benzo(E)Pyrene. PEL is enforceable (OSHA), REL is a recommendation (NIOSH), IDLH is the concentration at which escape becomes impossible without injury.
Limit Value Source
IDLH NIOSH considers coal tar pitch volatiles to be potential occupational carcinogens. /Coal tar pitch volatiles/ Hazardous Substances Data Bank (HSDB)

These are United States values. The European Union sets its own indicative and binding limits, and the figure that applies at a given workplace is the one in the local regulation — not the one shown here.

08 · Physical and chemical properties

Benzo(E)Pyrene properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

Benzo(E)Pyrene boiling point

Property Value Conditions Source
Boiling point 492 °C (917.6 °F) HSDB
492.22 °C (918 °F) at 760 mmHg CAMEO
250 °C (482 °F) sublimes, at -4 mmHg (reduced pressure), sublimes HSDB

Benzo(E)Pyrene melting point

Property Value Conditions Source
Melting point 178.5 °C (353.3 °F) range, midpoint shown HSDB
178.33 °C (353 °F) range, midpoint shown CAMEO

Benzo(E)Pyrene solubility

Property Value Conditions Source
Solubility Soluble in acetone HSDB
In water 0.0063 mg/L at 25 °C at 25 °C HSDB
2.9X10-8 mol/L dissolve in water at 25 °C at 25 °C HSDB

Benzo(E)Pyrene vapor pressure

Property Value Conditions Source
Vapor pressure 5.7e-9 mmHg at 25 °C HSDB
1e-8 mmHg Haz-Map

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

09 · Handling and storage

Benzo(E)Pyrene storage and handling

Benzo(E)Pyrene storage conditions

Keep container tightly closed in a dry and well-ventilated place.[Sigma-Aldrich; Safety Data Sheet for Benzo

Source: Hazardous Substances Data Bank (HSDB)

Benzo(E)Pyrene incompatible materials

Incompatible materials: Strong oxidizing agents.[Sigma-Aldrich; Safety Data Sheet for Benzo

Source: Hazardous Substances Data Bank (HSDB)

Benzo(E)Pyrene reactivity

BENZO[E]PYRENE may be sensitive to prolonged exposure to light.

Source: CAMEO Chemicals

Planning storage for a mix of chemicals? Check Benzo(E)Pyrene in the storage compatibility matrix →

10 · Questions

Benzo(E)Pyrene — frequently asked questions

What is the CAS number of Benzo(E)Pyrene?

The CAS number of Benzo(E)Pyrene is 192-97-2. Its EC number is 205-892-7.

What does a Benzo(E)Pyrene label have to show?

Under CLP Annex VI the label for Benzo(E)Pyrene carries the pictograms Health hazard and Environment and the signal word is Danger.

Is Benzo(E)Pyrene flammable?

CLP Annex VI assigns Benzo(E)Pyrene no flammability hazard class. That is not a statement that it cannot burn: the harmonised list only records the hazards that were assessed for it.

Is Benzo(E)Pyrene a carcinogen?

Yes. CLP Annex VI classifies Benzo(E)Pyrene as a category 1A or 1B carcinogen and assigns it H350: may cause cancer. IARC places it in Group 3: not classifiable as to its carcinogenicity to humans.

What is the boiling point of Benzo(E)Pyrene?

The boiling point reported for Benzo(E)Pyrene is 492 °C (917.6 °F) (HSDB).

What is the melting point of Benzo(E)Pyrene?

The melting point reported for Benzo(E)Pyrene is 178.5 °C (353.3 °F), range, midpoint shown (HSDB).

How should Benzo(E)Pyrene be stored?

Keep container tightly closed in a dry and well-ventilated place.[Sigma-Aldrich; Safety Data Sheet for Benzo (Hazardous Substances Data Bank (HSDB))

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