Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

Hydrocarbons, C1-4, debutanizer fraction

Hydrocarbons, C1-4, debutanizer fraction is a substance with a harmonised classification under EU CLP.

CAS 68527-19-5 Danger

01 · Identification

What Hydrocarbons, C1-4… is

Hydrocarbons, C1-4, debutanizer fraction is a substance with a harmonised classification under EU CLP.

Under the GHS it carries the signal word Danger.

02 · Identifiers

Hydrocarbons, C1-4… identifiers and molecular data

Hydrocarbons, C1-4… CAS number and EC number

CAS number68527-19-5
EC number271-261-8
Index number (CLP Annex VI)649-091-00-4

Other names for Hydrocarbons, C1-4…

  • Petroleum gas

03 · GHS classification

Hydrocarbons, C1-4… hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

Hydrocarbons, C1-4… pictograms and signal word

Signal wordDanger

Hydrocarbons, C1-4… hazard class and category

GHS hazard classes Hydrocarbons, C1-4… falls into
Hazard class Category From code Pictogram
Flammable gases GHS chapter 2.2 Category 1A H220 GHS02
Germ cell mutagenicity GHS chapter 3.5 Category 1A or 1B H340 GHS08
Carcinogenicity GHS chapter 3.6 Category 1A or 1B H350 GHS08

Where two values are shown with “or”, the hazard statement is shared by more than one category or by more than one class, and the code alone does not say which. H272, for example, belongs to oxidising liquids and to oxidising solids — the physical state decides. The binding answer for a specific entry is in the CLP Annex VI table itself.

Hydrocarbons, C1-4… hazard statements (H-codes)

Hazard statements assigned to Hydrocarbons, C1-4…
CodeHazard statement
H220 Extremely flammable gas.
H350 May cause cancer <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
H340 May cause genetic defects <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.

This page lists only the codes assigned to Hydrocarbons, C1-4…. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for Hydrocarbons, C1-4…

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of Hydrocarbons, C1-4… issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

04 · Precautionary statements

Hydrocarbons, C1-4… precautionary statements

CLP Annex VI assigns 7 precautionary statements to Hydrocarbons, C1-4…. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Response

What to do once exposure, spillage or fire has already happened.

Storage

How the container has to be kept between uses.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

Hydrocarbons, C1-4… name in 23 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български Въглеводороди, C 1-4 , фракция от колоната за дебутанизация Нефтен газ
Spanish español Hidrocarburos, C 1-4 , fracción del desbutanizador gas de petróleo
Czech čeština uhlovodíky, C 1-4 , debutanizérová frakce ropný plyn
Danish dansk carbonhydrider, C 1-4 -, debutanizer-fraktion kulbrintegasser
German Deutsch Kohlenwasserstoffe, C 1-4 , Butanabtrennungsfraktion Gase aus der Erdölverarbeitung
Estonian eesti C 1–4 -süsivesinikud, butaanieemaldi fraktsioon naftagaas
Greek ελληνικά Υδρογονάνθρακες, C 1-4 , κλάσμα αποβουτανιωτήρα Πετρελαϊκό αέριο
English English Hydrocarbons, C 1-4 , debutanizer fraction Petroleum gas
French français Hydrocarbures en C 1-4 , fraction débutanisée gaz de pétrole
Croatian hrvatski ugljikovodici, C 1-4 , frakcija debutanizera naftni plin
Italian italiano idrocarburi, C 1-4 , frazione debutanizzatore gas di petrolio
Latvian latviešu Ogļūdeņraži, C 1-4 , debutanizatora frakcija Naftas pavadgāze
Lithuanian lietuvių Angliavandeniliai, C 1-4 , debutanavimo įrenginio frakcija Naftos dujos
Hungarian magyar Szénhidrogének, C 1-4 , butánmentesítő frakció Ásványolaj gáz
Maltese Malti Idrokarburi, C 1-4 , frazzjoni tad-debutanizzatur Gass taż-żejt mhux maħdum
Dutch Nederlands koolwaterstoffen, C 1-4 , debutanisatorfractie petroleumgas
Polish polski Węglowodory, C 1-4 , frakcja z debutanizera Gaz z ropy naftowej
Portuguese português hidrocarbonetos, C 1-4 , fração de desbutanizador gás de petróleo
Romanian română Hidrocarburi cu C 1-4 , fracție fără butan Gaz petrolier
Slovak slovenčina C 1-4 -uhľovodíky, frakcia z oddeľovania butánu plyn zo spracovania ropy
Slovenian slovenščina ogljikovodiki, C 1–4 , frakcija iz debutanizatorja naftni plin
Finnish suomi Hiilivedyt, C 1 –4, debutanoitu fraktio Maaöljykaasu
Swedish svenska Kolväten, C 1-4 , butanavdrivarfraktion Petroleumgas

All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

Hydrocarbons, C1-4… GHS label elements

Everything CLP Annex VI fixes for Hydrocarbons, C1-4…, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS04 Gas cylinder pictogramGHS02 Flame pictogramGHS08 Health hazard pictogram

Danger

Hydrocarbons, C1-4…

  • Extremely flammable gas.
  • May cause cancer <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
  • May cause genetic defects <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
  • Obtain special instructions before use.
  • Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
  • Keep container tightly closed.
  • Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/
  • IF exposed or concerned:
  • Get medical advice/attention.
  • Store in a well-ventilated place.

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open Hydrocarbons, C1-4… in the GHS label constructor →

07 · Transport

Hydrocarbons, C1-4… UN number and transport classification

Transport classification is a separate system from the GHS classification above. It decides how a package is marked and how a load may be carried; it does not follow from the workplace label, and the workplace label does not follow from it. The entries below are linked by CAS number, never by name.

Hydrocarbons, C1-4… under UN 3295 — shipping name, class and packing group

Europe · ADR 2025, Table A

Proper shipping name (3.1.2) Class Classification code PG Labels (column 5)
HYDROCARBONS, LIQUID, N.O.S. 3 F1 I
  • ADR label model 3 — Flammable liquid
3
HYDROCARBONS, LIQUID, N.O.S. (vapour pressure at 50 °C more than 110 kPa) 3 F1 II
  • ADR label model 3 — Flammable liquid
3
HYDROCARBONS, LIQUID, N.O.S. (vapour pressure at 50 °C not more than 110 kPa) 3 F1 II
  • ADR label model 3 — Flammable liquid
3
HYDROCARBONS, LIQUID, N.O.S. 3 F1 III
  • ADR label model 3 — Flammable liquid
3

Source: ADR 2025, Table A of Chapter 3.2 · ECE/TRANS/352 Vol. I (UNECE). Class 3 is “Flammable liquids” (ADR 2.1.1.1).

Proper shipping name (column 2) Class or division PG Labels (column 6)
Hydrocarbons, liquid, n.o.s. 3 I
  • US DOT FLAMMABLE LIQUID label (§172.419)
3
Hydrocarbons, liquid, n.o.s. 3 II
  • US DOT FLAMMABLE LIQUID label (§172.419)
3
Hydrocarbons, liquid, n.o.s. 3 III
  • US DOT FLAMMABLE LIQUID label (§172.419)
3

Source: 49 CFR 172.101 Hazardous Materials Table · eCFR, revision 2026-08-03. Class 3 is “Flammable and combustible liquid” (49 CFR 173.2).

Full UN 3295 entry — special provisions, packing instructions, quantity limits and the orange plate →

08 · Questions

Hydrocarbons, C1-4… — frequently asked questions

What is the CAS number of Hydrocarbons, C1-4…?

The CAS number of Hydrocarbons, C1-4… is 68527-19-5. Its EC number is 271-261-8.

What does a Hydrocarbons, C1-4… label have to show?

Under CLP Annex VI the label for Hydrocarbons, C1-4… carries the pictograms Gas cylinder, Flame and Health hazard and the signal word is Danger.

Is Hydrocarbons, C1-4… flammable?

Yes. CLP Annex VI assigns Hydrocarbons, C1-4… H220 — extremely flammable gas.

Is Hydrocarbons, C1-4… a carcinogen?

Yes. CLP Annex VI classifies Hydrocarbons, C1-4… as a category 1A or 1B carcinogen and assigns it H350: may cause cancer.

How should Hydrocarbons, C1-4… be stored?

CLP Annex VI assigns Hydrocarbons, C1-4… the storage statement P403.

Nearby

Substances next to Hydrocarbons, C1-4…

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