Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

DIBENZ(a,h)ANTHRACENE

DIBENZ(a,h)ANTHRACENE is colorless plates or leaflets from acetic acid.

CAS 53-70-3 C22H14 278.3 g/mol Danger

01 · Identification

What DIBENZ(a,h)ANTHRACENE is

DIBENZ(a,h)ANTHRACENE is colorless plates or leaflets from acetic acid. Its molecular formula is C22H14 and its molecular weight is 278.3 g/mol. It boils at 524 °C, melts at 269 °C.

Under the GHS it carries the signal word Danger. It is classed as carcinogens.

02 · Identifiers

DIBENZ(a,h)ANTHRACENE identifiers and molecular data

DIBENZ(a,h)ANTHRACENE CAS number and EC number

CAS number53-70-3
EC number200-181-8
Index number (CLP Annex VI)601-041-00-2

DIBENZ(a,h)ANTHRACENE molecular formula and molecular weight

Molecular formulaC22H14
Molecular weight278.3 g/mol
Chemical class Carcinogens

Other names for DIBENZ(a,h)ANTHRACENE

  • dibenz[a,h]anthracene

03 · GHS classification

DIBENZ(a,h)ANTHRACENE hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

DIBENZ(a,h)ANTHRACENE pictograms and signal word

Signal wordDanger

DIBENZ(a,h)ANTHRACENE hazard class and category

GHS hazard classes DIBENZ(a,h)ANTHRACENE falls into
Hazard class Category From code Pictogram
Carcinogenicity GHS chapter 3.6 Category 1A or 1B H350 GHS08
Hazardous to the aquatic environment - acute GHS chapter 4.1 Category 1 H400 GHS09
Hazardous to the aquatic environment - chronic GHS chapter 4.1 Category 1 H410 GHS09

Where two values are shown with “or”, the hazard statement is shared by more than one category or by more than one class, and the code alone does not say which. H272, for example, belongs to oxidising liquids and to oxidising solids — the physical state decides. The binding answer for a specific entry is in the CLP Annex VI table itself.

DIBENZ(a,h)ANTHRACENE hazard statements (H-codes)

Hazard statements assigned to DIBENZ(a,h)ANTHRACENE
CodeHazard statement
H350 May cause cancer <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.

This page lists only the codes assigned to DIBENZ(a,h)ANTHRACENE. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for DIBENZ(a,h)ANTHRACENE

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of DIBENZ(a,h)ANTHRACENE issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

04 · Precautionary statements

DIBENZ(a,h)ANTHRACENE precautionary statements

CLP Annex VI assigns 7 precautionary statements to DIBENZ(a,h)ANTHRACENE. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Response

What to do once exposure, spillage or fire has already happened.

Disposal

What has to happen to the contents and the empty container.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

DIBENZ(a,h)ANTHRACENE name in 23 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български дибенз[ a , h ]антрацен
Spanish español Dibenz[ a , h ]antraceno
Czech čeština dibenzo[ a, h ]anthracen
Danish dansk dibenzo[ a, h ]anthracen
German Deutsch Dibenzo[ a , h ]anthracen
Estonian eesti dibens[ a , h ]antratseen
Greek ελληνικά διβενζο[ a , h ]ανθρακένιο
English English dibenz[ a , h ]anthracene
French français dibenz[ a , h ]anthracène
Croatian hrvatski dibenz[ a , h ]antracen
Italian italiano dibenzo[ a , h ]antracene
Latvian latviešu dibenz[ a , h ]antracēns
Lithuanian lietuvių dibenz[ a , h ]antracenas
Hungarian magyar dibenz[ a , h ]antracén
Maltese Malti dibenż[ a , h ]antraċen
Dutch Nederlands dibenzo[ a , h ]antraceen
Polish polski dibenzo[a, h]antracen
Portuguese português dibenzo[ a , h ]antraceno
Romanian română dibenzo[ a , h ]antracen
Slovak slovenčina dibenzo[ a, h ]antracén
Slovenian slovenščina dibenz[ a , h ]antracen
Finnish suomi dibentso[ a, h ]antraseeni
Swedish svenska dibens[ a , h ]antracen

All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

DIBENZ(a,h)ANTHRACENE GHS label elements

Everything CLP Annex VI fixes for DIBENZ(a,h)ANTHRACENE, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS08 Health hazard pictogramGHS09 Environment pictogram

Danger

DIBENZ(a,h)ANTHRACENE

  • May cause cancer <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
  • Very toxic to aquatic life.
  • Very toxic to aquatic life with long lasting effects.
  • Obtain special instructions before use.
  • Avoid release to the environment.
  • Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/
  • IF exposed or concerned:
  • Get medical advice/attention.
  • Collect spillage.
  • Dispose of contents/container to

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open DIBENZ(a,h)ANTHRACENE in the GHS label constructor →

07 · Health hazards

DIBENZ(a,h)ANTHRACENE health hazards and exposure limits

DIBENZ(a,h)ANTHRACENE hazard summary

May cause skin photosensitization; A probable human carcinogen; Can be absorbed through skin; [ICSC] Evidence of carcinogenicity, mutagenicity, developmental toxicity, and immunosuppression in experimental animals; Emergency treatment: Polynuclear aromatic hydrocarbons; Acute toxicity of PAHs is low; May cause photosensitivity; May cause cancer after chronic exposure; [HSDB] Causes decreased humoral immune response and changes in hepatic microsomal mixed oxidase in oral toxic-dose studies of mice; [RTECS] May cause skin and eye irritation; [Cerilliant MSDS] See POLYCYCLIC AROMATIC HYDROCARBONS.

Source: Haz-Map, Information on Hazardous Chemicals and Occupational Diseases

DIBENZ(a,h)ANTHRACENE carcinogenicity classification

IARC classification Group 2A — Probably carcinogenic to humans
IARC monographs Volume 92: (2010) Some Non-heterocyclic Polycyclic Aromatic Hydrocarbons and Some Related Exposures

No data are available in humans. Sufficient evidence of carcinogenicity in animals. OVERALL EVALUATION: Group 2A: The agent is probably carcinogenic to humans.

Source: Hazardous Substances Data Bank (HSDB)

Dibenz(a,h)anthracene: reasonably anticipated to be a human carcinogen. /Polycyclic Aromatic Hydrocarbons/

Source: Hazardous Substances Data Bank (HSDB)

An IARC group and a CLP classification answer different questions. IARC judges whether the evidence for cancer in humans is strong enough; CLP Annex VI is the legally binding EU classification. A substance can carry one and not the other.

DIBENZ(a,h)ANTHRACENE occupational exposure limits

US occupational exposure limits reported for DIBENZ(a,h)ANTHRACENE. PEL is enforceable (OSHA), REL is a recommendation (NIOSH), IDLH is the concentration at which escape becomes impossible without injury.
Limit Value Source
IDLH NIOSH considers coal tar pitch volatiles to be potential occupational carcinogens. /Coal tar pitch volatiles/ Hazardous Substances Data Bank (HSDB)

These are United States values. The European Union sets its own indicative and binding limits, and the figure that applies at a given workplace is the one in the local regulation — not the one shown here.

08 · Physical and chemical properties

DIBENZ(a,h)ANTHRACENE properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

DIBENZ(a,h)ANTHRACENE boiling point

Property Value Conditions Source
Boiling point 524 °C (975.2 °F) HSDB
523.89 °C (975 °F) at 760 mmHg CAMEO

DIBENZ(a,h)ANTHRACENE melting point

Property Value Conditions Source
Melting point 269 °C (516.2 °F) HSDB
214 °C (417.2 °F) HSDB
267 °C (512.6 °F) ICSC

DIBENZ(a,h)ANTHRACENE density

Property Value Conditions Source
Density 1.282 g/cm³ HSDB
1.28 g/cm³ HSDB

DIBENZ(a,h)ANTHRACENE solubility

Property Value Conditions Source
Solubility In water, 0.00166 mg/L at 24-25 °C (average of 5 measured values ranging from 0.0005 to 0.00249) HSDB
In water, 2.49X10-3 mg/L at 25 °C at 25 °C HSDB
In water, 0.000627 mg/L at 25 °C at 25 °C HSDB

DIBENZ(a,h)ANTHRACENE vapor pressure

Property Value Conditions Source
Vapor pressure 1e-10 mmHg at 20 °C, estimated CAMEO
9.55e-10 mmHg at 25 °C HSDB

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

09 · Fire and explosion

DIBENZ(a,h)ANTHRACENE fire and explosion behaviour

These are descriptions rather than measured values, so they are kept out of the table above and quoted here with the source that reported them.

DIBENZ(a,h)ANTHRACENE fire potential

This chemical is a combustible solid.

Source: Hazardous Substances Data Bank (HSDB)

10 · Handling and storage

DIBENZ(a,h)ANTHRACENE storage and handling

DIBENZ(a,h)ANTHRACENE safe storage

Well closed. Store in an area without drain or sewer access. Provision to contain effluent from fire extinguishing.

Source: ILO-WHO International Chemical Safety Cards (ICSCs)

DIBENZ(a,h)ANTHRACENE storage conditions

Keep container tightly closed in a dry and well-ventilated place. Storage class (TRGS 510): Non-combustible, acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects.[Sigma-Aldrich; Safety Data Sheet for Dibenz

Source: Hazardous Substances Data Bank (HSDB)

DIBENZ(a,h)ANTHRACENE incompatible materials

Incompatible materials: Strong oxidizing agents.[Sigma-Aldrich; Safety Data Sheet for Dibenz

Source: Hazardous Substances Data Bank (HSDB)

DIBENZ(a,h)ANTHRACENE reactivity

DIBENZ[A,H]ANTHRACENE is incompatible with strong oxidizing agents. Is oxidized by chromic acid and by osmium tetraoxide (NTP, 1992).

Source: CAMEO Chemicals

Planning storage for a mix of chemicals? Check DIBENZ(a,h)ANTHRACENE in the storage compatibility matrix →

11 · Questions

DIBENZ(a,h)ANTHRACENE — frequently asked questions

What is the CAS number of DIBENZ(a,h)ANTHRACENE?

The CAS number of DIBENZ(a,h)ANTHRACENE is 53-70-3. Its EC number is 200-181-8.

What is the chemical formula of DIBENZ(a,h)ANTHRACENE?

The molecular formula of DIBENZ(a,h)ANTHRACENE is C22H14 and its molecular weight is 278.3 g/mol.

What does a DIBENZ(a,h)ANTHRACENE label have to show?

Under CLP Annex VI the label for DIBENZ(a,h)ANTHRACENE carries the pictograms Health hazard and Environment and the signal word is Danger.

Is DIBENZ(a,h)ANTHRACENE flammable?

CLP Annex VI assigns DIBENZ(a,h)ANTHRACENE no flammability hazard class. That is not a statement that it cannot burn: the harmonised list only records the hazards that were assessed for it.

Is DIBENZ(a,h)ANTHRACENE a carcinogen?

Yes. CLP Annex VI classifies DIBENZ(a,h)ANTHRACENE as a category 1A or 1B carcinogen and assigns it H350: may cause cancer. IARC places it in Group 2A: probably carcinogenic to humans.

What is the boiling point of DIBENZ(a,h)ANTHRACENE?

The boiling point reported for DIBENZ(a,h)ANTHRACENE is 524 °C (975.2 °F) (HSDB).

What is the melting point of DIBENZ(a,h)ANTHRACENE?

The melting point reported for DIBENZ(a,h)ANTHRACENE is 269 °C (516.2 °F) (HSDB).

How should DIBENZ(a,h)ANTHRACENE be stored?

Keep container tightly closed in a dry and well-ventilated place. Storage class (TRGS 510): Non-combustible, acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects.[Sigma-Aldrich; Safety Data Sheet for Dibenz (Hazardous Substances Data Bank (HSDB))

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