Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

Oxamyl

Oxamyl is a white crystalline solid with a slight sulfurous odor.

CAS 23135-22-0 C7H13N3O3S 219.26 g/mol Danger

01 · Identification

What Oxamyl is

Oxamyl is a white crystalline solid with a slight sulfurous odor. Its molecular formula is C7H13N3O3S and its molecular weight is 219.26 g/mol. It boils at 310 °C, melts at 101 °C.

Under the GHS it carries the signal word Danger.

02 · Identifiers

Oxamyl identifiers and molecular data

Oxamyl CAS number and EC number

CAS number23135-22-0
EC number245-445-3
Index number (CLP Annex VI)006-059-00-9

Oxamyl molecular formula and molecular weight

Molecular formulaC7H13N3O3S
Molecular weight219.26 g/mol

Other names for Oxamyl

  • oxamyl (ISO)
  • N',N'-dimethylcarbamoyl(methylthio)methylenamine N-methylcarbamate

03 · GHS classification

Oxamyl hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

Oxamyl pictograms and signal word

Signal wordDanger

Oxamyl hazard class and category

GHS hazard classes Oxamyl falls into
Hazard class Category From code Pictogram
Acute toxicity - oral GHS chapter 3.1 Category 1 or 2 H300 GHS06
Acute toxicity - dermal GHS chapter 3.1 Category 4 H312 GHS07
Acute toxicity - inhalation GHS chapter 3.1 Category 1 or 2 H330 GHS06
Hazardous to the aquatic environment - chronic GHS chapter 4.1 Category 2 H411 GHS09

Where two values are shown with “or”, the hazard statement is shared by more than one category or by more than one class, and the code alone does not say which. H272, for example, belongs to oxidising liquids and to oxidising solids — the physical state decides. The binding answer for a specific entry is in the CLP Annex VI table itself.

Oxamyl hazard statements (H-codes)

Hazard statements assigned to Oxamyl
CodeHazard statement
H330 Fatal if inhaled.
H300 Fatal if swallowed.
H312 Harmful in contact with skin.
H411 Toxic to aquatic life with long lasting effects.

This page lists only the codes assigned to Oxamyl. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for Oxamyl

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of Oxamyl issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

04 · Precautionary statements

Oxamyl precautionary statements

CLP Annex VI assigns 14 precautionary statements to Oxamyl. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Disposal

What has to happen to the contents and the empty container.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

Oxamyl name in 23 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български оксамил (ISO) N ′, N ′-диметилкарбамоил(метилтио)метиленамин- N -метилкарбамат
Spanish español Oxamilo (ISO) N -metilcarbamato de N',N '-dimetilcarbamoil(metiltio)metilenamina
Czech čeština oxamyl (ISO) {[2-dimethylamino-1-(methylsulfanyl)-2-oxoethyliden]iminyl}- N -methylkarbamát
Danish dansk oxamyl (ISO) N' , N' -dimethylcarbamoyl(methylthio)methylenamin- N- methylcarbamat
German Deutsch Oxamyl (ISO) N',N' -Dimethylcarbamoyl(methylthio)methylenamin- N -methylcarbamat
Estonian eesti oksamüül (ISO) N ', N '-dimetüülkarbamoüül(metüültio)metüleenamiin- N -metüülkarbamaat
Greek ελληνικά oxamyl (οξαμύλη) (ISO) N -μεθυλοκαρβαμιδική N′,N′ -διμεθυλοκαρβαμοϋλο(μεθυλοθειο)μεθυλεναμίνη
English English oxamyl (ISO) N',N' -dimethylcarbamoyl(methylthio)methylenamine N -methylcarbamate
French français oxamyl (ISO) N -méthylcarbamate de N',N' -diméthylcarbamoyl(méthylthio)méthylénamine
Croatian hrvatski oksamil (ISO) N',N' -dimetil-karbamoil(metiltio)metilenamin- N -metil-karbamat
Italian italiano ossamil (ISO) N-metilcarbammato di N ', N '-dimetilcarbammoil(metiltio)metilenamina
Latvian latviešu oksamils (ISO) N',N' -dimetilkarbamoil(metiltio)metilēnamīn- N -metilkarbamāts
Lithuanian lietuvių oksamilas (ISO) N',N'-dimetilkarbamoil(metiltio)metilenamino N-metilkarbamatas
Hungarian magyar oxamil (ISO) N',N' -dimetil-karbamoil(metiltio)metilén-amin- N -metilkarbamát
Maltese Malti ossamil (ISO) N-metilkarbamat ta’ N’,N’-dimetilkarbamojl(metiltijo)metilenamina
Dutch Nederlands oxamyl (ISO) N',N' -dimethylcarbamoyl(methylthio)methylenamine- N -methylcarbamaat
Polish polski oksamyl (ISO) O -(metylokarbamoilo)monooksym 2-(dimetyloamino)-1-(metylosulfanylo)-glioksalu
Portuguese português oxamil (ISO) N -metilcarbamato N ', N '-dimetilcarbamoil(metiltio)metilenamínico
Romanian română oxamil (ISO) N -metilcarbamat de N',N' - dimetilcarbomoil(metiltio) metilenamină
Slovak slovenčina oxamyl (ISO) N',N '-dimetylkarbamoyl(metyltio)metylénamín N -metylkarbamát
Slovenian slovenščina oksamil (ISO) N',N' -dimetilkarbamoil(metiltio)metilenamin N -metilkarbamat
Finnish suomi oksamyyli (ISO) N',N' -dimetyylikarbamyyli(metyylitio)metyleeniamiini- N -metyylikarbamaatti
Swedish svenska oxamyl (ISO) N',N' -dimetylkarbamoyl(metyltio)metylenamin- N -metylkarbamat

All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

Oxamyl GHS label elements

Everything CLP Annex VI fixes for Oxamyl, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS06 Skull and crossbones pictogramGHS09 Environment pictogram

Danger

Oxamyl

  • Fatal if inhaled.
  • Fatal if swallowed.
  • Harmful in contact with skin.
  • Toxic to aquatic life with long lasting effects.
  • Do not breathe dust/fume/gas/mist/vapours/spray.
  • Do not eat, drink or smoke when using this product.
  • Use only outdoors or in a well-ventilated area.
  • Avoid release to the environment.
  • Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/
  • IF SWALLOWED:
  • IF ON SKIN:
  • IF INHALED:
  • Immediately call a POISON CENTER/doctor/
  • Call a POISON CENTER/doctor/ if you feel unwell.
  • Rinse mouth.
  • Wash with plenty of water/
  • Collect spillage.
  • Dispose of contents/container to

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open Oxamyl in the GHS label constructor →

07 · Health hazards

Oxamyl health hazards and exposure limits

Oxamyl hazard summary

No increase in birth defects at maternally toxic doses in rats or rabbits; Reduced litter size in reproductive studies of rats; [REPROTOX] See CARBAMATE INSECTICIDES.

Source: Haz-Map, Information on Hazardous Chemicals and Occupational Diseases

Oxamyl carcinogenicity classification

Cancer Classification: Group E Evidence of Non-carcinogenicity for Humans

Source: Hazardous Substances Data Bank (HSDB)

An IARC group and a CLP classification answer different questions. IARC judges whether the evidence for cancer in humans is strong enough; CLP Annex VI is the legally binding EU classification. A substance can carry one and not the other.

08 · Physical and chemical properties

Oxamyl properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

Oxamyl boiling point

Property Value Conditions Source
Boiling point 310 °C (590 °F) at 760 mmHg DOE PAC
Decomposes on distillation decomposes HSDB

Oxamyl melting point

Property Value Conditions Source
Melting point 101 °C (213.8 °F) range, midpoint shown HSDB
101.11 °C (214 °F) range, midpoint shown CAMEO

Oxamyl density

Property Value Conditions Source
Density 0.97 g/cm³ at 25 °C HSDB
0.98 g/cm³ at 25 °C DOE PAC

Oxamyl solubility

Property Value Conditions Source
Solubility Solubility (g/100 ml @ 25 °C): acetone, 67; ethanol, 33; 2-propanol, 11; methanol, 144; toluene, 1 at 25 °C HSDB
In water, 280 g/l @ 25 °C at 25 °C HSDB
Soluble at 77.0 °F (280g/kg) (NTP, 1992) at 25 °C CAMEO

Oxamyl vapor pressure

Property Value Conditions Source
Vapor pressure 0.00023 mmHg HSDB
0.00023 mmHg at 25 °C CAMEO

Oxamyl corrosivity

Property Value Conditions Source
Corrosivity Non-corrosive HSDB

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

09 · Handling and storage

Oxamyl storage and handling

Oxamyl storage conditions

You should protect this material from exposure to light and air, and store it under refrigerated temperatures.

Source: Hazardous Substances Data Bank (HSDB)

Oxamyl incompatible materials

Incompatible with alkaline materials.

Source: Hazardous Substances Data Bank (HSDB)

Oxamyl reactivity

OXAMYL is a carbamate ester. Carbamates are chemically similar to, but more reactive than amides. Like amides they form polymers such as polyurethane resins. Carbamates are incompatible with strong acids and bases, and especially incompatible with strong reducing agents such as hydrides. Flammable gaseous hydrogen is produced by the combination of active metals or nitrides with carbamates. Strongly oxidizing acids, peroxides, and hydroperoxides are incompatible with carbamates.

Source: CAMEO Chemicals

Planning storage for a mix of chemicals? Check Oxamyl in the storage compatibility matrix →

10 · Questions

Oxamyl — frequently asked questions

What is the CAS number of Oxamyl?

The CAS number of Oxamyl is 23135-22-0. Its EC number is 245-445-3.

What is the chemical formula of Oxamyl?

The molecular formula of Oxamyl is C7H13N3O3S and its molecular weight is 219.26 g/mol.

What does a Oxamyl label have to show?

Under CLP Annex VI the label for Oxamyl carries the pictograms Skull and crossbones and Environment and the signal word is Danger.

Is Oxamyl flammable?

CLP Annex VI assigns Oxamyl no flammability hazard class. That is not a statement that it cannot burn: the harmonised list only records the hazards that were assessed for it.

Is Oxamyl a carcinogen?

CLP Annex VI records no harmonised carcinogenicity classification for Oxamyl. Annex VI is a list of agreed classifications, not a list of substances found safe, so this is an absence of a classification rather than a clean bill of health.

What is the boiling point of Oxamyl?

The boiling point reported for Oxamyl is 310 °C (590 °F), at 760 mmHg (DOE PAC).

What is the melting point of Oxamyl?

The melting point reported for Oxamyl is 101 °C (213.8 °F), range, midpoint shown (HSDB).

How should Oxamyl be stored?

You should protect this material from exposure to light and air, and store it under refrigerated temperatures. (Hazardous Substances Data Bank (HSDB))

Nearby

Substances next to Oxamyl

Keep going: substances starting with O, or search the whole database by name, CAS number, pictogram or signal word.

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