Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

Nabam

Nabam is colorless crystals when pure.

CAS 142-59-6 C4H6N2Na2S4 256.4 g/mol Warning

01 · Identification

What Nabam is

Nabam is colorless crystals when pure. Its molecular formula is C4H6N2Na2S4 and its molecular weight is 256.4 g/mol. It is practically insoluble in water.

Under the GHS it carries the signal word Warning.

02 · Identifiers

Nabam identifiers and molecular data

Nabam CAS number and EC number

CAS number142-59-6
EC number205-547-0
Index number (CLP Annex VI)006-014-00-3

Nabam molecular formula and molecular weight

Molecular formulaC4H6N2Na2S4
Molecular weight256.4 g/mol

Other names for Nabam

  • nabam (ISO)
  • disodium ethylenebis(N,N'-dithiocarbamate)

03 · GHS classification

Nabam hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

Nabam pictograms and signal word

Signal wordWarning

Nabam hazard class and category

GHS hazard classes Nabam falls into
Hazard class Category From code Pictogram
Acute toxicity - oral GHS chapter 3.1 Category 4 H302 GHS07
Skin sensitisation GHS chapter 3.4 Category 1 or 1A or 1B H317 GHS07
Specific target organ toxicity - single exposure GHS chapter 3.8 Category 3 H335 GHS07
Hazardous to the aquatic environment - acute GHS chapter 4.1 Category 1 H400 GHS09
Hazardous to the aquatic environment - chronic GHS chapter 4.1 Category 1 H410 GHS09

Where two values are shown with “or”, the hazard statement is shared by more than one category or by more than one class, and the code alone does not say which. H272, for example, belongs to oxidising liquids and to oxidising solids — the physical state decides. The binding answer for a specific entry is in the CLP Annex VI table itself.

Nabam hazard statements (H-codes)

Hazard statements assigned to Nabam
CodeHazard statement
H302 Harmful if swallowed.
H335 May cause respiratory irritation.
H317 May cause an allergic skin reaction.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.

This page lists only the codes assigned to Nabam. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for Nabam

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of Nabam issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

04 · Precautionary statements

Nabam precautionary statements

CLP Annex VI assigns 12 precautionary statements to Nabam. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Disposal

What has to happen to the contents and the empty container.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

Nabam name in 23 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български набам (ISO) динатриев етиленбис( N , N ′-дитиокарбамат)
Spanish español Nabam (ISO) etilen-bis( N, N '-ditiocarbamato) de disodio
Czech čeština nabam (ISO) N, N' -ethylenbis(dithiokarbamát) disodný
Danish dansk nabam (ISO) dinatriumethylenbisdithiocarbamat
German Deutsch Nabam (ISO) Dinatriumethylenbis( N, N' -dithiocarbamat)
Estonian eesti nabaam (ISO) dinaatriumetüleenbis( N , N '-ditiokarbamaat)
Greek ελληνικά nabam (ναβάμη) (ISO) αιθυλενοδις( N, N′ -διθειοκαρβαμιδικό) δινάτριο
English English nabam (ISO) disodium ethylenebis( N, N' -dithiocarbamate)
French français nabam (ISO) éthylènebis( N, N' -dithiocarbamate) de disodium
Croatian hrvatski nabam (ISO) dinatrijev etilenbis( N, N' -ditiokarbamat)
Italian italiano nabam (ISO) etilenbisditiocarbammato di disodio
Latvian latviešu nabams (ISO) dinātrija etilēnbis( N, N '-ditiokarbamāts)
Lithuanian lietuvių nabamas (ISO) dinatrio etilenebis( N, N' -ditiokarbamatas)
Hungarian magyar nabám (ISO) dinátrium-etilén-bisz( N, N' -ditiokarbamát)
Maltese Malti nabam (ISO) etilenebis( N, N' -ditijokarbamat) tad-disodju
Dutch Nederlands nabam (ISO) dinatriumethyleenbisdithiocarbamaat
Polish polski nabam (ISO) etylenobis(ditiokarbaminian) disodu
Portuguese português nabame (ISO) etilenobis( N , N' -ditiocarbamato) de dissódio
Romanian română nabam (ISO) etilen bis( N, N ’-ditiocarbamat) disodic
Slovak slovenčina nabám (ISO) dinátrium- N, N '-etylénbis(ditiokarbamát)
Slovenian slovenščina nabam (ISO) dinatrijev etilenbis( N, N' -ditiokarbamat)
Finnish suomi nabami (ISO) dinatriumetyleenibisditiokarbamaatti
Swedish svenska nabam (ISO) dinatriumetylenbis( N, N' -ditiokarbamat)

All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

Nabam GHS label elements

Everything CLP Annex VI fixes for Nabam, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS07 Exclamation mark pictogramGHS09 Environment pictogram

Warning

Nabam

  • Harmful if swallowed.
  • May cause respiratory irritation.
  • May cause an allergic skin reaction.
  • Very toxic to aquatic life.
  • Very toxic to aquatic life with long lasting effects.
  • Avoid breathing dust/fume/gas/mist/vapours/spray.
  • Do not eat, drink or smoke when using this product.
  • Contaminated work clothing should not be allowed out of the workplace.
  • Avoid release to the environment.
  • Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/
  • IF SWALLOWED:
  • Call a POISON CENTER/doctor/ if you feel unwell.
  • Get medical advice/attention.
  • Rinse mouth.
  • If skin irritation or rash occurs:
  • Collect spillage.
  • Dispose of contents/container to

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open Nabam in the GHS label constructor →

07 · Health hazards

Nabam health hazards and exposure limits

Nabam hazard summary

A skin and mucous membrane irritant; CNS depressant at high concentrations; [Hawley] A skin, eye, and mucous membrane irritant; [HSDB] A skin and eye irritant; May cause skin sensitization; [CAMEO] A respiratory tract irritant; May cause skin sensitization; [eChemPortal: ESIS] Etheylene thiourea (ETU) is a metabolite. [Reference #1] Several of the dialkyldithiocarbamates are known skin sensitizers; See Ethylene thiourea. See Carba mix.

Source: Haz-Map, Information on Hazardous Chemicals and Occupational Diseases

08 · Physical and chemical properties

Nabam properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

Nabam melting point

Property Value Conditions Source
Melting point Decomposes on heating without melting decomposes HSDB

Nabam density

Property Value Conditions Source
Density 1.14 g/cm³ at 20 °C, solid HSDB
1.14 g/cm³ at 20 °C CAMEO

Nabam solubility

Property Value Conditions Source
Solubility Insoluble in common organic solvents. HSDB
Forms a continuous film on plant surfaces, which is said to become insoluble in water. HSDB
In water, 2X10+5 mg/L at room temperature HSDB

Nabam vapor pressure

Property Value Conditions Source
Vapor pressure Negligible HSDB

Nabam corrosivity

Property Value Conditions Source
Corrosivity Aqueous soln is corrosive HSDB

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

09 · Handling and storage

Nabam storage and handling

Nabam reactivity

NABAM is a dithiocarbamate. Flammable gases are generated by the combination of thiocarbamates and dithiocarbamates with aldehydes, nitrides, and hydrides. Thiocarbamates and dithiocarbamates are incompatible with acids, peroxides, and acid halides.

Source: CAMEO Chemicals

Planning storage for a mix of chemicals? Check Nabam in the storage compatibility matrix →

10 · Questions

Nabam — frequently asked questions

What is the CAS number of Nabam?

The CAS number of Nabam is 142-59-6. Its EC number is 205-547-0.

What is the chemical formula of Nabam?

The molecular formula of Nabam is C4H6N2Na2S4 and its molecular weight is 256.4 g/mol.

What does a Nabam label have to show?

Under CLP Annex VI the label for Nabam carries the pictograms Exclamation mark and Environment and the signal word is Warning.

Is Nabam flammable?

CLP Annex VI assigns Nabam no flammability hazard class. That is not a statement that it cannot burn: the harmonised list only records the hazards that were assessed for it.

Is Nabam a carcinogen?

CLP Annex VI records no harmonised carcinogenicity classification for Nabam. Annex VI is a list of agreed classifications, not a list of substances found safe, so this is an absence of a classification rather than a clean bill of health.

What is the melting point of Nabam?

The melting point reported for Nabam is Decomposes on heating without melting, decomposes (HSDB).

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