Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

Diethylethanolamine

Diethylethanolamine is a colorless liquid with a nauseating odor.

CAS 100-37-8 C6H15NO 117.19 g/mol Danger

01 · Identification

What Diethylethanolamine is

Diethylethanolamine is a colorless liquid with a nauseating odor. Its molecular formula is C6H15NO and its molecular weight is 117.19 g/mol. It boils at 163 °C, melts at -70 °C, is miscible with water.

Under the GHS it carries the signal word Danger. It is classed as flammable agents - 2nd degree.

02 · Identifiers

Diethylethanolamine identifiers and molecular data

Diethylethanolamine CAS number and EC number

CAS number100-37-8
EC number202-845-2
Index number (CLP Annex VI)603-048-00-6

Diethylethanolamine molecular formula and molecular weight

Molecular formulaC6H15NO
Molecular weight117.19 g/mol
Chemical class Flammable agents - 2nd degree

Other names for Diethylethanolamine

  • 2-diethylaminoethanol
  • N,N-diethylethanolamine

03 · GHS classification

Diethylethanolamine hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

Diethylethanolamine pictograms and signal word

Signal wordDanger

Diethylethanolamine hazard class and category

GHS hazard classes Diethylethanolamine falls into
Hazard class Category From code Pictogram
Flammable liquids GHS chapter 2.6 Category 3 H226 GHS02
Acute toxicity - oral GHS chapter 3.1 Category 4 H302 GHS07
Acute toxicity - dermal GHS chapter 3.1 Category 4 H312 GHS07
Acute toxicity - inhalation GHS chapter 3.1 Category 4 H332 GHS07
Skin corrosion/irritation GHS chapter 3.2 Category 1A or 1B or 1C H314 GHS05

Where two values are shown with “or”, the hazard statement is shared by more than one category or by more than one class, and the code alone does not say which. H272, for example, belongs to oxidising liquids and to oxidising solids — the physical state decides. The binding answer for a specific entry is in the CLP Annex VI table itself.

Diethylethanolamine hazard statements (H-codes)

Hazard statements assigned to Diethylethanolamine
CodeHazard statement
H226 Flammable liquid and vapour.
H332 Harmful if inhaled.
H312 Harmful in contact with skin.
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.

This page lists only the codes assigned to Diethylethanolamine. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for Diethylethanolamine

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of Diethylethanolamine issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

04 · Precautionary statements

Diethylethanolamine precautionary statements

CLP Annex VI assigns 17 precautionary statements to Diethylethanolamine. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Storage

How the container has to be kept between uses.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

Diethylethanolamine name in 23 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български 2-диетиламиноетанол N , N -диетилетаноламин
Spanish español 2-Dietilaminoetanol N , N -dietiletanolamina
Czech čeština 2-(diethylamino)ethan-1-ol N, N -diethylethanolamin
Danish dansk 2-diethylaminoethanol N, N- diethylethanolamin
German Deutsch 2-Diethylaminoethanol N , N -diethylethanolamin
Estonian eesti 2-dietüülaminoetanool N , N -dietüületanoolamiin
Greek ελληνικά 2-διαιθυλαμινοαιθανόλη N , N -διαιθυλαιθανολαμίνη
English English 2-diethylaminoethanol N , N -diethylethanolamine
French français 2-diéthylaminoéthanol N , N -diéthyléthanolamine
Croatian hrvatski 2-dietilaminoetanol N , N -dietiletanolamin
Italian italiano 2- dietilaminoetanolo N , N - dietilaminoetanolo
Latvian latviešu 2-dietilaminoetanols N , N -dietiletanolamīns
Lithuanian lietuvių 2-dietilaminoetanolis N , N -dietiletanolaminas
Hungarian magyar 2-dietiletanolamin N , N -dietiletanolamin
Maltese Malti 2-dietilamminoetanol N , N -dietiletanolammina
Dutch Nederlands 2-diëthylaminoethanol N , N -diëthylethanolamine
Polish polski 2-(dietyloamino)etanol N , N -dietyloetanoloamina
Portuguese português 2-dietilaminoetanol N , N -dietiletanolamina
Romanian română 2-dietilaminoetanol N , N -dietiletanolamină
Slovak slovenčina 2-(dietylamino)etanol N , N -dietyletanolamín
Slovenian slovenščina 2-dietilaminoetanol N , N -dietiletanolamin
Finnish suomi 2-dietyyliaminoetanoli N, N -dietyylietanoliamiini
Swedish svenska 2-dietylaminoetanol N , N -dietyletanolamin

All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

Diethylethanolamine GHS label elements

Everything CLP Annex VI fixes for Diethylethanolamine, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS02 Flame pictogramGHS05 Corrosion pictogramGHS07 Exclamation mark pictogramGHS09 Environment pictogram

Danger

Diethylethanolamine

  • Flammable liquid and vapour.
  • Harmful if inhaled.
  • Harmful in contact with skin.
  • Harmful if swallowed.
  • Causes severe skin burns and eye damage.
  • Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
  • Keep container tightly closed.
  • Use explosion-proof [electrical/ventilating/lighting/…] equipment.
  • Use only non-sparking tools.
  • Do not breathe dust/fume/gas/mist/vapours/spray.
  • Do not eat, drink or smoke when using this product.
  • Use only outdoors or in a well-ventilated area.
  • Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/
  • IF SWALLOWED:
  • IF ON SKIN:
  • IF INHALED:
  • Immediately call a POISON CENTER/doctor/
  • Call a POISON CENTER/doctor/ if you feel unwell.
  • Rinse mouth.
  • Do NOT induce vomiting.
  • Wash with plenty of water/
  • Store in a well-ventilated place.

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open Diethylethanolamine in the GHS label constructor →

07 · Health hazards

Diethylethanolamine health hazards and exposure limits

Diethylethanolamine hazard summary

Corrosive to skin; [Quick CPC] Possible cause of asthma; [Reference #1] Causes upper and lower respiratory tract irritation; Rats show signs of upper respiratory irritation with exposures above 120 mg/m3; [NIOSH Criteria Document] May cause allergic contact dermatitis; [CAMEO] Corrosive to the eyes; [ICSC]

Source: Haz-Map, Information on Hazardous Chemicals and Occupational Diseases

Diethylethanolamine occupational exposure limits

US occupational exposure limits reported for Diethylethanolamine. PEL is enforceable (OSHA), REL is a recommendation (NIOSH), IDLH is the concentration at which escape becomes impossible without injury.
Limit Value Source
PEL 10.0 [ppm] Haz-Map, Information on Hazardous Chemicals and Occupational Diseases
PEL 10 ppm (50 mg/m³) Occupational Safety and Health Administration (OSHA)
PEL TWA 10 ppm (50 mg/m3) [skin] The National Institute for Occupational Safety and Health (NIOSH)
REL 10 ppm (50 mg/m³) Occupational Safety and Health Administration (OSHA)
REL TWA 10 ppm (50 mg/m3) [skin] The National Institute for Occupational Safety and Health (NIOSH)
IDLH 100 ppm (NIOSH, 2024) CAMEO Chemicals
IDLH 100.0 [ppm] Haz-Map, Information on Hazardous Chemicals and Occupational Diseases
IDLH 100 ppm Hazardous Substances Data Bank (HSDB)

These are United States values. The European Union sets its own indicative and binding limits, and the figure that applies at a given workplace is the one in the local regulation — not the one shown here.

08 · Physical and chemical properties

Diethylethanolamine properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

Diethylethanolamine boiling point

Property Value Conditions Source
Boiling point 163 °C (325.4 °F) at 760 mmHg HSDB
162.78 °C (325 °F) NIOSH
162.78 °C (325 °F) at 760 mmHg CAMEO

Diethylethanolamine melting point

Property Value Conditions Source
Melting point -70 °C (-94 °F) HSDB

Diethylethanolamine density

Property Value Conditions Source
Density 0.89 g/cm³ NIOSH
0.8921 g/cm³ at 20 °C HSDB
0.8921 g/cm³ at 25 °C CAMEO

Diethylethanolamine solubility

Property Value Conditions Source
Solubility SOL IN ALL PROPORTIONS IN WATER; SOL IN ALC, ETHER, ACETONE, BENZENE, PETROLEUM ETHER HSDB
Miscible NIOSH
Very soluble (NTP, 1992) CAMEO

Diethylethanolamine vapor pressure

Property Value Conditions Source
Vapor pressure 1 mmHg NIOSH
21 mmHg at 20 °C HSDB

Diethylethanolamine flash point

Property Value Conditions Source
Flash point 60 °C (140 °F) HSDB
51.67 °C (125 °F) HSDB
52.22 °C (126 °F) NIOSH

Diethylethanolamine autoignition temperature

Property Value Conditions Source
Autoignition temperature 320 °C (608 °F) HSDB
250 °C (482 °F) ICSC

Diethylethanolamine lower explosive limit (LEL)

Property Value Conditions Source
Lower explosive limit (LEL) 6.7 % by volume HSDB

Diethylethanolamine upper explosive limit (UEL)

Property Value Conditions Source
Upper explosive limit (UEL) 11.7 % by volume HSDB

Diethylethanolamine vapor density

Property Value Conditions Source
Vapor density 4.03 (air = 1) HSDB

Diethylethanolamine odor threshold

Property Value Conditions Source
Odor threshold Absolute perception limit in air = 0.011 ppm. 100% recognition in air = 0.04 ppm. HSDB
Odor Threshold Low: 0.01 [ppm] Haz-Map
Detection odor threshold from AIHA (mean = 0.011 ppm) Haz-Map

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

09 · Fire and explosion

Diethylethanolamine fire and explosion behaviour

These are descriptions rather than measured values, so they are kept out of the table above and quoted here with the source that reported them.

Diethylethanolamine fire potential

Flammable; moderate fire hazard

Source: Hazardous Substances Data Bank (HSDB)

10 · Handling and storage

Diethylethanolamine storage and handling

Diethylethanolamine safe storage

Fireproof. Separated from strong oxidants and strong acids. Cool. Dry.

Source: ILO-WHO International Chemical Safety Cards (ICSCs)

Diethylethanolamine incompatible materials

Strong oxidizers, strong acids.

Source: Hazardous Substances Data Bank (HSDB)

Diethylethanolamine reactivity

2-DIETHYLAMINOETHANOL is an organic compound with both amine and alcohol substituents. Amines are chemical bases. They neutralize acids to form salts plus water. These acid-base reactions are exothermic. The amount of heat that is evolved per mole of amine in a neutralization is largely independent of the strength of the amine as a base. Amines may be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen is generated by amines in combination with strong reducing agents, such as hydrides. This compound can react with strong oxidizers and acids. (NTP, 1992)

Source: CAMEO Chemicals

Planning storage for a mix of chemicals? Check Diethylethanolamine in the storage compatibility matrix →

11 · Questions

Diethylethanolamine — frequently asked questions

What is the CAS number of Diethylethanolamine?

The CAS number of Diethylethanolamine is 100-37-8. Its EC number is 202-845-2.

What is the chemical formula of Diethylethanolamine?

The molecular formula of Diethylethanolamine is C6H15NO and its molecular weight is 117.19 g/mol.

What does a Diethylethanolamine label have to show?

Under CLP Annex VI the label for Diethylethanolamine carries the pictograms Flame, Corrosion, Exclamation mark and Environment and the signal word is Danger.

Is Diethylethanolamine flammable?

Yes. CLP Annex VI assigns Diethylethanolamine H226 — flammable liquid and vapour. The flash point reported for it is 60 °C (140 °F) (HSDB).

Is Diethylethanolamine a carcinogen?

CLP Annex VI records no harmonised carcinogenicity classification for Diethylethanolamine. Annex VI is a list of agreed classifications, not a list of substances found safe, so this is an absence of a classification rather than a clean bill of health.

What is the exposure limit for Diethylethanolamine?

The US occupational exposure limit reported for Diethylethanolamine is 10.0 [ppm] (Haz-Map, Information on Hazardous Chemicals and Occupational Diseases). Limits differ by country: the EU sets its own indicative and binding values, and the figure that applies at a given workplace is the one in the local regulation.

What is the boiling point of Diethylethanolamine?

The boiling point reported for Diethylethanolamine is 163 °C (325.4 °F), at 760 mmHg (HSDB).

What is the melting point of Diethylethanolamine?

The melting point reported for Diethylethanolamine is -70 °C (-94 °F) (HSDB).

How should Diethylethanolamine be stored?

CLP Annex VI assigns Diethylethanolamine the storage statement P403.

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