Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

Petroleum gases, liquefied

Petroleum gases, liquefied is a substance with a harmonised classification under EU CLP.

CAS 68476-85-7 Danger

01 · Identification

What Petroleum gases, liquefied is

Petroleum gases, liquefied is a substance with a harmonised classification under EU CLP.

Under the GHS it carries the signal word Danger.

02 · Identifiers

Petroleum gases, liquefied identifiers and molecular data

Petroleum gases, liquefied CAS number and EC number

CAS number68476-85-7
EC number270-704-2
Index number (CLP Annex VI)649-202-00-6

Other names for Petroleum gases, liquefied

  • Petroleum gas
  • [A complex combination of hydrocarbons produced by the distillation of crude oil. It consists of hydrocarbons having carbon numbers predominantly in the range of C3 through C7 and boiling in the range of approximately – 40 °C to 80 °C (– 40 °F to 176 °F).]

03 · GHS classification

Petroleum gases, liquefied hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

Petroleum gases, liquefied pictograms and signal word

Signal wordDanger

Petroleum gases, liquefied hazard class and category

GHS hazard classes Petroleum gases, liquefied falls into
Hazard class Category From code Pictogram
Flammable gases GHS chapter 2.2 Category 1A H220 GHS02
Germ cell mutagenicity GHS chapter 3.5 Category 1A or 1B H340 GHS08
Carcinogenicity GHS chapter 3.6 Category 1A or 1B H350 GHS08

Where two values are shown with “or”, the hazard statement is shared by more than one category or by more than one class, and the code alone does not say which. H272, for example, belongs to oxidising liquids and to oxidising solids — the physical state decides. The binding answer for a specific entry is in the CLP Annex VI table itself.

Petroleum gases, liquefied hazard statements (H-codes)

Hazard statements assigned to Petroleum gases, liquefied
CodeHazard statement
H220 Extremely flammable gas.
H350 May cause cancer <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
H340 May cause genetic defects <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.

This page lists only the codes assigned to Petroleum gases, liquefied. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for Petroleum gases, liquefied

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of Petroleum gases… issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

04 · Precautionary statements

Petroleum gases, liquefied precautionary statements

CLP Annex VI assigns 7 precautionary statements to Petroleum gases, liquefied. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Response

What to do once exposure, spillage or fire has already happened.

Storage

How the container has to be kept between uses.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

Petroleum gases, liquefied name in 23 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български Нефтени газове, втечнени нефтен газ
Spanish español Gases del petróleo, licuados gas de petróleo
Czech čeština ropné plyny, zkapalněné ropný plyn
Danish dansk råoliegasser, fortættede kulbrintegasser
German Deutsch Erdölgase, flüssig Gase aus der Erdölverarbeitung
Estonian eesti naftagaasid, veeldatud naftagaas
Greek ελληνικά Αέρια πετρελαίου, υγροποιημένα Πετρελαϊκό αέριο
English English Petroleum gases, liquefied Petroleum gas
French français Gaz de pétrole liquélifés gaz de pétrole
Croatian hrvatski naftni plinovi, ukapljeni naftni plin
Italian italiano gas di petrolio, liquefatti gas di petrolio
Latvian latviešu Naftas pavadgāzes, sašķidrinātas Naftas pavadgāze
Lithuanian lietuvių Naftos dujos, suskystintosios Naftos dujos
Hungarian magyar Ásványolaj gázok, cseppfolyósított Ásványolaj gáz
Maltese Malti Gassijiet taż-żejt mhux maħdum, likwifikati Gass taż-żejt mhux maħdum
Dutch Nederlands petroleumgassen, vloeibaar gemaakt petroleumgas
Polish polski Gazy z ropy naftowej, skroplone Gaz z ropy naftowej
Portuguese português gases de petróleo, liquefeitos gás de petróleo
Romanian română Gaze petroliere lichefiate Gaz petrolier
Slovak slovenčina ropné plyny, skvapalnené plyn zo spracovania ropy[Komplexná zmes uhľovodíkov získavaná destiláciou ropy. Pozostáva z uhľovodíkov s počtom atómov uhlíka prevažne v rozmedzí od C 3 do C 7 . Má teplotu varu v rozmedzí približne od mínus 40 o C do 80 o C (od mínus 40 o F do 176 o F).
Slovenian slovenščina naftni plini, utekočinjeni naftni plin
Finnish suomi Maaöljykaasut, nesteytetyt Maaöljykaasu
Swedish svenska Petroleumgaser, flytande Petroleumgas

All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

Petroleum gases, liquefied GHS label elements

Everything CLP Annex VI fixes for Petroleum gases, liquefied, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS04 Gas cylinder pictogramGHS02 Flame pictogramGHS08 Health hazard pictogram

Danger

Petroleum gases, liquefied

  • Extremely flammable gas.
  • May cause cancer <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
  • May cause genetic defects <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
  • Obtain special instructions before use.
  • Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
  • Keep container tightly closed.
  • Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/
  • IF exposed or concerned:
  • Get medical advice/attention.
  • Store in a well-ventilated place.

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open Petroleum gases, liquefied in the GHS label constructor →

07 · Transport

Petroleum gases, liquefied UN number and transport classification

Transport classification is a separate system from the GHS classification above. It decides how a package is marked and how a load may be carried; it does not follow from the workplace label, and the workplace label does not follow from it. The entries below are linked by CAS number, never by name.

Petroleum gases, liquefied under UN 1075 — shipping name, class and packing group

Europe · ADR 2025, Table A

Proper shipping name (3.1.2) Class Classification code PG Labels (column 5)
PETROLEUM GASES, LIQUEFIED 2 2F
  • ADR label model 2.1 — Flammable gas
2.1

Source: ADR 2025, Table A of Chapter 3.2 · ECE/TRANS/352 Vol. I (UNECE). Class 2 is “Gases” (ADR 2.1.1.1).

Proper shipping name (column 2) Class or division PG Labels (column 6)
Petroleum gases, liquefied or Liquefied petroleum gas 2.1
  • US DOT FLAMMABLE GAS label (§172.417)
2.1

Source: 49 CFR 172.101 Hazardous Materials Table · eCFR, revision 2026-08-03. Class 2.1 is “Flammable gas” (49 CFR 173.2).

Full UN 1075 entry — special provisions, packing instructions, quantity limits and the orange plate →

08 · Questions

Petroleum gases, liquefied — frequently asked questions

What is the CAS number of Petroleum gases, liquefied?

The CAS number of Petroleum gases, liquefied is 68476-85-7. Its EC number is 270-704-2.

What does a Petroleum gases, liquefied label have to show?

Under CLP Annex VI the label for Petroleum gases, liquefied carries the pictograms Gas cylinder, Flame and Health hazard and the signal word is Danger.

Is Petroleum gases, liquefied flammable?

Yes. CLP Annex VI assigns Petroleum gases, liquefied H220 — extremely flammable gas.

Is Petroleum gases, liquefied a carcinogen?

Yes. CLP Annex VI classifies Petroleum gases, liquefied as a category 1A or 1B carcinogen and assigns it H350: may cause cancer.

How should Petroleum gases, liquefied be stored?

CLP Annex VI assigns Petroleum gases, liquefied the storage statement P403.

Nearby

Substances next to Petroleum gases, liquefied

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