Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

Ligroine

Ligroine is a substance with a harmonised classification under EU CLP.

CAS 8032-32-4 Danger

01 · Identification

What Ligroine is

Ligroine is a substance with a harmonised classification under EU CLP.

Under the GHS it carries the signal word Danger.

02 · Identifiers

Ligroine identifiers and molecular data

Ligroine CAS number and EC number

CAS number8032-32-4
EC number232-453-7
Index number (CLP Annex VI)649-263-00-9

Other names for Ligroine

  • Low boiling point naphtha
  • [A complex combination of hydrocarbons obtained by the fractional distillation of petroleum. This fraction boils in a range of approximately 20°C to 135°C (58°F to 275°F).]

03 · GHS classification

Ligroine hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

Ligroine pictograms and signal word

Signal wordDanger

Ligroine hazard class and category

GHS hazard classes Ligroine falls into
Hazard class Category From code Pictogram
Germ cell mutagenicity GHS chapter 3.5 Category 1A or 1B H340 GHS08
Carcinogenicity GHS chapter 3.6 Category 1A or 1B H350 GHS08
Aspiration hazard GHS chapter 3.10 Category 1 H304 GHS08

Where two values are shown with “or”, the hazard statement is shared by more than one category or by more than one class, and the code alone does not say which. H272, for example, belongs to oxidising liquids and to oxidising solids — the physical state decides. The binding answer for a specific entry is in the CLP Annex VI table itself.

Ligroine hazard statements (H-codes)

Hazard statements assigned to Ligroine
CodeHazard statement
H350 May cause cancer <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
H340 May cause genetic defects <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
H304 May be fatal if swallowed and enters airways.

This page lists only the codes assigned to Ligroine. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for Ligroine

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of Ligroine issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

04 · Precautionary statements

Ligroine precautionary statements

CLP Annex VI assigns 4 precautionary statements to Ligroine. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Response

What to do once exposure, spillage or fire has already happened.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

Ligroine name in 23 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български Лигроин Нафта с ниска температура на кипене
Spanish español Ligroína nafta de bajo punto de ebullición
Czech čeština ligroin nízkovroucí benzínová frakce
Danish dansk ligroin lavtkogende nafta
German Deutsch Ligroin Naphtha, niedrigsiedend
Estonian eesti petrooleeter kergkeev toorbensiin
Greek ελληνικά Λιγροΐνη Νάφθα χαμηλού σημείου ζέσεως
English English Ligroine Low boiling point naphtha
French français Ligroïne naphta à bas point d'ébullition
Croatian hrvatski ligroin ( petroleter ) niskovrijući teški benzin
Italian italiano ligroina nafta con basso punto di ebollizione
Latvian latviešu Ligroīns Jēlbenzīns ar zemu viršanas punktu
Lithuanian lietuvių Ligroinas Žematemperatūris pirminis benzinas
Hungarian magyar Ligroin Alacsony forráspontú benzin
Maltese Malti Ligroine Nafta b’punt tat-togħlija baxx
Dutch Nederlands ligroïne nafta met laag kookpunt
Polish polski Ligroina Niskowrząca frakcja benzynowa
Portuguese português ligroína nafta de baixo ponto de ebulição
Romanian română Ligroină Benzină nafta cu temperaturi de fierbere scăzute
Slovak slovenčina ligroín benzín s nízkou teplotou varu
Slovenian slovenščina ligroin nafta z nizkim vreliščem
Finnish suomi Ligroiini Matalalla kiehuva teollisuusbensiini
Swedish svenska Ligroin Lågkokande nafta

All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

Ligroine GHS label elements

Everything CLP Annex VI fixes for Ligroine, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS08 Health hazard pictogram

Danger

Ligroine

  • May cause cancer <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
  • May cause genetic defects <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
  • May be fatal if swallowed and enters airways.
  • Obtain special instructions before use.
  • Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/
  • IF exposed or concerned:
  • Get medical advice/attention.

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open Ligroine in the GHS label constructor →

07 · Questions

Ligroine — frequently asked questions

What is the CAS number of Ligroine?

The CAS number of Ligroine is 8032-32-4. Its EC number is 232-453-7.

What does a Ligroine label have to show?

Under CLP Annex VI the label for Ligroine carries the pictogram Health hazard and the signal word is Danger.

Is Ligroine flammable?

CLP Annex VI assigns Ligroine no flammability hazard class. That is not a statement that it cannot burn: the harmonised list only records the hazards that were assessed for it.

Is Ligroine a carcinogen?

Yes. CLP Annex VI classifies Ligroine as a category 1A or 1B carcinogen and assigns it H350: may cause cancer.

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