Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

Dieldrin

Dieldrin is colorless crystals with a mild, chemical odor.

CAS 60-57-1 C12H8Cl6O 380.9 g/mol Danger

01 · Identification

What Dieldrin is

Dieldrin is colorless crystals with a mild, chemical odor. Its molecular formula is C12H8Cl6O and its molecular weight is 380.9 g/mol. It melts at 176 °C, is soluble in water.

Under the GHS it carries the signal word Danger. It is classed as carcinogens.

02 · Identifiers

Dieldrin identifiers and molecular data

Dieldrin CAS number and EC number

CAS number60-57-1
EC number200-484-5
Index number (CLP Annex VI)602-049-00-9

Dieldrin molecular formula and molecular weight

Molecular formulaC12H8Cl6O
Molecular weight380.9 g/mol
Chemical class Carcinogens

Other names for Dieldrin

  • dieldrin (ISO)

03 · GHS classification

Dieldrin hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

Dieldrin pictograms and signal word

Signal wordDanger

Dieldrin hazard class and category

GHS hazard classes Dieldrin falls into
Hazard class Category From code Pictogram
Acute toxicity - oral GHS chapter 3.1 Category 3 H301 GHS06
Acute toxicity - dermal GHS chapter 3.1 Category 1 or 2 H310 GHS06
Carcinogenicity GHS chapter 3.6 Category 2 H351 GHS08
Specific target organ toxicity - repeated exposure GHS chapter 3.9 Category 1 H372 GHS08
Hazardous to the aquatic environment - acute GHS chapter 4.1 Category 1 H400 GHS09
Hazardous to the aquatic environment - chronic GHS chapter 4.1 Category 1 H410 GHS09

Where two values are shown with “or”, the hazard statement is shared by more than one category or by more than one class, and the code alone does not say which. H272, for example, belongs to oxidising liquids and to oxidising solids — the physical state decides. The binding answer for a specific entry is in the CLP Annex VI table itself.

Dieldrin hazard statements (H-codes)

Hazard statements assigned to Dieldrin
CodeHazard statement
H351 Suspected of causing cancer <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
H310 Fatal in contact with skin.
H301 Toxic if swallowed.
H372 Causes damage to organs <or state all organs affected, if known> through prolonged or repeated exposure <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.

This page lists only the codes assigned to Dieldrin. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for Dieldrin

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of Dieldrin issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

04 · Precautionary statements

Dieldrin precautionary statements

CLP Annex VI assigns 15 precautionary statements to Dieldrin. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Disposal

What has to happen to the contents and the empty container.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

Dieldrin name in 23 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български диелдрин (ISO)
Spanish español Dieldrina (ISO)
Czech čeština dieldrin (ISO)
Danish dansk dieldrin (ISO)
German Deutsch Dieldrin (ISO)
Estonian eesti dieldriin (ISO)
Greek ελληνικά dieldrin (διελδρίνη) (ISO)
English English dieldrin (ISO)
French français dieldrine (ISO)
Croatian hrvatski dieldrin (ISO)
Italian italiano dieldrin (ISO)
Latvian latviešu dieldrīns (ISO)
Lithuanian lietuvių dieldrinas (ISO)
Hungarian magyar dieldrin (ISO)
Maltese Malti dieldrin (ISO)
Dutch Nederlands dieldrin (ISO)
Polish polski dieldryna (ISO)
Portuguese português dieldrina (ISO)
Romanian română dieldrin (ISO)
Slovak slovenčina dieldrín (ISO)
Slovenian slovenščina dieldrin (ISO)
Finnish suomi dieldriini (ISO)
Swedish svenska dieldrin (ISO)

All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

Dieldrin GHS label elements

Everything CLP Annex VI fixes for Dieldrin, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS06 Skull and crossbones pictogramGHS08 Health hazard pictogramGHS09 Environment pictogram

Danger

Dieldrin

  • Suspected of causing cancer <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
  • Fatal in contact with skin.
  • Toxic if swallowed.
  • Causes damage to organs <or state all organs affected, if known> through prolonged or repeated exposure <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
  • Very toxic to aquatic life.
  • Very toxic to aquatic life with long lasting effects.
  • Obtain special instructions before use.
  • Do not breathe dust/fume/gas/mist/vapours/spray.
  • Do not eat, drink or smoke when using this product.
  • Avoid release to the environment.
  • Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/
  • IF SWALLOWED:
  • IF ON SKIN:
  • IF exposed or concerned:
  • Immediately call a POISON CENTER/doctor/
  • Get medical advice/attention.
  • Get medical advice/attention if you feel unwell.
  • Rinse mouth.
  • Wash with plenty of water/
  • Collect spillage.
  • Dispose of contents/container to

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open Dieldrin in the GHS label constructor →

07 · Health hazards

Dieldrin health hazards and exposure limits

Dieldrin carcinogenicity classification

Studied by the US National Toxicology Program: TR-022: Bioassay of Dieldrin for Possible Carcinogenicity (CASRN 60-57-1) (1978 )

Cancer Classification: Group B2 Probable Human Carcinogen

Source: Hazardous Substances Data Bank (HSDB)

CLASSIFICATION: B2; probable human carcinogen. BASIS FOR CLASSIFICATION: Dieldrin is carcinogenic in seven strains of mice when administered orally. Dieldrin is structurally related to compounds (aldrin, chlordane, heptachlor, heptachlor epoxide, and chlorendic acid) which produce tumors in rodents. HUMAN CARCINOGENICITY DATA: Inadequate. ANIMAL CARCINOGENICITY DATA: Sufficient.

Source: Hazardous Substances Data Bank (HSDB)

An IARC group and a CLP classification answer different questions. IARC judges whether the evidence for cancer in humans is strong enough; CLP Annex VI is the legally binding EU classification. A substance can carry one and not the other.

Dieldrin occupational exposure limits

US occupational exposure limits reported for Dieldrin. PEL is enforceable (OSHA), REL is a recommendation (NIOSH), IDLH is the concentration at which escape becomes impossible without injury.
Limit Value Source
PEL 0.25 [mg/m3] Haz-Map, Information on Hazardous Chemicals and Occupational Diseases
PEL TWA 0.25 mg/m3 [skin] The National Institute for Occupational Safety and Health (NIOSH)
REL Ca TWA 0.25 mg/m3 [skin] See Appendix A The National Institute for Occupational Safety and Health (NIOSH)
IDLH 50 mg/m3 ; A potential occupational carcinogen. (NIOSH, 2024) CAMEO Chemicals
IDLH 50.0 [mg/m3] Haz-Map, Information on Hazardous Chemicals and Occupational Diseases
IDLH 50 mg/cu m; NIOSH has recommended that dieldrin be treated as a potential human carcinogen. Hazardous Substances Data Bank (HSDB)

These are United States values. The European Union sets its own indicative and binding limits, and the figure that applies at a given workplace is the one in the local regulation — not the one shown here.

08 · Physical and chemical properties

Dieldrin properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

Dieldrin boiling point

Property Value Conditions Source
Boiling point Decomposes decomposes NIOSH
Decomposes (NIOSH, 2024) decomposes CAMEO

Dieldrin melting point

Property Value Conditions Source
Melting point 175.5 °C (347.9 °F) HSDB
176.11 °C (349 °F) NIOSH

Dieldrin density

Property Value Conditions Source
Density 1.75 g/cm³ HSDB
1.75 g/cm³ at 20 °C CAMEO

Dieldrin solubility

Property Value Conditions Source
Solubility SLIGHTLY SOL IN MINERAL OILS, MODERATELY SOL IN ACETONE HSDB
Soluble in aromatic solvents; moderately soluble in acetone HSDB
Insol in methanol, aliphatic hydrocarbons; soluble in benzene HSDB

Dieldrin vapor pressure

Property Value Conditions Source
Vapor pressure 0.0000031 mmHg at 20 °C HSDB
0.00000589 mmHg at 25 °C HSDB
8e-7 mmHg at 25 °C NIOSH

Dieldrin lower explosive limit (LEL)

Property Value Conditions Source
Lower explosive limit (LEL) Noncombustible Solid NIOSH

Dieldrin vapor density

Property Value Conditions Source
Vapor density 13.2 (air = 1) HSDB

Dieldrin odor threshold

Property Value Conditions Source
Odor threshold 0.041 ppm HSDB

Dieldrin corrosivity

Property Value Conditions Source
Corrosivity Slightly corrosive to metals HSDB

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

09 · Fire and explosion

Dieldrin fire and explosion behaviour

These are descriptions rather than measured values, so they are kept out of the table above and quoted here with the source that reported them.

Dieldrin fire potential

Not flammable

Source: Hazardous Substances Data Bank (HSDB)

10 · Handling and storage

Dieldrin storage and handling

Dieldrin safe storage

Provision to contain effluent from fire extinguishing. Separated from food and feedstuffs and incompatible materials. See Chemical Dangers. Well closed. Keep in a well-ventilated room. Store in an area without drain or sewer access.

Source: ILO-WHO International Chemical Safety Cards (ICSCs)

Dieldrin storage conditions

Storage temp: ambient; venting: open (flame arrester) (for liquid form)

Source: Hazardous Substances Data Bank (HSDB)

Dieldrin incompatible materials

Strong oxidizers, active metals such as sodium, strong acids, phenols.

Source: Hazardous Substances Data Bank (HSDB)

Dieldrin reactivity

DIELDRIN is sensitive to mineral acids, acid catalysts, acid oxidizing agents and active metals. It reacts with phenols. This compound is also slightly corrosive to metals. It may react vigorously with strong oxidizers such as chlorine and permanganates and strong acids such as sulfuric or nitric. (NTP, 1992)

Source: CAMEO Chemicals

Planning storage for a mix of chemicals? Check Dieldrin in the storage compatibility matrix →

11 · Questions

Dieldrin — frequently asked questions

What is the CAS number of Dieldrin?

The CAS number of Dieldrin is 60-57-1. Its EC number is 200-484-5.

What is the chemical formula of Dieldrin?

The molecular formula of Dieldrin is C12H8Cl6O and its molecular weight is 380.9 g/mol.

What does a Dieldrin label have to show?

Under CLP Annex VI the label for Dieldrin carries the pictograms Skull and crossbones, Health hazard and Environment and the signal word is Danger.

Is Dieldrin flammable?

CLP Annex VI assigns Dieldrin no flammability hazard class. That is not a statement that it cannot burn: the harmonised list only records the hazards that were assessed for it.

Is Dieldrin a carcinogen?

CLP Annex VI assigns Dieldrin H351 — suspected of causing cancer. That is category 2: the evidence points that way but is not conclusive.

What is the exposure limit for Dieldrin?

The US occupational exposure limit reported for Dieldrin is 0.25 [mg/m3] (Haz-Map, Information on Hazardous Chemicals and Occupational Diseases). Limits differ by country: the EU sets its own indicative and binding values, and the figure that applies at a given workplace is the one in the local regulation.

What is the boiling point of Dieldrin?

The boiling point reported for Dieldrin is Decomposes, decomposes (NIOSH).

What is the melting point of Dieldrin?

The melting point reported for Dieldrin is 175.5 °C (347.9 °F) (HSDB).

How should Dieldrin be stored?

Storage temp: ambient; venting: open (flame arrester) (for liquid form) (Hazardous Substances Data Bank (HSDB))

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