Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

Cyanophos

Cyanophos is a yellow to reddish-yellow transparent liquid with a faint characteristic odor.

CAS 2636-26-2 Warning

01 · Identification

What Cyanophos is

Cyanophos is a yellow to reddish-yellow transparent liquid with a faint characteristic odor. It melts at 14.5 °C.

Under the GHS it carries the signal word Warning.

02 · Identifiers

Cyanophos identifiers and molecular data

Cyanophos CAS number and EC number

CAS number2636-26-2
EC number220-130-3
Index number (CLP Annex VI)015-087-00-0

Other names for Cyanophos

  • cyanophos (ISO)
  • O-4-cyanophenyl O,O-dimethyl phosphorothioate

03 · GHS classification

Cyanophos hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

Cyanophos pictograms and signal word

Signal wordWarning

Cyanophos hazard class and category

GHS hazard classes Cyanophos falls into
Hazard class Category From code Pictogram
Acute toxicity - oral GHS chapter 3.1 Category 4 H302 GHS07
Acute toxicity - dermal GHS chapter 3.1 Category 4 H312 GHS07
Hazardous to the aquatic environment - acute GHS chapter 4.1 Category 1 H400 GHS09
Hazardous to the aquatic environment - chronic GHS chapter 4.1 Category 1 H410 GHS09

Cyanophos hazard statements (H-codes)

Hazard statements assigned to Cyanophos
CodeHazard statement
H312 Harmful in contact with skin.
H302 Harmful if swallowed.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.

This page lists only the codes assigned to Cyanophos. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for Cyanophos

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of Cyanophos issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

04 · Precautionary statements

Cyanophos precautionary statements

CLP Annex VI assigns 10 precautionary statements to Cyanophos. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Disposal

What has to happen to the contents and the empty container.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

Cyanophos name in 23 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български цианофос (ISO) O -4-цианофенилов О , О -диметилов фосфоротиоат
Spanish español Cianofós (ISO) fosforotioato de O -4-cianofenilo y O , O -dimetilo
Czech čeština kyanofos (ISO) O -(4-kyanfenyl)- O, O -dimethyl-fosforothioát
Danish dansk cyanophos (ISO) O- 4-cyanophenyl- O, O- dimethylthiophosphat
German Deutsch Cyanophos (ISO) O -4-Cyanphenyl- O, O -dimethylphosphorothioat
Estonian eesti tsüanofoss (ISO) O -4-tsüanofenüül- O , O -dimetüülfosforotioaat
Greek ελληνικά cyanophos (κυανοφός) (ISO) θειοφωσφορικό O -4-κυανοφαινύλιο O , O -διμεθύλιο
English English cyanophos (ISO) O -4-cyanophenyl O , O -dimethyl phosphorothioate
French français cyanophos (ISO) phosphorothioate de O -4-cyanophényle et de O, O -diméthyle
Croatian hrvatski cijanofos (ISO) O -4-cijanofenil- O , O -dimetil-fosforotioat
Italian italiano cianofos (ISO) tiofosfato di O-4-cianofenile e O, O-dimetile
Latvian latviešu ciānfoss (ISO) O -4-ciānfenil- O , O -dimetilfosfortioāts
Lithuanian lietuvių cianofosas (ISO) O -4-cianfenil- O , O -dimetiltiofosfatas
Hungarian magyar cianofosz (ISO) O -4-cianofenil- O , O -dimetil-tiofoszfát
Maltese Malti ċjanofos (ISO) fosforotijoat ta’ O -4-ċjanofenil O , O -dimetil
Dutch Nederlands cyanofos (ISO) O -4-cyaanfenyl- O , O -dimethylthiofosfaat
Polish polski cyjanofos (ISO) tiofosforan O -4-cyjanofenylu- O , O -dimetylu
Portuguese português cianofos (ISO) tiofosfato de O -4-cianofenilo e de O , O -dimetilo
Romanian română cianofos (ISO) tiofosfat de O -4-cianofenil și de O, O -dimetil
Slovak slovenčina kyanofos (ISO) O -(4-kyanofenyl)- O, O -dimetyl-fosforotioát
Slovenian slovenščina cianofos (ISO) O -4-cianofenil O , O -dimetil fosforotioat
Finnish suomi syanofossi (ISO) O -4-syanofenyyli- O , O -dimetyylifosforotioaatti
Swedish svenska cyanofos (ISO) O -4-cyanofenyl- O , O -dimetylfosfortioat

All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

Cyanophos GHS label elements

Everything CLP Annex VI fixes for Cyanophos, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS07 Exclamation mark pictogramGHS09 Environment pictogram

Warning

Cyanophos

  • Harmful in contact with skin.
  • Harmful if swallowed.
  • Very toxic to aquatic life.
  • Very toxic to aquatic life with long lasting effects.
  • Do not eat, drink or smoke when using this product.
  • Avoid release to the environment.
  • Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/
  • IF SWALLOWED:
  • IF ON SKIN:
  • Call a POISON CENTER/doctor/ if you feel unwell.
  • Rinse mouth.
  • Wash with plenty of water/
  • Collect spillage.
  • Dispose of contents/container to

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open Cyanophos in the GHS label constructor →

07 · Health hazards

Cyanophos health hazards and exposure limits

Cyanophos hazard summary

A cholinesterase inhibitor; [Merck Index] Effects in high-dose animal studies include convulsions and spastic paralysis; [RTECS] The average of two baseline respective cholinesterase activity determinations three days apart, with no exposures to enzyme inhibiting pesticides for at least 30 days, is recommended for each worker prior to exposure to cholinesterase inhibitors because of large inter-individual differences in published baseline values. To be established at least once a year. Removal from workplace exposures is recommended until the cholinesterase activity returns to within 20% of baseline. [TLVs and BEIs]

Source: Haz-Map, Information on Hazardous Chemicals and Occupational Diseases

08 · Physical and chemical properties

Cyanophos properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

Cyanophos boiling point

Property Value Conditions Source
Boiling point 119.5 °C (247.1 °F) range, midpoint shown, at 0.09 mmHg (reduced pressure) HSDB
119.44 °C (247 °F) range, midpoint shown, at 0.09 mmHg (reduced pressure) CAMEO

Cyanophos melting point

Property Value Conditions Source
Melting point 14.5 °C (58.1 °F) range, midpoint shown HSDB
14.44 °C (58 °F) range, midpoint shown CAMEO

Cyanophos density

Property Value Conditions Source
Density 1.26 g/cm³ range, midpoint shown, at 25 °C HSDB

Cyanophos solubility

Property Value Conditions Source
Solubility Very soluble in methanol, ethanol, acetone & chloroform. Sparingly soluble in n-hexane, kerosene. HSDB
Miscible in alcohols, benzene, chloroform, ketones, toluene, xylene. HSDB
Solubility: 46 mg/l water at 30 °C; 27 g/kg hexane at 20 °C at 30 °C, Technical grade HSDB

Cyanophos vapor pressure

Property Value Conditions Source
Vapor pressure 787600 mmHg at 20 °C HSDB
0.0008 mmHg at 20 °C CAMEO

Cyanophos flash point

Property Value Conditions Source
Flash point 104 °C (219.2 °F) HSDB

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

09 · Handling and storage

Cyanophos storage and handling

Cyanophos storage conditions

Rooms used for storage only should be soundly constructed & fitted with secure locks. Floors should be kept clear & pesticides clearly identified. If repacking is carried out in storage rooms, adequate light should be available; floors should be impervious & sound ... . /Pesticides/

Source: Hazardous Substances Data Bank (HSDB)

Cyanophos reactivity

Organophosphates, such as CYANOPHOS, are susceptible to formation of highly toxic and flammable phosphine gas in the presence of strong reducing agents such as hydrides. Partial oxidation by oxidizing agents may result in the release of toxic phosphorus oxides.

Source: CAMEO Chemicals

Planning storage for a mix of chemicals? Check Cyanophos in the storage compatibility matrix →

10 · Questions

Cyanophos — frequently asked questions

What is the CAS number of Cyanophos?

The CAS number of Cyanophos is 2636-26-2. Its EC number is 220-130-3.

What does a Cyanophos label have to show?

Under CLP Annex VI the label for Cyanophos carries the pictograms Exclamation mark and Environment and the signal word is Warning.

Is Cyanophos flammable?

CLP Annex VI assigns Cyanophos no flammability hazard class. That is not a statement that it cannot burn: the harmonised list only records the hazards that were assessed for it. The flash point reported for it is 104 °C (219.2 °F) (HSDB).

Is Cyanophos a carcinogen?

CLP Annex VI records no harmonised carcinogenicity classification for Cyanophos. Annex VI is a list of agreed classifications, not a list of substances found safe, so this is an absence of a classification rather than a clean bill of health.

What is the boiling point of Cyanophos?

The boiling point reported for Cyanophos is 119.5 °C (247.1 °F), range, midpoint shown, at 0.09 mmHg (reduced pressure) (HSDB).

What is the melting point of Cyanophos?

The melting point reported for Cyanophos is 14.5 °C (58.1 °F), range, midpoint shown (HSDB).

How should Cyanophos be stored?

Rooms used for storage only should be soundly constructed & fitted with secure locks. Floors should be kept clear & pesticides clearly identified. If repacking is carried out in storage rooms, adequate light should be available; floors should be impervious & sound ... . /Pesticides/ (Hazardous Substances Data Bank (HSDB))

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