Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

Calcium Chromate

Calcium Chromate is yellow monoclinic rhombic crystals.

CAS 13765-19-0 Danger

01 · Identification

What Calcium Chromate is

Calcium Chromate is yellow monoclinic rhombic crystals. It melts at 1000 °C, is slightly soluble in water.

Under the GHS it carries the signal word Danger. It is classed as carcinogens.

02 · Identifiers

Calcium Chromate identifiers and molecular data

Calcium Chromate CAS number and EC number

CAS number13765-19-0
EC number237-366-8
Index number (CLP Annex VI)024-008-00-9

Calcium Chromate molecular formula and molecular weight

Chemical class Carcinogens

03 · GHS classification

Calcium Chromate hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

Calcium Chromate pictograms and signal word

Signal wordDanger

Calcium Chromate hazard class and category

GHS hazard classes Calcium Chromate falls into
Hazard class Category From code Pictogram
Acute toxicity - oral GHS chapter 3.1 Category 4 H302 GHS07
Carcinogenicity GHS chapter 3.6 Category 1A or 1B H350 GHS08
Hazardous to the aquatic environment - acute GHS chapter 4.1 Category 1 H400 GHS09
Hazardous to the aquatic environment - chronic GHS chapter 4.1 Category 1 H410 GHS09

Where two values are shown with “or”, the hazard statement is shared by more than one category or by more than one class, and the code alone does not say which. H272, for example, belongs to oxidising liquids and to oxidising solids — the physical state decides. The binding answer for a specific entry is in the CLP Annex VI table itself.

Calcium Chromate hazard statements (H-codes)

Hazard statements assigned to Calcium Chromate
CodeHazard statement
H350 May cause cancer <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
H302 Harmful if swallowed.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.

This page lists only the codes assigned to Calcium Chromate. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for Calcium Chromate

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of Calcium Chromate issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

04 · Precautionary statements

Calcium Chromate precautionary statements

CLP Annex VI assigns 11 precautionary statements to Calcium Chromate. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Disposal

What has to happen to the contents and the empty container.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

Calcium Chromate name in 23 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български калциев хромат
Spanish español Cromato de calcio
Czech čeština chroman vápenatý
Danish dansk calciumchromat
German Deutsch Calciumchromat
Estonian eesti kaltsiumkromaat
Greek ελληνικά χρωμικό ασβέστιο
English English calcium chromate
French français chromate de calcium
Croatian hrvatski kalcijev kromat
Italian italiano cromato di calcio
Latvian latviešu kalcija hromāts
Lithuanian lietuvių kalcio chromatas
Hungarian magyar kálcium-kromát
Maltese Malti kromat tal-kalċju
Dutch Nederlands calciumchromaat
Polish polski chromian(VI) wapnia
Portuguese português cromato de cálcio
Romanian română cromat de calciu
Slovak slovenčina chróman vápenatý
Slovenian slovenščina kalcijev kromat
Finnish suomi kalsiumkromaatti
Swedish svenska kalciumkromat

All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

Calcium Chromate GHS label elements

Everything CLP Annex VI fixes for Calcium Chromate, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS08 Health hazard pictogramGHS07 Exclamation mark pictogramGHS09 Environment pictogram

Danger

Calcium Chromate

  • May cause cancer <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
  • Harmful if swallowed.
  • Very toxic to aquatic life.
  • Very toxic to aquatic life with long lasting effects.
  • Obtain special instructions before use.
  • Do not eat, drink or smoke when using this product.
  • Avoid release to the environment.
  • Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/
  • IF SWALLOWED:
  • IF exposed or concerned:
  • Call a POISON CENTER/doctor/ if you feel unwell.
  • Get medical advice/attention.
  • Rinse mouth.
  • Collect spillage.
  • Dispose of contents/container to

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open Calcium Chromate in the GHS label constructor →

07 · Health hazards

Calcium Chromate health hazards and exposure limits

Calcium Chromate hazard summary

CrVI compounds are irritants, sensitizers, and may be corrosive to the skin. CrVI compounds are respiratory tract irritants and may cause pulmonary sensitization. CrVI may cause acute tubular necrosis and liver injury. [ATSDR Case Studies] Calcium chromate is approximately 10 times more potent than zinc chromate as an animal carcinogen by intrabronchial implantation. [ACGIH] Skin contact may cause dermatitis and ulcers; [CHRIS] Very toxic by ingestion; Not soluble in water; [CAMEO] See Chromium and linked occupational diseases.

Source: Haz-Map, Information on Hazardous Chemicals and Occupational Diseases

Calcium Chromate carcinogenicity classification

Evaluation: There is sufficient evidence in humans for the carcinogenicity of chromium(VI) compounds. Chromium(VI) compounds cause cancer of the lung. Also positive associations have been observed between exposure to Chromium(IV) compounds and cancer of the nose and nasal sinuses. There is sufficient evidence in experimental animals for the carcinogenicity of chromium(VI) compounds. Chromium(VI) compounds are carcinogenic to humans (Group 1). /Chromium(VI) compounds/

Source: Hazardous Substances Data Bank (HSDB)

Chromium Hexavalent Compounds: known to be human carcinogens. /Chromium hexavalent compound/

Source: Hazardous Substances Data Bank (HSDB)

An IARC group and a CLP classification answer different questions. IARC judges whether the evidence for cancer in humans is strong enough; CLP Annex VI is the legally binding EU classification. A substance can carry one and not the other.

Calcium Chromate occupational exposure limits

US occupational exposure limits reported for Calcium Chromate. PEL is enforceable (OSHA), REL is a recommendation (NIOSH), IDLH is the concentration at which escape becomes impossible without injury.
Limit Value Source
PEL 0.005 [mg/m3], as Cr(VI) Haz-Map, Information on Hazardous Chemicals and Occupational Diseases
IDLH 15 mg Cr(VI)/m3 ; A potential occupational carcinogen. (NIOSH, 2024) CAMEO Chemicals
IDLH 250 mg/cu m (as Cr(II)). /Chromium(II) compounds (as Cr)/ Hazardous Substances Data Bank (HSDB)
IDLH 25 mg/cu m (as Cr(III)). /Chromium(III) compounds (as Cr)/ Hazardous Substances Data Bank (HSDB)

These are United States values. The European Union sets its own indicative and binding limits, and the figure that applies at a given workplace is the one in the local regulation — not the one shown here.

08 · Physical and chemical properties

Calcium Chromate properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

Calcium Chromate melting point

Property Value Conditions Source
Melting point 1000 °C (1832 °F) DOE PAC
1000 °C (1832 °F) decomposes, decomposes HSDB

Calcium Chromate density

Property Value Conditions Source
Density 2.89 g/cm³ HSDB
3.12 g/cm³ ICSC
1 g/cm³ at 20 °C CAMEO

Calcium Chromate solubility

Property Value Conditions Source
Solubility Slightly soluble in water HSDB
Soluble in dilute acids HSDB
Insoluble in acetone HSDB

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

09 · Fire and explosion

Calcium Chromate fire and explosion behaviour

These are descriptions rather than measured values, so they are kept out of the table above and quoted here with the source that reported them.

Calcium Chromate fire potential

Mixture with boron burns violently if ignited.

Source: Hazardous Substances Data Bank (HSDB)

10 · Handling and storage

Calcium Chromate storage and handling

Calcium Chromate safe storage

Provision to contain effluent from fire extinguishing. Dry. Well closed. Separated from combustible substances, reducing agents and food and feedstuffs. Store in an area without drain or sewer access.

Source: ILO-WHO International Chemical Safety Cards (ICSCs)

Calcium Chromate storage conditions

Keep container tightly closed in a dry and well-ventilated place. Storage class (TRGS 510): Non-combustible, acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects.

Source: Hazardous Substances Data Bank (HSDB)

Calcium Chromate incompatible materials

Incompatible materials: Reducing agents, azides, aluminum, hydrogen peroxide, hydrazine, magnesium

Source: Hazardous Substances Data Bank (HSDB)

Calcium Chromate reactivity

CALCIUM CHROMATE is a strong oxidizer and reacts with acids and ethanol. (NTP, 1992)

Source: CAMEO Chemicals

Planning storage for a mix of chemicals? Check Calcium Chromate in the storage compatibility matrix →

11 · Questions

Calcium Chromate — frequently asked questions

What is the CAS number of Calcium Chromate?

The CAS number of Calcium Chromate is 13765-19-0. Its EC number is 237-366-8.

What does a Calcium Chromate label have to show?

Under CLP Annex VI the label for Calcium Chromate carries the pictograms Health hazard, Exclamation mark and Environment and the signal word is Danger.

Is Calcium Chromate flammable?

CLP Annex VI assigns Calcium Chromate no flammability hazard class. That is not a statement that it cannot burn: the harmonised list only records the hazards that were assessed for it.

Is Calcium Chromate a carcinogen?

Yes. CLP Annex VI classifies Calcium Chromate as a category 1A or 1B carcinogen and assigns it H350: may cause cancer.

What is the exposure limit for Calcium Chromate?

The US occupational exposure limit reported for Calcium Chromate is 0.005 [mg/m3], as Cr(VI) (Haz-Map, Information on Hazardous Chemicals and Occupational Diseases). Limits differ by country: the EU sets its own indicative and binding values, and the figure that applies at a given workplace is the one in the local regulation.

What is the melting point of Calcium Chromate?

The melting point reported for Calcium Chromate is 1000 °C (1832 °F) (DOE PAC).

How should Calcium Chromate be stored?

Keep container tightly closed in a dry and well-ventilated place. Storage class (TRGS 510): Non-combustible, acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects. (Hazardous Substances Data Bank (HSDB))

Nearby

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