Substance profile
Clodinafop-propargyl
Clodinafop-propargyl is colorless crystals and is odorless.
01 · Identification
What Clodinafop-propargyl is
Clodinafop-propargyl is colorless crystals and is odorless. Its molecular formula is C17H13ClFNO4 and its molecular weight is 349.7 g/mol. It melts at 59.5 °C, is soluble in water.
Under the GHS it carries the signal word Warning.
02 · Identifiers
Clodinafop-propargyl identifiers and molecular data
Clodinafop-propargyl CAS number and EC number
Clodinafop-propargyl molecular formula and molecular weight
Other names for Clodinafop-propargyl
- clodinafop-propargyl (ISO)
03 · GHS classification
Clodinafop-propargyl hazard classification
Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.
Clodinafop-propargyl pictograms and signal word
Clodinafop-propargyl hazard class and category
| Hazard class | Category | From code | Pictogram |
|---|---|---|---|
| Acute toxicity - oral GHS chapter 3.1 | Category 4 | H302 | GHS07 |
| Skin sensitisation GHS chapter 3.4 | Category 1 or 1A or 1B | H317 | GHS07 |
| Specific target organ toxicity - repeated exposure GHS chapter 3.9 | Category 2 | H373 | GHS08 |
| Hazardous to the aquatic environment - acute GHS chapter 4.1 | Category 1 | H400 | GHS09 |
| Hazardous to the aquatic environment - chronic GHS chapter 4.1 | Category 1 | H410 | GHS09 |
Where two values are shown with “or”, the hazard statement is shared by more than one category or by more than one class, and the code alone does not say which. H272, for example, belongs to oxidising liquids and to oxidising solids — the physical state decides. The binding answer for a specific entry is in the CLP Annex VI table itself.
Clodinafop-propargyl hazard statements (H-codes)
| Code | Hazard statement |
|---|---|
| H302 | Harmful if swallowed. |
| H373 | May cause damage to organs <or state all organs affected, if known> through prolonged or repeated exposure <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>. |
| H317 | May cause an allergic skin reaction. |
| H400 | Very toxic to aquatic life. |
| H410 | Very toxic to aquatic life with long lasting effects. |
This page lists only the codes assigned to Clodinafop-propargyl. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.
Safety Data Sheet
Getting an SDS for Clodinafop-propargyl
A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of Clodinafop-propargyl issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.
04 · Precautionary statements
Clodinafop-propargyl precautionary statements
CLP Annex VI assigns 14 precautionary statements to Clodinafop-propargyl. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.
Prevention
What to do before and during handling so the hazard never happens.
Response
What to do once exposure, spillage or fire has already happened.
Disposal
What has to happen to the contents and the empty container.
Reading the notation. … is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.
05 · Names in the regulation
Clodinafop-propargyl name in 23 EU languages
CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.
| Language | Name in CLP Annex VI Part 3 |
|---|---|
| Bulgarian български | клодинафоп-пропаргил (ISO) |
| Spanish español | Clodinafop-propargilo (ISO) |
| Czech čeština | klodinafop-propargyl (ISO) |
| Danish dansk | clodinafop-propargyl (ISO) |
| German Deutsch | Clodinafop-propargyl (ISO) |
| Estonian eesti | klodinafop-propargüül (ISO) |
| Greek ελληνικά | clodinafop-propargyl (προπαργυλική κλοδιναφόπη) (ISO) |
| English English | clodinafop-propargyl (ISO) |
| French français | clodinafop-propargyl (ISO) |
| Croatian hrvatski | klodinafop-propargil (ISO) |
| Italian italiano | clodinafop-propargil (ISO) |
| Latvian latviešu | klodinafoppropargils (ISO) |
| Lithuanian lietuvių | klodinafoppropargilas (ISO) |
| Hungarian magyar | klodinafop-propargil (ISO) |
| Maltese Malti | klodinafop-propargil (ISO) |
| Dutch Nederlands | clodinafop-propargyl (ISO) |
| Polish polski | chlodinafop propargilowy (ISO) |
| Portuguese português | clodinafope-propargilo (ISO) |
| Romanian română | clodinafop-propargil (ISO) |
| Slovak slovenčina | klodinafop-propargyl (ISO) O -(prop-2-inyl)-( R )-2-[4-(3-fluór-5- chlórpyridín-2-yloxy)fenoxy]propanoát |
| Slovenian slovenščina | klodinafop-propargil (ISO) |
| Finnish suomi | klodinafoppipropargyyli (ISO) |
| Swedish svenska | klodinafop-propargyl (ISO) |
All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.
06 · Label elements
Clodinafop-propargyl GHS label elements
Everything CLP Annex VI fixes for Clodinafop-propargyl, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.
Warning
Clodinafop-propargyl
- Harmful if swallowed.
- May cause damage to organs <or state all organs affected, if known> through prolonged or repeated exposure <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
- May cause an allergic skin reaction.
- Very toxic to aquatic life.
- Very toxic to aquatic life with long lasting effects.
- Do not breathe dust/fume/gas/mist/vapours/spray.
- Avoid breathing dust/fume/gas/mist/vapours/spray.
- Do not eat, drink or smoke when using this product.
- Contaminated work clothing should not be allowed out of the workplace.
- Avoid release to the environment.
- Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/…
- IF SWALLOWED:
- Call a POISON CENTER/doctor/… if you feel unwell.
- Get medical advice/attention.
- Get medical advice/attention if you feel unwell.
- Rinse mouth.
- If skin irritation or rash occurs:
- Collect spillage.
- Dispose of contents/container to …
Supplier name, address and telephone number· Product identifier·Nominal quantity
Need this as an actual label? Open Clodinafop-propargyl in the GHS label constructor →
07 · Health hazards
Clodinafop-propargyl health hazards and exposure limits
Clodinafop-propargyl hazard summary
May cause irritation; May cause skin sensitization; Caused no irritation to the skin or eyes of rabbits; [MSDSonline]
Source: Haz-Map, Information on Hazardous Chemicals and Occupational Diseases
Clodinafop-propargyl carcinogenicity classification
Cancer Classification: Suggestive Evidence of Carcinogenic Potential
Source: Hazardous Substances Data Bank (HSDB)
An IARC group and a CLP classification answer different questions. IARC judges whether the evidence for cancer in humans is strong enough; CLP Annex VI is the legally binding EU classification. A substance can carry one and not the other.
08 · Physical and chemical properties
Clodinafop-propargyl properties
Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.
Clodinafop-propargyl melting point
| Property | Value | Conditions | Source |
|---|---|---|---|
| Melting point | 59.5 °C (139.1 °F) | HSDB | |
| 52.65 °C (126.8 °F) | range, midpoint shown | HSDB |
Clodinafop-propargyl density
| Property | Value | Conditions | Source |
|---|---|---|---|
| Density | 1.37 g/cm³ | at 22 °C | HSDB |
| 1.076 g/cm³ | HSDB |
Clodinafop-propargyl solubility
| Property | Value | Conditions | Source |
|---|---|---|---|
| Solubility | Soluble in most organic solvents | HSDB | |
| In water, 2.5 ppm at 20 °C | at 20 °C | HSDB | |
| In organic solvents at 25 °C (g/L): ethanol - 92; acetone - 880; toluene - 690; n-hexane - 0.0086; n-octanol - 25 | at 25 °C | HSDB |
Clodinafop-propargyl vapor pressure
| Property | Value | Conditions | Source |
|---|---|---|---|
| Vapor pressure | 3.975e-8 mmHg | at 20 °C | HSDB |
| 2.4e-8 mmHg | at 25 °C | HSDB | |
| 2e-8 mmHg | Haz-Map |
Clodinafop-propargyl autoignition temperature
| Property | Value | Conditions | Source |
|---|---|---|---|
| Autoignition temperature | 510 °C (950 °F) | HSDB |
Clodinafop-propargyl lower explosive limit (LEL)
| Property | Value | Conditions | Source |
|---|---|---|---|
| Lower explosive limit (LEL) | 1 % by volume | HSDB |
Clodinafop-propargyl upper explosive limit (UEL)
| Property | Value | Conditions | Source |
|---|---|---|---|
| Upper explosive limit (UEL) | 7 % by volume | Discover Herbicide | HSDB |
Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.
09 · Handling and storage
Clodinafop-propargyl storage and handling
Clodinafop-propargyl storage conditions
Do not contaminate water, food, or feed by storage or disposal. Do not use in animal feeds. Store in a cool, dry place. /Discover Herbicide/
Source: Hazardous Substances Data Bank (HSDB)
Clodinafop-propargyl incompatible materials
Combustible liquid. Can release vapors that form explosive mixtures at temperatures at or above the flash point. Heavy vapors can flow along surfaces to distant ignition sources and flash back. /Discover Herbicide/
Source: Hazardous Substances Data Bank (HSDB)
Planning storage for a mix of chemicals? Check Clodinafop-propargyl in the storage compatibility matrix →
10 · Questions
Clodinafop-propargyl — frequently asked questions
What is the CAS number of Clodinafop-propargyl?
The CAS number of Clodinafop-propargyl is 105512-06-9.
What is the chemical formula of Clodinafop-propargyl?
The molecular formula of Clodinafop-propargyl is C17H13ClFNO4 and its molecular weight is 349.7 g/mol.
What does a Clodinafop-propargyl label have to show?
Under CLP Annex VI the label for Clodinafop-propargyl carries the pictograms Health hazard, Exclamation mark and Environment and the signal word is Warning.
Is Clodinafop-propargyl flammable?
CLP Annex VI assigns Clodinafop-propargyl no flammability hazard class. That is not a statement that it cannot burn: the harmonised list only records the hazards that were assessed for it.
Is Clodinafop-propargyl a carcinogen?
CLP Annex VI records no harmonised carcinogenicity classification for Clodinafop-propargyl. Annex VI is a list of agreed classifications, not a list of substances found safe, so this is an absence of a classification rather than a clean bill of health.
What is the melting point of Clodinafop-propargyl?
The melting point reported for Clodinafop-propargyl is 59.5 °C (139.1 °F) (HSDB).
How should Clodinafop-propargyl be stored?
Do not contaminate water, food, or feed by storage or disposal. Do not use in animal feeds. Store in a cool, dry place. /Discover Herbicide/ (Hazardous Substances Data Bank (HSDB))
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Substances next to Clodinafop-propargyl
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