Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

Gases (petroleum), crude oil fractionation off

Gases (petroleum), crude oil fractionation off is a substance with a harmonised classification under EU CLP.

CAS 68918-99-0 Danger

01 · Identification

What Gases (petroleum), crude oil… is

Gases (petroleum), crude oil fractionation off is a substance with a harmonised classification under EU CLP.

Under the GHS it carries the signal word Danger.

02 · Identifiers

Gases (petroleum), crude oil… identifiers and molecular data

Gases (petroleum), crude oil… CAS number and EC number

CAS number68918-99-0
EC number272-871-7
Index number (CLP Annex VI)649-100-00-1

Other names for Gases (petroleum), crude oil…

  • Petroleum gas
  • [A complex combination of hydrocarbons produced by the fractionation of crude oil. It consists of saturated aliphatic hydrocarbons having carbon numbers predominantly in the range of C1 through C5.]

03 · GHS classification

Gases (petroleum), crude oil… hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

Gases (petroleum), crude oil… pictograms and signal word

Signal wordDanger

Gases (petroleum), crude oil… hazard class and category

GHS hazard classes Gases (petroleum), crude… falls into
Hazard class Category From code Pictogram
Flammable gases GHS chapter 2.2 Category 1A H220 GHS02
Germ cell mutagenicity GHS chapter 3.5 Category 1A or 1B H340 GHS08
Carcinogenicity GHS chapter 3.6 Category 1A or 1B H350 GHS08

Where two values are shown with “or”, the hazard statement is shared by more than one category or by more than one class, and the code alone does not say which. H272, for example, belongs to oxidising liquids and to oxidising solids — the physical state decides. The binding answer for a specific entry is in the CLP Annex VI table itself.

Gases (petroleum), crude oil… hazard statements (H-codes)

Hazard statements assigned to Gases (petroleum), crude…
CodeHazard statement
H220 Extremely flammable gas.
H350 May cause cancer <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
H340 May cause genetic defects <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.

This page lists only the codes assigned to Gases (petroleum), crude…. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for Gases (petroleum), crude…

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of Gases (petroleum)… issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

04 · Precautionary statements

Gases (petroleum), crude oil… precautionary statements

CLP Annex VI assigns 7 precautionary statements to Gases (petroleum), crude…. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Response

What to do once exposure, spillage or fire has already happened.

Storage

How the container has to be kept between uses.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

Gases (petroleum), crude oil… name in 23 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български Газове (нефтени), от фракциониране на суров нефт нефтен газ
Spanish español Gases (petróleo), del fraccionamiento de petróleo crudo gas de petróleo
Czech čeština plyny (ropné), výstup z frakcionační destilace ropy ropný plyn
Danish dansk gasser (råolie), råoliefraktioneringsaftræks- kulbrintegasser
German Deutsch Gase (Erdöl), Abgase aus Rohölfraktionierung Gase aus der Erdölverarbeitung
Estonian eesti gaasid (nafta), toornafta fraktsioneerimisseadme heitgaas naftagaas
Greek ελληνικά Αέρια (πετρελαίου), εξόδου κλασμάτωσης αργού πετρελαίου Πετρελαϊκό αέριο
English English Gases (petroleum), crude oil fractionation off Petroleum gas
French français Gaz résiduels (pétrole), fractionnement de pétrole brut gaz de pétrole
Croatian hrvatski plinovi (nafta), ispušni plinovi iz frakcionacije sirove nafte naftni plin
Italian italiano gas (petrolio), dal frazionamento del grezzo gas di petrolio
Latvian latviešu Izdalgāzes (naftas), jēlnaftas frakcionēšanas Naftas pavadgāze
Lithuanian lietuvių Dujos (nafta), žalios naftos frakcionavimo Naftos dujos
Hungarian magyar Gázok (ásványolaj), nyersolaj frakcionálás távozó terméke Ásványolaj gáz
Maltese Malti Gassijiet (żejt mhux maħdum), effluwenti gassużi mill-frazzjonazzjoni ta' żejt mhux raffinat Gass taż-żejt mhux maħdum
Dutch Nederlands gassen (aardolie), ruwe olie-fractioneringuitstoot- petroleumgas
Polish polski Gazy (ropa naftowa) z destylacji frakcyjnej ropy naftowej Gaz z ropy naftowej
Portuguese português gases (petróleo), de fracionamento de petróleo bruto gás de petróleo
Romanian română Gaze reziduale (petrol), fracționarea țițeiului Gaz petrolier
Slovak slovenčina plyny (ropné), z frakcionácie ropy plyn zo spracovania ropy
Slovenian slovenščina plini (nafta), izhodni plini frakcionacije surove nafte naftni plin
Finnish suomi Kaasut (maaöljy), raakaöljyn jakotislauspoisto Maaöljykaasu
Swedish svenska Gaser (petroleum), råoljefraktionering, avgaser Petroleumgas

All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

Gases (petroleum), crude oil… GHS label elements

Everything CLP Annex VI fixes for Gases (petroleum), crude…, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS04 Gas cylinder pictogramGHS02 Flame pictogramGHS08 Health hazard pictogram

Danger

Gases (petroleum), crude oil…

  • Extremely flammable gas.
  • May cause cancer <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
  • May cause genetic defects <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
  • Obtain special instructions before use.
  • Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
  • Keep container tightly closed.
  • Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/
  • IF exposed or concerned:
  • Get medical advice/attention.
  • Store in a well-ventilated place.

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open Gases (petroleum), crude… in the GHS label constructor →

07 · Questions

Gases (petroleum), crude oil… — frequently asked questions

What is the CAS number of Gases (petroleum), crude oil…?

The CAS number of Gases (petroleum), crude oil… is 68918-99-0. Its EC number is 272-871-7.

What does a Gases (petroleum), crude oil… label have to show?

Under CLP Annex VI the label for Gases (petroleum), crude oil… carries the pictograms Gas cylinder, Flame and Health hazard and the signal word is Danger.

Is Gases (petroleum), crude oil… flammable?

Yes. CLP Annex VI assigns Gases (petroleum), crude oil… H220 — extremely flammable gas.

Is Gases (petroleum), crude oil… a carcinogen?

Yes. CLP Annex VI classifies Gases (petroleum), crude oil… as a category 1A or 1B carcinogen and assigns it H350: may cause cancer.

How should Gases (petroleum), crude oil… be stored?

CLP Annex VI assigns Gases (petroleum), crude oil… the storage statement P403.

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