Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

Spirodiclofen

Spirodiclofen is a white powder with a no characteristic odor.

CAS 148477-71-8 Danger

01 · Identification

What Spirodiclofen is

Spirodiclofen is a white powder with a no characteristic odor. It melts at 94.8 °C.

Under the GHS it carries the signal word Danger.

02 · Identifiers

Spirodiclofen identifiers and molecular data

Spirodiclofen CAS number and EC number

CAS number148477-71-8
Index number (CLP Annex VI)607-730-00-4

Other names for Spirodiclofen

  • spirodiclofen (ISO)
  • 3-(2,4-dichlorophenyl)-2-oxo-1-oxaspiro[4.5]dec-3-en-4-yl 2,2-dimethylbutyrate

03 · GHS classification

Spirodiclofen hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

Spirodiclofen pictograms and signal word

Signal wordDanger

Spirodiclofen hazard class and category

GHS hazard classes Spirodiclofen falls into
Hazard class Category From code Pictogram
Skin sensitisation GHS chapter 3.4 Category 1 or 1A or 1B H317 GHS07
Carcinogenicity GHS chapter 3.6 Category 1A or 1B H350 GHS08
Specific target organ toxicity - repeated exposure GHS chapter 3.9 Category 2 H373 GHS08
Hazardous to the aquatic environment - chronic GHS chapter 4.1 Category 1 H410 GHS09

Where two values are shown with “or”, the hazard statement is shared by more than one category or by more than one class, and the code alone does not say which. H272, for example, belongs to oxidising liquids and to oxidising solids — the physical state decides. The binding answer for a specific entry is in the CLP Annex VI table itself.

Spirodiclofen hazard statements (H-codes)

Hazard statements assigned to Spirodiclofen
CodeHazard statement
H350 May cause cancer <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
H361f Suspected of damaging fertility.
H373 May cause damage to organs <or state all organs affected, if known> through prolonged or repeated exposure <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
H317 May cause an allergic skin reaction.
H410 Very toxic to aquatic life with long lasting effects.

This page lists only the codes assigned to Spirodiclofen. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for Spirodiclofen

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of Spirodiclofen issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

04 · Precautionary statements

Spirodiclofen precautionary statements

CLP Annex VI assigns 13 precautionary statements to Spirodiclofen. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Disposal

What has to happen to the contents and the empty container.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

Spirodiclofen name in 23 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български спиродиклофен (ISO) 3-(2,4-дихлорофенил)-2-оксо-1-оксаспиро[4.5]дец-3-ен-4-илов 2,2-диметилбутират
Spanish español Espirodiclofeno (ISO) 2,2-dimetilbutirato de 3-(2,4-diclorofenil)-2-oxo-1-oxaespiro[4.5]dec-3-en-4-ilo
Czech čeština spirodiklofen (ISO) 3-(2,4-dichlorfenyl)-2-oxo-1-oxaspiro[4.5]dec-3-en-4-yl-2,2-dimethylbutyrát
Danish dansk spirodiclofen (ISO) 3-(2,4-dichlorphenyl)-2-oxo-1-oxaspiro[4,5]dec-3-en-4-yl-2,2-dimethylbutyrat
German Deutsch Spirodiclofen (ISO) 3-(2,4-Dichlorphenyl)-2-oxo-1-oxaspiro[4.5]dec-3-en-4-yl 2,2-dimethylbutyrat
Estonian eesti spirodiklofeen (ISO) 3-(2,4-diklorofenüül)-2-okso-1-oksaspiro[4.5]dets-3-een-4-üül-2,2-dimetüülbutüraat
Greek ελληνικά spirodiclofen (σπειροδικλοφαίνη) (ISO) 2,2-διμεθυλοβουτυρικός 3-(2,4-διχλωροφαινυλ)-2-οξο-1-οξασπειρο[4.5]δεκ-3-εν-4-υλεστέρας2,2-διμεθυλοβουτυρικό 3-(2,4-διχλωροφαινυλ)-2-οξο-1-οξασπειρο[4.5]δεκ-3-εν-4-ύλιο
English English spirodiclofen (ISO) 3-(2,4-dichlorophenyl)-2-oxo-1-oxaspiro[4.5]dec-3-en-4-yl 2,2-dimethylbutyrate
French français spirodiclofène (ISO) 2,2-diméthylbutyrate de 3-(2,4-dichlorophényl)-2-oxo-1-oxaspiro[4.5]déc-3-én-4-yle
Croatian hrvatski spirodiklofen (ISO) 3-(2,4-diklorfenil)-2-okso-1-oksaspiro[4.5]dec-3-en-4-il-2,2-dimetilbutirat
Italian italiano spirodiclofen (ISO) 3-(2,4-diclorofenil)-2-osso-1-ossaspiro[4.5]dec-3-en-4-il 2,2-dimetilbutirato
Latvian latviešu spirodiklofēns (ISO) 3-(2,4-dihlorfenil)-2-okso-1-oksaspiro[4.5]dec-3-ēn-4-il 2,2-dimetilbutirāts
Lithuanian lietuvių spirodiklofenas (ISO) 3-(2,4-dichlorfenil)-2-okso-1-oksaspiro[4.5]dek-3-en-4-il-2,2-dimetilbutiratas
Hungarian magyar spirodiklofen (ISO) 3-(2,4-diklór-fenil)-2-oxo-1-oxaspiro[4.5]dec-3-én-4-il-2,2-dimetilbutirát
Maltese Malti spirodiklofen (ISO) 3-(2,4-diklorofenil)-2-osso-1-ossaspiro[4.5]dek-3-en-4-il 2,2-dimetilbutirat
Dutch Nederlands spirodiclofen (ISO) 3-(2,4-dichloorfenyl)-2-oxo-1-oxaspiro[4.5]dec-3-een-4-yl-2,2-dimethylbutyraat
Polish polski spirodiklofen (ISO) 2,2-dimetylomaślan 3-(2,4-dichlorofenylo)-2-okso-1-oksaspiro[4.5]dek-3-en-4-ylu
Portuguese português espirodiclofena (ISO) 2,2-dimetilbutirato de 3-(2,4-diclorofenil)-2-oxo-1-oxaspiro[4.5]dec-3-en-4-ilo
Romanian română spirodiclofen (ISO) 3-(2,4-diclorofenil)-2-oxo-1-oxaspiro[4.5]dec-3-en-4-il 2,2-dimetilbutirat
Slovak slovenčina spirodiklofén (ISO) 3-(2,4-dichlórfenyl)-2-oxo-1-oxaspiro[4.5]dec-3-en-4-yl 2,2-dimetylbutyrát
Slovenian slovenščina spirodiklofen (ISO) 3-(2,4-diklorofenil)-2-okso-1-oksaspiro[4.5]dec-3-en-4-il 2,2-dimetilbutirat
Finnish suomi spirodiklofeeni (ISO) 3-(2,4-dikloorifenyyli)-2-okso-1-oksaspiro[4,5]dek-3-en-4-yyli-2,2-dimetyylibutyraatti
Swedish svenska spirodiklofen (ISO) 3-(2,4-diklorfenyl)-2-oxo-1-oxaspiro[4.5]deka-3-en-4-yl-2,2-dimetylbutyrat

All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

Spirodiclofen GHS label elements

Everything CLP Annex VI fixes for Spirodiclofen, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS08 Health hazard pictogramGHS07 Exclamation mark pictogramGHS09 Environment pictogram

Danger

Spirodiclofen

  • May cause cancer <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
  • Suspected of damaging fertility.
  • May cause damage to organs <or state all organs affected, if known> through prolonged or repeated exposure <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
  • May cause an allergic skin reaction.
  • Very toxic to aquatic life with long lasting effects.
  • Obtain special instructions before use.
  • Do not breathe dust/fume/gas/mist/vapours/spray.
  • Avoid breathing dust/fume/gas/mist/vapours/spray.
  • Do not eat, drink or smoke when using this product.
  • Contaminated work clothing should not be allowed out of the workplace.
  • Avoid release to the environment.
  • Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/
  • IF exposed or concerned:
  • Get medical advice/attention.
  • Get medical advice/attention if you feel unwell.
  • If skin irritation or rash occurs:
  • Collect spillage.
  • Dispose of contents/container to

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open Spirodiclofen in the GHS label constructor →

07 · Physical and chemical properties

Spirodiclofen properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

Spirodiclofen melting point

Property Value Conditions Source
Melting point 94.8 °C (202.6 °F) HSDB

Spirodiclofen density

Property Value Conditions Source
Density 1.29 g/cm³ HSDB

Spirodiclofen solubility

Property Value Conditions Source
Solubility In water, 50 (pH 4); 190 (pH 7); both in ug/L at 20 °C at 20 °C HSDB

Spirodiclofen vapor pressure

Property Value Conditions Source
Vapor pressure 5.25e-9 mmHg at 25 °C HSDB

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

08 · Source notes

Further notes on Spirodiclofen

These are descriptions rather than measured values, so they are kept out of the table above and quoted here with the source that reported them.

Solubility

In n-heptane 20, polyethylene glycol 24, n-octanol 44, isopropanol 47, DMSO 75, acetone, dichlormethane, ethyl acetate, acetonitrile and xylene >250 (all in g/L, 20 °C)

Source: HSDB

09 · Handling and storage

Spirodiclofen storage and handling

Spirodiclofen storage conditions

Do not allow product or containers to freeze. Store in a cool, dry place and in such a manner as to prevent cross contamination with other pesticides, fertilizers food, and feed. Store in original container and out of reach of children, preferably in a locked storage area. /Envidor 2 SC Miticide/

Source: Hazardous Substances Data Bank (HSDB)

Planning storage for a mix of chemicals? Check Spirodiclofen in the storage compatibility matrix →

10 · Questions

Spirodiclofen — frequently asked questions

What is the CAS number of Spirodiclofen?

The CAS number of Spirodiclofen is 148477-71-8.

What does a Spirodiclofen label have to show?

Under CLP Annex VI the label for Spirodiclofen carries the pictograms Health hazard, Exclamation mark and Environment and the signal word is Danger.

Is Spirodiclofen flammable?

CLP Annex VI assigns Spirodiclofen no flammability hazard class. That is not a statement that it cannot burn: the harmonised list only records the hazards that were assessed for it.

Is Spirodiclofen a carcinogen?

Yes. CLP Annex VI classifies Spirodiclofen as a category 1A or 1B carcinogen and assigns it H350: may cause cancer.

What is the melting point of Spirodiclofen?

The melting point reported for Spirodiclofen is 94.8 °C (202.6 °F) (HSDB).

How should Spirodiclofen be stored?

Do not allow product or containers to freeze. Store in a cool, dry place and in such a manner as to prevent cross contamination with other pesticides, fertilizers food, and feed. Store in original container and out of reach of children, preferably in a locked storage area. /Envidor 2 SC Miticide/ (Hazardous Substances Data Bank (HSDB))

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