Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

Di-allate

Di-allate is a brown liquid.

CAS 2303-16-4 C10H17Cl2NOS 270.22 g/mol Warning

01 · Identification

What Di-allate is

Di-allate is a brown liquid. Its molecular formula is C10H17Cl2NOS and its molecular weight is 270.22 g/mol. It melts at 27.5 °C.

Under the GHS it carries the signal word Warning.

02 · Identifiers

Di-allate identifiers and molecular data

Di-allate CAS number and EC number

CAS number2303-16-4
EC number218-961-1
Index number (CLP Annex VI)006-019-00-0

Di-allate molecular formula and molecular weight

Molecular formulaC10H17Cl2NOS
Molecular weight270.22 g/mol

Other names for Di-allate

  • di-allate (ISO)
  • S-(2,3-dichloroallyl)-N,N-diisopropylthiocarbamate

03 · GHS classification

Di-allate hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

Di-allate pictograms and signal word

Signal wordWarning

Di-allate hazard class and category

GHS hazard classes Di-allate falls into
Hazard class Category From code Pictogram
Acute toxicity - oral GHS chapter 3.1 Category 4 H302 GHS07
Carcinogenicity GHS chapter 3.6 Category 2 H351 GHS08
Hazardous to the aquatic environment - acute GHS chapter 4.1 Category 1 H400 GHS09
Hazardous to the aquatic environment - chronic GHS chapter 4.1 Category 1 H410 GHS09

Di-allate hazard statements (H-codes)

Hazard statements assigned to Di-allate
CodeHazard statement
H351 Suspected of causing cancer <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
H302 Harmful if swallowed.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.

This page lists only the codes assigned to Di-allate. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for Di-allate

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of Di-allate issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

04 · Precautionary statements

Di-allate precautionary statements

CLP Annex VI assigns 11 precautionary statements to Di-allate. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Disposal

What has to happen to the contents and the empty container.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

Di-allate name in 23 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български ди-алат (ISO) S -(2,3-дихлороалил)- N , N -диизопропилтиокарбамат
Spanish español Dialato (ISO) N , N -Diisopropiltiocarbamato de S -(2,3-dicloroalilo)
Czech čeština diallát (ISO) S -(2,3-dichlorallyl)- N, N -diisopropylthiokarbamát
Danish dansk di-allat (ISO) S -2,3-dichlorallyldiisopropylthiocarbamat
German Deutsch Diallat (ISO) S -(2,3-Dichlorallyl)- N, N -diisopropylthiocarbamat
Estonian eesti diallaat (ISO) S -(2,3-dikloroallüül)- N , N -diisopropüültiokarbamaat
Greek ελληνικά di-allate (δι-αλλάτη) (ISO) N , N -διισοπροπυλοθειοκαρβαμιδικός S -(2,3-διχλωραλλυλ)εστέρας
English English di-allate (ISO) S -(2,3-dichloroallyl)- N , N -diisopropylthiocarbamate
French français diallate (ISO) S -(2,3-dichloroallyl)- N , N -diisopropylthiocarbamate
Croatian hrvatski di-alat (ISO) S -(2,3-dikloralil)- N , N -diizopropiltiokarbamat
Italian italiano diallate (ISO) diisopropiltiocarbammato di S-2,3-dicloroallile
Latvian latviešu diallāts (ISO) S -(2,3-dihloralil)- N , N -diizopropiltiokarbamāts
Lithuanian lietuvių dialatas (ISO) S -(2,3-dichloralil)- N , N -diizopropiltiokarbamatas
Hungarian magyar diallát (ISO) S -(2,3-diklórallil)- N , N - diizopropil-tiokarbamát
Maltese Malti diallat (ISO) S -(2,3-dikloroallil)- N , N -diisopropiltijokarbamat
Dutch Nederlands diallaat (ISO) S -(2,3-dichloorallyl)- N , N -diisopropylthiocarbamaat
Polish polski dialat (ISO) N , N -diizopropylotiokarbaminian S -2,3-dichloroallilu
Portuguese português di-alato (ISO) N , N -diisopropiltiocarbamato de S -(2,3-dicloroalilo)
Romanian română dialat (ISO) tiocarbamat de S -(2,3-dicloralil)- N , N - diizopropil
Slovak slovenčina di-alát (ISO) S -(2,3-dichlóralyl)- N, N -diizopropyltiokarbamát
Slovenian slovenščina di-alat (ISO) S -(2,3-dikloroalil)- N , N -diizopropiltiokarbamat
Finnish suomi di-allaatti (ISO) S -2,3-diklooriallyyli- N, N -di-isopropyylitiokarbamaatti
Swedish svenska di-allat (ISO) S -(2,3-diklorallyl)- N , N -diisopropyltiokarbamat

All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

Di-allate GHS label elements

Everything CLP Annex VI fixes for Di-allate, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS08 Health hazard pictogramGHS07 Exclamation mark pictogramGHS09 Environment pictogram

Warning

Di-allate

  • Suspected of causing cancer <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
  • Harmful if swallowed.
  • Very toxic to aquatic life.
  • Very toxic to aquatic life with long lasting effects.
  • Obtain special instructions before use.
  • Do not eat, drink or smoke when using this product.
  • Avoid release to the environment.
  • Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/
  • IF SWALLOWED:
  • IF exposed or concerned:
  • Call a POISON CENTER/doctor/ if you feel unwell.
  • Get medical advice/attention.
  • Rinse mouth.
  • Collect spillage.
  • Dispose of contents/container to

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open Di-allate in the GHS label constructor →

07 · Health hazards

Di-allate health hazards and exposure limits

Di-allate hazard summary

Commercial product contains approximately equal parts of the cis- and trans- isomers;[HSDB] See Diallate.

Source: Haz-Map, Information on Hazardous Chemicals and Occupational Diseases

Di-allate carcinogenicity classification

IARC classification Group 3 — Not classifiable as to its carcinogenicity to humans
IARC monographs Volume 30: (1983) Miscellaneous Pesticides

The Human Health Assessment Group in EPA's Office of Health and Environmental Assessment has evaluated diallate for carcinogenicity. According to their analysis, the weight-of-evidence for diallate is group C, which is based on limited evidence in animals. No data is available in human. As a group C chemical, diallate is considered to be a possible human carcinogen.

Source: Hazardous Substances Data Bank (HSDB)

No data are available in humans. Limited evidence of carcinogenicity in animals. OVERALL EVALUATION: Group 3: The agent is not classifiable as to its carcinogenicity to humans.

Source: Hazardous Substances Data Bank (HSDB)

An IARC group and a CLP classification answer different questions. IARC judges whether the evidence for cancer in humans is strong enough; CLP Annex VI is the legally binding EU classification. A substance can carry one and not the other.

08 · Physical and chemical properties

Di-allate properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

Di-allate boiling point

Property Value Conditions Source
Boiling point 150 °C (302 °F) at 9 mmHg (reduced pressure) HSDB

Di-allate melting point

Property Value Conditions Source
Melting point 27.5 °C (81.5 °F) range, midpoint shown HSDB

Di-allate density

Property Value Conditions Source
Density 1.188 g/cm³ at 25 °C HSDB

Di-allate solubility

Property Value Conditions Source
Solubility SOL IN ACETONE, BENZENE, CHLOROFORM, ETHER, & HEPTANE HSDB
SOL IN WATER 14 PPM @ 25 °C at 25 °C HSDB
MISCIBLE WITH ETHANOL & ISOPROPYL ALCOHOL. MISCIBLE IN XYLENE, KEROSENE, & ETHYL ACETATE @ 25 °C. at 25 °C HSDB

Di-allate vapor pressure

Property Value Conditions Source
Vapor pressure 0.00015 mmHg at 25 °C HSDB
0.00015 mmHg Haz-Map

Di-allate flash point

Property Value Conditions Source
Flash point 77 °C (170.6 °F) closed cup HSDB
77 °C (170.6 °F) Haz-Map

Di-allate corrosivity

Property Value Conditions Source
Corrosivity NONCORROSIVE HSDB

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

09 · Fire and explosion

Di-allate fire and explosion behaviour

These are descriptions rather than measured values, so they are kept out of the table above and quoted here with the source that reported them.

Di-allate fire potential

Nonflammable

Source: Hazardous Substances Data Bank (HSDB)

10 · Handling and storage

Di-allate storage and handling

Di-allate storage conditions

Rooms used for storage only should be soundly constructed and fitted with secure locks. Floors should be kept clear and the pesticides clearly identified. /Pesticides/

Source: Hazardous Substances Data Bank (HSDB)

Di-allate reactivity

DIALLATE is a thiocarbamate ester. Flammable gases are generated by the combination of thiocarbamates and dithiocarbamates with aldehydes, nitrides, and hydrides. Thiocarbamates and dithiocarbamates are incompatible with acids, peroxides, and acid halides.

Source: CAMEO Chemicals

Planning storage for a mix of chemicals? Check Di-allate in the storage compatibility matrix →

11 · Questions

Di-allate — frequently asked questions

What is the CAS number of Di-allate?

The CAS number of Di-allate is 2303-16-4. Its EC number is 218-961-1.

What is the chemical formula of Di-allate?

The molecular formula of Di-allate is C10H17Cl2NOS and its molecular weight is 270.22 g/mol.

What does a Di-allate label have to show?

Under CLP Annex VI the label for Di-allate carries the pictograms Health hazard, Exclamation mark and Environment and the signal word is Warning.

Is Di-allate flammable?

CLP Annex VI assigns Di-allate no flammability hazard class. That is not a statement that it cannot burn: the harmonised list only records the hazards that were assessed for it. The flash point reported for it is 77 °C (170.6 °F), closed cup (HSDB).

Is Di-allate a carcinogen?

CLP Annex VI assigns Di-allate H351 — suspected of causing cancer. That is category 2: the evidence points that way but is not conclusive. IARC places it in Group 3: not classifiable as to its carcinogenicity to humans.

What is the boiling point of Di-allate?

The boiling point reported for Di-allate is 150 °C (302 °F), at 9 mmHg (reduced pressure) (HSDB).

What is the melting point of Di-allate?

The melting point reported for Di-allate is 27.5 °C (81.5 °F), range, midpoint shown (HSDB).

How should Di-allate be stored?

Rooms used for storage only should be soundly constructed and fitted with secure locks. Floors should be kept clear and the pesticides clearly identified. /Pesticides/ (Hazardous Substances Data Bank (HSDB))

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