Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

Dithallium sulphate

Dithallium sulphate is white, rhomboid prisms and is odorless.

CAS 7446-18-6 Danger

01 · Identification

What Dithallium sulphate is

Dithallium sulphate is white, rhomboid prisms and is odorless. It melts at 632 °C.

Under the GHS it carries the signal word Danger.

02 · Identifiers

Dithallium sulphate identifiers and molecular data

Dithallium sulphate CAS number and EC number

CAS number7446-18-6
EC number231-201-3
Index number (CLP Annex VI)081-003-00-4

Other names for Dithallium sulphate

  • thallic sulphate

03 · GHS classification

Dithallium sulphate hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

Dithallium sulphate pictograms and signal word

Signal wordDanger

Dithallium sulphate hazard class and category

GHS hazard classes Dithallium sulphate falls into
Hazard class Category From code Pictogram
Acute toxicity - oral GHS chapter 3.1 Category 1 or 2 H300 GHS06
Skin corrosion/irritation GHS chapter 3.2 Category 2 H315 GHS07
Specific target organ toxicity - repeated exposure GHS chapter 3.9 Category 1 H372 GHS08
Hazardous to the aquatic environment - chronic GHS chapter 4.1 Category 2 H411 GHS09

Where two values are shown with “or”, the hazard statement is shared by more than one category or by more than one class, and the code alone does not say which. H272, for example, belongs to oxidising liquids and to oxidising solids — the physical state decides. The binding answer for a specific entry is in the CLP Annex VI table itself.

Dithallium sulphate hazard statements (H-codes)

Hazard statements assigned to Dithallium sulphate
CodeHazard statement
H300 Fatal if swallowed.
H372 Causes damage to organs <or state all organs affected, if known> through prolonged or repeated exposure <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
H315 Causes skin irritation.
H411 Toxic to aquatic life with long lasting effects.

This page lists only the codes assigned to Dithallium sulphate. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for Dithallium sulphate

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of Dithallium sulphate issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

04 · Precautionary statements

Dithallium sulphate precautionary statements

CLP Annex VI assigns 15 precautionary statements to Dithallium sulphate. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Disposal

What has to happen to the contents and the empty container.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

Dithallium sulphate name in 23 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български диталиев сулфат талиев сулфат
Spanish español Sulfato de ditalio sulfato tálico
Czech čeština síran thallný
Danish dansk dithalliumsulfat thallium(I)sulfat
German Deutsch Dithalliumsulfat Thallium(I)-sulfat
Estonian eesti ditalliumsulfaat talliumsulfaat
Greek ελληνικά θειικό διθάλλιο θειικό θάλλιο(III)
English English dithallium sulphate thallic sulphate
French français sulfate de dithallium sulfate thallique
Croatian hrvatski ditalijev sulfat talijev sulfat
Italian italiano solfato di ditallio
Latvian latviešu ditallija sulfāts tallija(III) sulfāts
Lithuanian lietuvių ditalio sulfatas talio sulfatas
Hungarian magyar ditallium-szulfát tallium-szulfát
Maltese Malti sulfat tad-ditallju sulfat talliku
Dutch Nederlands dithalliumsulfaat thalliumsulfaat
Polish polski siarczan(VI) talu(I) siarczan(VI) ditalusiarczan talawy
Portuguese português sulfato de ditálio sulfato tálico
Romanian română sulfat de ditaliu sulfat talic
Slovak slovenčina síran tálny
Slovenian slovenščina ditalijev sulfat talijev sulfat
Finnish suomi ditalliumsulfaatti talliumsulfaatti
Swedish svenska ditalliumsulfat talliumsulfat

All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

Dithallium sulphate GHS label elements

Everything CLP Annex VI fixes for Dithallium sulphate, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS06 Skull and crossbones pictogramGHS08 Health hazard pictogramGHS09 Environment pictogram

Danger

Dithallium sulphate

  • Fatal if swallowed.
  • Causes damage to organs <or state all organs affected, if known> through prolonged or repeated exposure <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
  • Causes skin irritation.
  • Toxic to aquatic life with long lasting effects.
  • Do not breathe dust/fume/gas/mist/vapours/spray.
  • Wash thoroughly after handling.
  • Do not eat, drink or smoke when using this product.
  • Avoid release to the environment.
  • Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/
  • IF SWALLOWED:
  • IF ON SKIN:
  • Immediately call a POISON CENTER/doctor/
  • Get medical advice/attention.
  • Get medical advice/attention if you feel unwell.
  • Rinse mouth.
  • If skin irritation occurs:
  • Wash with plenty of water/
  • Collect spillage.
  • Dispose of contents/container to

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open Dithallium sulphate in the GHS label constructor →

07 · Health hazards

Dithallium sulphate health hazards and exposure limits

Dithallium sulphate hazard summary

A skin and eye irritant; Can be absorbed through skin; Can cause thallium poisoning; [ICSC] See Thallium and linked occupational diseases.

Source: Haz-Map, Information on Hazardous Chemicals and Occupational Diseases

Dithallium sulphate carcinogenicity classification

Cancer Classification: Group D Not Classifiable as to Human Carcinogenicity

Source: Hazardous Substances Data Bank (HSDB)

CLASSIFICATION: D; not classifiable as to human carcinogenicity. BASIS FOR CLASSIFICATION: Based on the lack of carcinogenicity data in animals and humans. HUMAN CARCINOGENICITY DATA: Inadequate. ANIMAL CARCINOGENICITY DATA: None.

Source: Hazardous Substances Data Bank (HSDB)

An IARC group and a CLP classification answer different questions. IARC judges whether the evidence for cancer in humans is strong enough; CLP Annex VI is the legally binding EU classification. A substance can carry one and not the other.

Dithallium sulphate occupational exposure limits

US occupational exposure limits reported for Dithallium sulphate. PEL is enforceable (OSHA), REL is a recommendation (NIOSH), IDLH is the concentration at which escape becomes impossible without injury.
Limit Value Source
PEL 0.1 [mg/m3], as Tl Haz-Map, Information on Hazardous Chemicals and Occupational Diseases
IDLH 15 mg Tl/m3 (NIOSH, 2024) CAMEO Chemicals
IDLH 15.0 [mg/m3], as Tl (soluble compounds) Haz-Map, Information on Hazardous Chemicals and Occupational Diseases
IDLH 15 mg/cu m (as Tl). /Thallium (soluble cmpds, as Tl)/ Hazardous Substances Data Bank (HSDB)

These are United States values. The European Union sets its own indicative and binding limits, and the figure that applies at a given workplace is the one in the local regulation — not the one shown here.

08 · Physical and chemical properties

Dithallium sulphate properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

Dithallium sulphate boiling point

Property Value Conditions Source
Boiling point Decomposes decomposes HSDB
Decomposes (EPA, 1998) decomposes CAMEO

Dithallium sulphate melting point

Property Value Conditions Source
Melting point 632 °C (1169.6 °F) HSDB
632.22 °C (1170 °F) CAMEO

Dithallium sulphate density

Property Value Conditions Source
Density 6.77 g/cm³ HSDB

Dithallium sulphate solubility

Property Value Conditions Source
Solubility Solubility in water, g/100ml at 20 °C: 4.87 (moderate) at 20 °C ICSC
48.7 g/l @ 15 °C; 191.4 g/l @ 100 °C at 15 °C HSDB
Solubility in 100 ml water at 0 °C: 2.70 g, at 20 °C: 4.87 g, at 100 °C: 18.45 g at 0 °C HSDB

Dithallium sulphate vapor pressure

Property Value Conditions Source
Vapor pressure Zero HSDB
Inappreciable (EPA, 1998) CAMEO

Dithallium sulphate corrosivity

Property Value Conditions Source
Corrosivity Slightly corrosive to iron HSDB

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

09 · Handling and storage

Dithallium sulphate storage and handling

Dithallium sulphate safe storage

Provision to contain effluent from fire extinguishing. Store only in original container. Well closed. Separated from strong oxidants and food and feedstuffs. Store in an area without drain or sewer access.

Source: ILO-WHO International Chemical Safety Cards (ICSCs)

Dithallium sulphate reactivity

THALLIUM SULFATE has weak oxidizing and weak reducing powers. Redox reactions can however still occur.

Source: CAMEO Chemicals

Planning storage for a mix of chemicals? Check Dithallium sulphate in the storage compatibility matrix →

10 · Questions

Dithallium sulphate — frequently asked questions

What is the CAS number of Dithallium sulphate?

The CAS number of Dithallium sulphate is 7446-18-6. Its EC number is 231-201-3.

What does a Dithallium sulphate label have to show?

Under CLP Annex VI the label for Dithallium sulphate carries the pictograms Skull and crossbones, Health hazard and Environment and the signal word is Danger.

Is Dithallium sulphate flammable?

CLP Annex VI assigns Dithallium sulphate no flammability hazard class. That is not a statement that it cannot burn: the harmonised list only records the hazards that were assessed for it.

Is Dithallium sulphate a carcinogen?

CLP Annex VI records no harmonised carcinogenicity classification for Dithallium sulphate. Annex VI is a list of agreed classifications, not a list of substances found safe, so this is an absence of a classification rather than a clean bill of health.

What is the exposure limit for Dithallium sulphate?

The US occupational exposure limit reported for Dithallium sulphate is 0.1 [mg/m3], as Tl (Haz-Map, Information on Hazardous Chemicals and Occupational Diseases). Limits differ by country: the EU sets its own indicative and binding values, and the figure that applies at a given workplace is the one in the local regulation.

What is the boiling point of Dithallium sulphate?

The boiling point reported for Dithallium sulphate is Decomposes, decomposes (HSDB).

What is the melting point of Dithallium sulphate?

The melting point reported for Dithallium sulphate is 632 °C (1169.6 °F) (HSDB).

Nearby

Substances next to Dithallium sulphate

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