Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

DDT (ISO)

DDT (ISO) is biaxial elongated tablets, needles from 95% alcohol and is odorless.

CAS 50-29-3 C14H9Cl5 354.5 g/mol Danger

01 · Identification

What DDT (ISO) is

DDT (ISO) is biaxial elongated tablets, needles from 95% alcohol and is odorless. Its molecular formula is C14H9Cl5 and its molecular weight is 354.5 g/mol. It boils at 260 °C, melts at 109 °C.

Under the GHS it carries the signal word Danger. It is classed as carcinogens.

02 · Identifiers

DDT (ISO) identifiers and molecular data

DDT (ISO) CAS number and EC number

CAS number50-29-3
EC number200-024-3
Index number (CLP Annex VI)602-045-00-7

DDT (ISO) molecular formula and molecular weight

Molecular formulaC14H9Cl5
Molecular weight354.5 g/mol
Chemical class Carcinogens

Other names for DDT (ISO)

  • clofenotane (INN)
  • dicophane
  • 1,1,1-trichloro-2,2-bis(4-chlorophenyl)ethane
  • dichlorodiphenyltrichloroethane

03 · GHS classification

DDT (ISO) hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

DDT (ISO) pictograms and signal word

Signal wordDanger

DDT (ISO) hazard class and category

GHS hazard classes DDT (ISO) falls into
Hazard class Category From code Pictogram
Acute toxicity - oral GHS chapter 3.1 Category 3 H301 GHS06
Carcinogenicity GHS chapter 3.6 Category 2 H351 GHS08
Specific target organ toxicity - repeated exposure GHS chapter 3.9 Category 1 H372 GHS08
Hazardous to the aquatic environment - acute GHS chapter 4.1 Category 1 H400 GHS09
Hazardous to the aquatic environment - chronic GHS chapter 4.1 Category 1 H410 GHS09

DDT (ISO) hazard statements (H-codes)

Hazard statements assigned to DDT (ISO)
CodeHazard statement
H351 Suspected of causing cancer <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
H301 Toxic if swallowed.
H372 Causes damage to organs <or state all organs affected, if known> through prolonged or repeated exposure <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.

This page lists only the codes assigned to DDT (ISO). The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for DDT (ISO)

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of DDT (ISO) issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

04 · Precautionary statements

DDT (ISO) precautionary statements

CLP Annex VI assigns 13 precautionary statements to DDT (ISO). They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Disposal

What has to happen to the contents and the empty container.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

DDT (ISO) name in 23 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български ДДТ (ISO) клофенотан (INN)дикофан1,1,1-трихлоро-2,2-бис(4-хлорофенил)етандихлородифенилтрихлороетан
Spanish español DDT (ISO) clofenotano (DCI)dicofano1,1,1-tricloro-2,2-bis(4-clorofenil)etanodiclorodifeniltricloroetano
Czech čeština DDT (ISO) klofenotan (INN)dikofan1,1,1-trichlor-2,2- bis (4-chlorfenyl)ethandichlordifenyltrichlorethan
Danish dansk DDT (ikke anerkendt af ISO) clofenotan (INN)dicophan1,1,1-trichlor-2,2-bis(4-chlorphenyl)ethandichlordiphenyltrichlorethan
German Deutsch DDT (ISO) Clofenotan (INN)Dicophan1,1,1-Trichlor-2,2-bis(4-chlorphenyl)-ethanDichlorodiphenyltrichlorethan
Estonian eesti DDT (ISO) klofenotaan (INN)dikofaan1,1,1-trikloro-2,2-bis(4-klorofenüül)etaandiklorodifenüültrikloroetaan
Greek ελληνικά DDT (ISO) clofenotane (κλοφαινοτάνη) (INN)δικοφάνιο1,1,1-τριχλωρο-2,2-δις(4-χλωροφαινυλ)αιθάνιοδιχλωροδιφαινυλοτριχλωροαιθάνιο
English English DDT (ISO) clofenotane (INN)dicophane1,1,1-trichloro-2,2-bis(4-chlorophenyl)ethanedichlorodiphenyltrichloroethane
French français DDT (ISO) clofénotane (INN)dicophane1,1,1-trichloro-2,2-bis(4-chlorophényl)éthanedichlorodiphényltrichloroéthane
Croatian hrvatski DDT (ISO) klofenotan (INN)dikofan1,1,1-triklor-2,2-bis(4-klorfenil)etandiklordifenil-trikloretan
Italian italiano DDT (ISO) clofenotano (INN)dicofano1,1,1-tricloro-2,2-bis(4-clorofenil)etanodiclorodifeniltricloroetano
Latvian latviešu DDT (ISO) klofenotāns (INN)dikofāns1,1,1-trihlor-2,2-bis(4-hlorfenil)etānsdihlordifeniltrihloretāns
Lithuanian lietuvių DDT (ISO) klofenotanas (INN)dikofanas1,1,1-trichlor-2,2-bis(4-chlorfenil)etanasdichlordifeniltrichloetanas
Hungarian magyar DDT (ISO) klofenotán (INN)dikofán1,1,1-triklór-2,2-bisz(4-klórfenil)etándiklordifeniltriklóretán
Maltese Malti DDT (ISO) klofenotan (INN)dikofan1,1,1-trikloro-2,2-bis(4-klorofenil)etandiklorodifeniltrikloroetan
Dutch Nederlands DDT (ISO) clofenotaan (INN)dicofaan1,1,1-trichloor-2,2-bis(4-chloorfenyl)ethaandichloordifenyltrichloorethaan
Polish polski DDT (ISO) klofenotan (INN)dikofan1,1,1-trichloro-2,2-bis(4-chlorofenylo)etandichlorodifenylotrichloroetan
Portuguese português DDT (ISO) clofenotano (DCI)dicofano1,1,1-tricloro-2,2-bis(4-clorofenil)etanodiclorodifeniltricloroetano
Romanian română DDT (ISO) clofenotan (INN)dicofan1,1,1-triclor-2,2-bis(4-clorofenil)etandicloridifeniltricloroetan
Slovak slovenčina DDT (ISO) klofenotán (INN)dikofán1,1,1-trichlór-2,2-bis(4-chlórfenyl)etándichlórdifenyltrichlóretán
Slovenian slovenščina DDT (ISO) klofenotan (INN)dikofan1,1,1-trikloro-2,2-bis(4-klorofenil)etandiklorodifeniltrikloroetan
Finnish suomi DDT (ISO) klofenotaani (INN)dicophane1,1,1-trikloori-2,2-bis(4-kloorifenyyli)etaanidiklooridifenyylitrikloorietaani
Swedish svenska DDT (ISO) klofenotan (INN)dikofan1,1,1-triklor-2,2-bis(4-klorfenyl)etandiklordifenyltrikloretan

All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

DDT (ISO) GHS label elements

Everything CLP Annex VI fixes for DDT (ISO), laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS06 Skull and crossbones pictogramGHS08 Health hazard pictogramGHS09 Environment pictogram

Danger

DDT (ISO)

  • Suspected of causing cancer <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
  • Toxic if swallowed.
  • Causes damage to organs <or state all organs affected, if known> through prolonged or repeated exposure <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
  • Very toxic to aquatic life.
  • Very toxic to aquatic life with long lasting effects.
  • Obtain special instructions before use.
  • Do not breathe dust/fume/gas/mist/vapours/spray.
  • Do not eat, drink or smoke when using this product.
  • Avoid release to the environment.
  • Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/
  • IF SWALLOWED:
  • IF exposed or concerned:
  • Immediately call a POISON CENTER/doctor/
  • Get medical advice/attention.
  • Get medical advice/attention if you feel unwell.
  • Rinse mouth.
  • Collect spillage.
  • Dispose of contents/container to

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open DDT (ISO) in the GHS label constructor →

07 · Health hazards

DDT (ISO) health hazards and exposure limits

DDT (ISO) hazard summary

Still used in some parts of the world, DDT persists in the environment and in animal tissues. It has been especially harmful to predator species of birds. High-dose animal studies show that organochlorine insecticides are toxic to the liver. [LaDou, p. 553] Allergic contact dermatitis reported in farmworkers; [Kanerva, p. 1777] Despite the billions of pounds of DDT that have been manufactured and used, hepatic injury acquired as the result of occupational or environmental exposure to it remains to be reported. [Zimmerman, p. 413]

Source: Haz-Map, Information on Hazardous Chemicals and Occupational Diseases

DDT (ISO) carcinogenicity classification

IARC classification Group 2A — Probably carcinogenic to humans
IARC monographs Volume 53: (1991) Occupational Exposures in Insecticide Application, and Some Pesticides; Volume 113: (2018) DDT, Lindane, and 2,4-D

Under the conditions of these bioassays there was no evidence for the carcinogenicity of DDT in Osborne-Mendel rats or B6C3F1 mice, of TDE in female Osborne-Mendel rats or B6C3F1 mice of either sex, or of p,p'-DDE in Osborne-Mendel rats, although p,p'-DDE was hepatotoxic in Osborne-Mendel rats. The findings suggest a possible carcinogenic effect of TDE in male Osborne-Mendel rats, based on the induction of combined follicular-cell carcinomas and follicular-cell adenomas of the thyroid. Because of the variation of these tumors in control male rats in this study, the evidence does not permit a more conclusive interpretation of these lesions. p,p'-DDE was carcinogenic in B6C3F1 mice, causing hepatocellular carcinomas in both sexes.

Source: US National Toxicology Program · TR-131: Bioassays of DDT, TDE, and p,p'-DDE for Possible Carcinogenicity (CASRN 50-29-3, CASRN 72-54-8, CASRN 72-55-9) (1978 )

Evaluation: There is inadequate evidence in humans for the carcinogenicity of DDT. There is sufficient evidence in experimental animals for the carcinogenicity of DDT. Overall evaluation: DDT is possibly carcinogenic to humans (2B).

Source: Hazardous Substances Data Bank (HSDB)

DDT: reasonably anticipated to be a human carcinogen.

Source: Hazardous Substances Data Bank (HSDB)

An IARC group and a CLP classification answer different questions. IARC judges whether the evidence for cancer in humans is strong enough; CLP Annex VI is the legally binding EU classification. A substance can carry one and not the other.

DDT (ISO) occupational exposure limits

US occupational exposure limits reported for DDT (ISO). PEL is enforceable (OSHA), REL is a recommendation (NIOSH), IDLH is the concentration at which escape becomes impossible without injury.
Limit Value Source
PEL 1.0 [mg/m3] Haz-Map, Information on Hazardous Chemicals and Occupational Diseases
PEL TWA 1 mg/m3 [skin] The National Institute for Occupational Safety and Health (NIOSH)
REL Ca TWA 0.5 mg/m3 See Appendix A The National Institute for Occupational Safety and Health (NIOSH)
IDLH 500 mg/m3 ; A potential occupational carcinogen. (NIOSH, 2024) CAMEO Chemicals
IDLH 500.0 [mg/m3] Haz-Map, Information on Hazardous Chemicals and Occupational Diseases
IDLH NIOSH considers DDT to be a potential occupational carcinogen. Hazardous Substances Data Bank (HSDB)

These are United States values. The European Union sets its own indicative and binding limits, and the figure that applies at a given workplace is the one in the local regulation — not the one shown here.

08 · Physical and chemical properties

DDT (ISO) properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

DDT (ISO) boiling point

Property Value Conditions Source
Boiling point 260 °C (500 °F) at 760 mmHg CAMEO
260 °C (500 °F) ICSC

DDT (ISO) melting point

Property Value Conditions Source
Melting point 108.5 °C (227.3 °F) HSDB
108.33 °C (227 °F) NIOSH
109 °C (228.2 °F) ICSC

DDT (ISO) density

Property Value Conditions Source
Density 0.99 g/cm³ NIOSH
1.6 g/cm³ ICSC
0.985 g/cm³ range, midpoint shown HSDB

DDT (ISO) solubility

Property Value Conditions Source
Solubility Soluble in acetone, ether, benzene, carbon tetrachloride, kerosene, dioxane, and pyridine. HSDB
High solubility in fat (100,000 ppm) HSDB

DDT (ISO) vapor pressure

Property Value Conditions Source
Vapor pressure 2e-7 mmHg NIOSH
1.6e-7 mmHg at 20 °C HSDB
1.5e-7 mmHg at 20 °C CAMEO

DDT (ISO) flash point

Property Value Conditions Source
Flash point 75 °C (167 °F) closed cup HSDB
74.72 °C (166.5 °F) range, midpoint shown HSDB

DDT (ISO) lower explosive limit (LEL)

Property Value Conditions Source
Lower explosive limit (LEL) Contact with strong oxidizers may cause fire and explosion hazard. HSDB
Combustible Solid NIOSH

DDT (ISO) odor threshold

Property Value Conditions Source
Odor threshold Detection threshold in water: 0.35 ppm HSDB
Odor high 5.0725 mg/cu m; odor low 5.0725 mg/cu m. HSDB

DDT (ISO) corrosivity

Property Value Conditions Source
Corrosivity Should not be kept in iron containers HSDB

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

09 · Fire and explosion

DDT (ISO) fire and explosion behaviour

These are descriptions rather than measured values, so they are kept out of the table above and quoted here with the source that reported them.

DDT (ISO) fire potential

Behavior in fire: Melts and burns.

Source: Hazardous Substances Data Bank (HSDB)

Solubility

Solubility, g/100 mL solvent: 58 acetone; 78 benzene; 42 benzyl benzoate; 45 carbon tetrachloride; 74 chlorobenzene; 116 cyclohexanone; 2 g/100 ml 95% alcohol; 28 ethyl ether; 10 gasoline; 3 isopropanol; 8-10 kerosene; 75 morpholine; 11 peanut oil; 10-16 pine oil; 61 tetralin; 50 tributyl phosphate.

Source: HSDB

10 · Handling and storage

DDT (ISO) storage and handling

DDT (ISO) safe storage

Provision to contain effluent from fire extinguishing. Separated from iron, aluminium, aluminium salts and food and feedstuffs. See Chemical Dangers.

Source: ILO-WHO International Chemical Safety Cards (ICSCs)

DDT (ISO) storage conditions

... Should not be kept in iron containers and should not be mixed with iron and aluminum salts nor with alkaline substances. High storage temperatures should also be avoided.

Source: Hazardous Substances Data Bank (HSDB)

DDT (ISO) incompatible materials

Strong oxidizers, alkalis.

Source: Hazardous Substances Data Bank (HSDB)

DDT (ISO) reactivity

DDT may react with iron, aluminum, aluminum and iron salts, and alkalis. It is incompatible with ferric chloride and aluminum chloride. It can also react with strong oxidizing materials. (NTP, 1992).

Source: CAMEO Chemicals

Planning storage for a mix of chemicals? Check DDT (ISO) in the storage compatibility matrix →

11 · Questions

DDT (ISO) — frequently asked questions

What is the CAS number of DDT (ISO)?

The CAS number of DDT (ISO) is 50-29-3. Its EC number is 200-024-3.

What is the chemical formula of DDT (ISO)?

The molecular formula of DDT (ISO) is C14H9Cl5 and its molecular weight is 354.5 g/mol.

What does a DDT (ISO) label have to show?

Under CLP Annex VI the label for DDT (ISO) carries the pictograms Skull and crossbones, Health hazard and Environment and the signal word is Danger.

Is DDT (ISO) flammable?

CLP Annex VI assigns DDT (ISO) no flammability hazard class. That is not a statement that it cannot burn: the harmonised list only records the hazards that were assessed for it. The flash point reported for it is 75 °C (167 °F), closed cup (HSDB).

Is DDT (ISO) a carcinogen?

CLP Annex VI assigns DDT (ISO) H351 — suspected of causing cancer. That is category 2: the evidence points that way but is not conclusive. IARC places it in Group 2A: probably carcinogenic to humans.

What is the exposure limit for DDT (ISO)?

The US occupational exposure limit reported for DDT (ISO) is 1.0 [mg/m3] (Haz-Map, Information on Hazardous Chemicals and Occupational Diseases). Limits differ by country: the EU sets its own indicative and binding values, and the figure that applies at a given workplace is the one in the local regulation.

What is the boiling point of DDT (ISO)?

The boiling point reported for DDT (ISO) is 260 °C (500 °F), at 760 mmHg (CAMEO).

What is the melting point of DDT (ISO)?

The melting point reported for DDT (ISO) is 108.5 °C (227.3 °F) (HSDB).

How should DDT (ISO) be stored?

... Should not be kept in iron containers and should not be mixed with iron and aluminum salts nor with alkaline substances. High storage temperatures should also be avoided. (Hazardous Substances Data Bank (HSDB))

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