Substance profile
Molinate
Molinate is a clear liquid with an aromatic odor.
01 · Identification
What Molinate is
Molinate is a clear liquid with an aromatic odor. Its molecular formula is C9H17NOS and its molecular weight is 187.3 g/mol.
Under the GHS it carries the signal word Warning.
02 · Identifiers
Molinate identifiers and molecular data
Molinate CAS number and EC number
Molinate molecular formula and molecular weight
Other names for Molinate
- molinate (ISO)
- S-ethyl 1-perhydroazepinecarbothioate
- S-ethyl perhydroazepine-1-carbothioate
03 · GHS classification
Molinate hazard classification
Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.
Molinate pictograms and signal word
Molinate hazard class and category
| Hazard class | Category | From code | Pictogram |
|---|---|---|---|
| Acute toxicity - oral GHS chapter 3.1 | Category 4 | H302 | GHS07 |
| Acute toxicity - inhalation GHS chapter 3.1 | Category 4 | H332 | GHS07 |
| Skin sensitisation GHS chapter 3.4 | Category 1 or 1A or 1B | H317 | GHS07 |
| Carcinogenicity GHS chapter 3.6 | Category 2 | H351 | GHS08 |
| Specific target organ toxicity - repeated exposure GHS chapter 3.9 | Category 2 | H373 | GHS08 |
| Hazardous to the aquatic environment - acute GHS chapter 4.1 | Category 1 | H400 | GHS09 |
| Hazardous to the aquatic environment - chronic GHS chapter 4.1 | Category 1 | H410 | GHS09 |
Where two values are shown with “or”, the hazard statement is shared by more than one category or by more than one class, and the code alone does not say which. H272, for example, belongs to oxidising liquids and to oxidising solids — the physical state decides. The binding answer for a specific entry is in the CLP Annex VI table itself.
Molinate hazard statements (H-codes)
| Code | Hazard statement |
|---|---|
| H351 | Suspected of causing cancer <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>. |
| H361f | Suspected of damaging fertility. |
| H332 | Harmful if inhaled. |
| H302 | Harmful if swallowed. |
| H373 | May cause damage to organs <or state all organs affected, if known> through prolonged or repeated exposure <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>. |
| H317 | May cause an allergic skin reaction. |
| H400 | Very toxic to aquatic life. |
| H410 | Very toxic to aquatic life with long lasting effects. |
This page lists only the codes assigned to Molinate. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.
Safety Data Sheet
Getting an SDS for Molinate
A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of Molinate issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.
04 · Precautionary statements
Molinate precautionary statements
CLP Annex VI assigns 18 precautionary statements to Molinate. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.
Prevention
What to do before and during handling so the hazard never happens.
Response
What to do once exposure, spillage or fire has already happened.
Disposal
What has to happen to the contents and the empty container.
Reading the notation. … is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.
05 · Names in the regulation
Molinate name in 23 EU languages
CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.
| Language | Name in CLP Annex VI Part 3 |
|---|---|
| Bulgarian български | молинат (ISO) S -етилов 1-перхидроазепинкарботиоатS -етилов перхидроазепин-1-карботиоат |
| Spanish español | Molinato (ISO) 1-perhidroazepinacarbotioato de S -etiloperhidroazepina-1-carbotioato de S -etilo |
| Czech čeština | molinát (ISO) S -ethyl-hexahydroazepin-1-karbothioát |
| Danish dansk | molinat (ISO) S-ethyl-1-perhydroazepincarbothioatS-ethyl-perhydroazepin-1-carbothioat |
| German Deutsch | Molinat (ISO) S-ethyl-1-perhydroazepincarbothioatS-ethyl-perhydroazepin-1-carbothioat |
| Estonian eesti | molinaat (ISO) S -etüül-1-perhüdroasepiinkarbotioaatS -etüül-perhüdroasepiin-1-karbotioaat |
| Greek ελληνικά | molinate (μολινάτη) (ISO) 1-υπερυδροαζεπινοκαρβοθειοϊκός S-αιθυλεστέραςυπερυδροαζεπινο-1-καρβοθειοϊκός S-αιθυλεστέρας |
| English English | molinate (ISO) S-ethyl 1-perhydroazepinecarbothioateS-ethyl perhydroazepine-1-carbothioate |
| French français | molinate (ISO) 1-perhydroazépinecarbothioate de S-éthyleperhydroazépine-1-carbothioate de S-éthyle |
| Croatian hrvatski | molinat (ISO) S-etil 1-perhidroazepinkarbotioatS-etil perhidroazepin-1-karbotioat |
| Italian italiano | molinato (ISO) 1-peridroazepintioato di S -etileperidroazepin-1-carbotioato di S -etile |
| Latvian latviešu | molināts (ISO) S -etil-1-perhidroazepīnkarbotioātsS -etil-perhidroazepīn-1-karbotioāts |
| Lithuanian lietuvių | molinatas (ISO) S-etil-1-perhidroazepinkarbotioatasS-etil perhidroazepino-1-karbotionatas |
| Hungarian magyar | molinát (ISO) S-etil-1-perhidroazepin-karbotioátS-etil-perhidroazepin-1-karbotioát |
| Maltese Malti | molinat (ISO) 1-peridroażepinekarbotijoat ta’ S-etilperidroażepin-1-karbotijoat ta’ S-etil |
| Dutch Nederlands | molinaat (ISO) S -ethyl-1-perhydroazepinecarbothioaatS -ethyl-perhydroazepine-1-carbothioaat |
| Polish polski | molinat (ISO) N , N -heksametylenotiokarbaminian S -etylu |
| Portuguese português | molinato (ISO) 1-per-hidroazepinacarbotioato de S -etiloper-hidroazepina-1-carbotioato de S -etilo |
| Romanian română | molinat (ISO) 1-perhidroazepintiocarbonat de S-etilperhidroazepin-1-carbotioat de S-etil |
| Slovak slovenčina | molinát (ISO) S -etyl-1-hexahydroazepínkarbotioátS -etyl-hexahydroazepín-1-karbotioát |
| Slovenian slovenščina | molinat (ISO) S-etil 1-perhidroazepinkarbotioatS-etil perhidroazepin-1-karbotioat |
| Finnish suomi | molinaatti (ISO) S-etyyli-1-perhydroatsepiinikarbotioaattiS-etyyliperhydroatsepiini-1-karbotioaatti |
| Swedish svenska | molinat (ISO) S -etyl-1-perhydroazepinkarbotioatS -etylperhydroazepin-1-karbotioat |
All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.
06 · Label elements
Molinate GHS label elements
Everything CLP Annex VI fixes for Molinate, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.
Warning
Molinate
- Suspected of causing cancer <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
- Suspected of damaging fertility.
- Harmful if inhaled.
- Harmful if swallowed.
- May cause damage to organs <or state all organs affected, if known> through prolonged or repeated exposure <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
- May cause an allergic skin reaction.
- Very toxic to aquatic life.
- Very toxic to aquatic life with long lasting effects.
- Obtain special instructions before use.
- Do not breathe dust/fume/gas/mist/vapours/spray.
- Avoid breathing dust/fume/gas/mist/vapours/spray.
- Do not eat, drink or smoke when using this product.
- Use only outdoors or in a well-ventilated area.
- Contaminated work clothing should not be allowed out of the workplace.
- Avoid release to the environment.
- Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/…
- IF SWALLOWED:
- IF INHALED:
- IF exposed or concerned:
- Call a POISON CENTER/doctor/… if you feel unwell.
- Get medical advice/attention.
- Get medical advice/attention if you feel unwell.
- Rinse mouth.
- If skin irritation or rash occurs:
- Collect spillage.
- Dispose of contents/container to …
Supplier name, address and telephone number· Product identifier·Nominal quantity
Need this as an actual label? Open Molinate in the GHS label constructor →
07 · Health hazards
Molinate health hazards and exposure limits
Molinate hazard summary
A skin and eye irritant; [HSDB] High-dose animal studies: Reproductive toxicity at 4 mg/kg/day; Increased thyroid weights at 45 mg/kg/day in 13-week feeding study of dogs; May cause skin sensitization; [eChemPortal: ESIS] May cause irritation; May cause skin sensitization; Targets the thyroid; [MSDSonline] See Diallate and Thiobencarb.
Source: Haz-Map, Information on Hazardous Chemicals and Occupational Diseases
Molinate carcinogenicity classification
Cancer Classification: Suggestive Evidence of Carcinogenicity to Humans
Source: Hazardous Substances Data Bank (HSDB)
An IARC group and a CLP classification answer different questions. IARC judges whether the evidence for cancer in humans is strong enough; CLP Annex VI is the legally binding EU classification. A substance can carry one and not the other.
08 · Physical and chemical properties
Molinate properties
Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.
Molinate boiling point
| Property | Value | Conditions | Source |
|---|---|---|---|
| Boiling point | 136.5 °C (277.7 °F) | at 10 mmHg (reduced pressure) | HSDB |
Molinate density
| Property | Value | Conditions | Source |
|---|---|---|---|
| Density | 1.063 g/cm³ | at 20 °C | HSDB |
Molinate solubility
| Property | Value | Conditions | Source |
|---|---|---|---|
| Solubility | Miscible with acetone, ethanol, kerosene, 4-methylpentan-2-one, xylene | HSDB | |
| In water, 970 mg/l @ 25 °C | at 25 °C | HSDB |
Molinate vapor pressure
| Property | Value | Conditions | Source |
|---|---|---|---|
| Vapor pressure | 0.0056 mmHg | at 25 °C | HSDB |
| 0.0056 mmHg | Haz-Map |
Molinate flash point
| Property | Value | Conditions | Source |
|---|---|---|---|
| Flash point | 139 °C (282.2 °F) | HSDB |
Molinate corrosivity
| Property | Value | Conditions | Source |
|---|---|---|---|
| Corrosivity | Noncorrosive | HSDB |
Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.
09 · Fire and explosion
Molinate fire and explosion behaviour
These are descriptions rather than measured values, so they are kept out of the table above and quoted here with the source that reported them.
Molinate fire potential
FIRE POINT= 143 °C.
Source: Hazardous Substances Data Bank (HSDB)
10 · Handling and storage
Molinate storage and handling
Molinate storage conditions
Store away from food and feedstuffs and out of reach of children.
Source: Hazardous Substances Data Bank (HSDB)
Molinate reactivity
MOLINATE is a thiocarbamate. Flammable gases are generated by the combination of thiocarbamates and dithiocarbamates with aldehydes, nitrides, and hydrides. Thiocarbamates and dithiocarbamates are incompatible with acids, peroxides, and acid halides.
Source: CAMEO Chemicals
Planning storage for a mix of chemicals? Check Molinate in the storage compatibility matrix →
11 · Questions
Molinate — frequently asked questions
What is the CAS number of Molinate?
The CAS number of Molinate is 2212-67-1. Its EC number is 218-661-0.
What is the chemical formula of Molinate?
The molecular formula of Molinate is C9H17NOS and its molecular weight is 187.3 g/mol.
What does a Molinate label have to show?
Under CLP Annex VI the label for Molinate carries the pictograms Health hazard, Exclamation mark and Environment and the signal word is Warning.
Is Molinate flammable?
CLP Annex VI assigns Molinate no flammability hazard class. That is not a statement that it cannot burn: the harmonised list only records the hazards that were assessed for it. The flash point reported for it is 139 °C (282.2 °F) (HSDB).
Is Molinate a carcinogen?
CLP Annex VI assigns Molinate H351 — suspected of causing cancer. That is category 2: the evidence points that way but is not conclusive.
What is the boiling point of Molinate?
The boiling point reported for Molinate is 136.5 °C (277.7 °F), at 10 mmHg (reduced pressure) (HSDB).
How should Molinate be stored?
Store away from food and feedstuffs and out of reach of children. (Hazardous Substances Data Bank (HSDB))
Nearby
Substances next to Molinate
Keep going: substances starting with M, or search the whole database by name, CAS number, pictogram or signal word.