Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

Sulfallate

Sulfallate is an amber oil.

CAS 95-06-7 C8H14ClNS2 223.8 g/mol Danger

01 · Identification

What Sulfallate is

Sulfallate is an amber oil. Its molecular formula is C8H14ClNS2 and its molecular weight is 223.8 g/mol. It boils at 129 °C.

Under the GHS it carries the signal word Danger. It is classed as carcinogens.

02 · Identifiers

Sulfallate identifiers and molecular data

Sulfallate CAS number and EC number

CAS number95-06-7
EC number202-388-9
Index number (CLP Annex VI)006-038-00-4

Sulfallate molecular formula and molecular weight

Molecular formulaC8H14ClNS2
Molecular weight223.8 g/mol
Chemical class Carcinogens

Other names for Sulfallate

  • sulfallate (ISO)
  • 2-chloroallyl N,N-dimethyldithiocarbamate

03 · GHS classification

Sulfallate hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

Sulfallate pictograms and signal word

Signal wordDanger

Sulfallate hazard class and category

GHS hazard classes Sulfallate falls into
Hazard class Category From code Pictogram
Acute toxicity - oral GHS chapter 3.1 Category 4 H302 GHS07
Carcinogenicity GHS chapter 3.6 Category 1A or 1B H350 GHS08
Hazardous to the aquatic environment - acute GHS chapter 4.1 Category 1 H400 GHS09
Hazardous to the aquatic environment - chronic GHS chapter 4.1 Category 1 H410 GHS09

Where two values are shown with “or”, the hazard statement is shared by more than one category or by more than one class, and the code alone does not say which. H272, for example, belongs to oxidising liquids and to oxidising solids — the physical state decides. The binding answer for a specific entry is in the CLP Annex VI table itself.

Sulfallate hazard statements (H-codes)

Hazard statements assigned to Sulfallate
CodeHazard statement
H350 May cause cancer <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
H302 Harmful if swallowed.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.

This page lists only the codes assigned to Sulfallate. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for Sulfallate

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of Sulfallate issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

04 · Precautionary statements

Sulfallate precautionary statements

CLP Annex VI assigns 11 precautionary statements to Sulfallate. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Disposal

What has to happen to the contents and the empty container.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

Sulfallate name in 23 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български сулфалат (ISO) 2-хлороалилов N, N -диметилдитиокарбамат
Spanish español Sulfalato (ISO) N, N -dimetilditiocarbamato de 2-cloroalilo
Czech čeština sulfallát (ISO) (2-chlorallyl)- N, N -diethyldithiokarbamát
Danish dansk sulfallat (ISO) 2-chlorallyldiethyldithiocarbamat
German Deutsch Sulfallat (ISO) 2-Chlorallyl-N, N-dimethyldithiocarbamat
Estonian eesti sulfallaat (ISO) 2-kloroallüül- N , N -dimetüülditiokarbamaat
Greek ελληνικά sulfallate (σουλφαλλάτη) (ISO) N, N -διμεθυλοδιθειοκαρβαμιδικός 2-χλωροαλλυλεστέρας
English English sulfallate (ISO) 2-chloroallyl N, N -dimethyldithiocarbamate
French français sulfallate (ISO) N, N -diméthyldithiocarbamate de 2-chloroallyle
Croatian hrvatski sulfalat (ISO) 2-kloralil- N, N -dimetil-ditiokarbamat
Italian italiano sulfallate (ISO) dietilditiocarbammato di 2-cloroallile
Latvian latviešu sulfallāts (ISO) 2-hloralil N, N -dimetilditiokarbamāts
Lithuanian lietuvių sulfalatas (ISO) 2-chloralil-N, N-dimetilditiokarbamatas
Hungarian magyar szulfallát (ISO) 2-klórallil- N, N -dimetilditiokarbamát
Maltese Malti sulfallat (ISO) N, N-dimetilditijokarbamat ta’ 2-kloroallil
Dutch Nederlands sulfallaat (ISO) 2-chloorallyl- N, N -dimethyldithiocarbamaat
Polish polski sulfalat (ISO) dietyloditiokarbaminian 2-chloroallilu
Portuguese português sulfalato (ISO) N , N -dimetilditiocarbamato de 2-cloroalilo
Romanian română sulfalat (ISO) N, N -dimetilditiocarbamat de 2-cloroalil
Slovak slovenčina sulfalát (ISO) S -(2-chlóralyl)- N, N -dimetylditiokarbamát
Slovenian slovenščina sulfalat (ISO) 2-kloroalil N, N -dimetilditiokarbamat
Finnish suomi sulfallaatti (ISO) 2-klooriallyyli- N , N -dimetyyliditiokarbamaatti
Swedish svenska sulfallat (ISO) 2-klorallyl N, N -dimetylditiokarbamat

All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

Sulfallate GHS label elements

Everything CLP Annex VI fixes for Sulfallate, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS08 Health hazard pictogramGHS07 Exclamation mark pictogramGHS09 Environment pictogram

Danger

Sulfallate

  • May cause cancer <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
  • Harmful if swallowed.
  • Very toxic to aquatic life.
  • Very toxic to aquatic life with long lasting effects.
  • Obtain special instructions before use.
  • Do not eat, drink or smoke when using this product.
  • Avoid release to the environment.
  • Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/
  • IF SWALLOWED:
  • IF exposed or concerned:
  • Call a POISON CENTER/doctor/ if you feel unwell.
  • Get medical advice/attention.
  • Rinse mouth.
  • Collect spillage.
  • Dispose of contents/container to

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open Sulfallate in the GHS label constructor →

07 · Health hazards

Sulfallate health hazards and exposure limits

Sulfallate hazard summary

May cause skin and eye irritation on prolonged contact; [Merck Index] Although marked adverse effects may follow injection of EBDC compounds into animals, systemic toxicity by oral and dermal routes is generally low. [EPA Pesticides, p. 144] Several of the dialkyldithiocarbamates are known skin sensitizers; See Carba mix.

Source: Haz-Map, Information on Hazardous Chemicals and Occupational Diseases

Sulfallate carcinogenicity classification

IARC classification Group 2B — Possibly carcinogenic to humans
IARC monographs Volume 30: (1983) Miscellaneous Pesticides

Under the conditions of this bioassay, dietary administration of sulfallate was carcinogenic to Osborne-Mendel rats and to B6C3F1 mice, inducing mammary gland tumors in females of both species, tumors of the forestomach in male rats, and lung tumors in male mice.

Source: US National Toxicology Program · TR-115: Bioassay of Sulfallate for Possible Carcinogenicity (CASRN 95-06-7) (1978 )

Classification of carcinogenicity: 1) evidence in humans: No adequate data. 2) evidence in animals: Sufficient evidence. Overall summary evaluation of carcinogenic risk to humans is Group 2B: The agent is possibly carcinogenic to humans. /From table/

Source: Hazardous Substances Data Bank (HSDB)

Sulfallate: reasonably anticipated to be a human carcinogen.

Source: Hazardous Substances Data Bank (HSDB)

An IARC group and a CLP classification answer different questions. IARC judges whether the evidence for cancer in humans is strong enough; CLP Annex VI is the legally binding EU classification. A substance can carry one and not the other.

08 · Physical and chemical properties

Sulfallate properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

Sulfallate boiling point

Property Value Conditions Source
Boiling point 129 °C (264.2 °F) range, midpoint shown HSDB
128.89 °C (264 °F) range, midpoint shown, at 1 mmHg (reduced pressure) CAMEO

Sulfallate density

Property Value Conditions Source
Density 1.088 g/cm³ CAMEO
1.088 g/cm³ at 25 °C HSDB

Sulfallate solubility

Property Value Conditions Source
Solubility Soluble in most organic solvents. HSDB
In water, 100 mg/L at 25 °C at 25 °C HSDB
Soluble in acetone, benzene, chloroform, ethyl acetate, ethyl alcohol, kerosene at 25 °C at 25 °C HSDB

Sulfallate vapor pressure

Property Value Conditions Source
Vapor pressure 0.0022 mmHg at 20 °C HSDB
0.0022 mmHg Haz-Map

Sulfallate flash point

Property Value Conditions Source
Flash point 93.33 °C (200 °F) above this value CAMEO

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

09 · Handling and storage

Sulfallate storage and handling

Sulfallate storage conditions

PRECAUTIONS FOR "CARCINOGENS": Storage site should be as close as practical to lab in which carcinogens are to be used, so that only small quantities required for ... expt need to be carried. Carcinogens should be kept in only one section of cupboard, an explosion-proof refrigerator or freezer (depending on chemicophysical properties ...) that bears appropriate label. An inventory ... should be kept, showing quantity of carcinogen & date it was acquired ... Facilities for dispensing ... should be contiguous to storage area. /Chemical Carcinogens/

Source: Hazardous Substances Data Bank (HSDB)

Sulfallate incompatible materials

Strong oxidizers

Source: Hazardous Substances Data Bank (HSDB)

Sulfallate reactivity

SULFALLATE is incompatible with strong oxidizing agents. Also incompatible with alkalis. (NTP, 1992).

Source: CAMEO Chemicals

Planning storage for a mix of chemicals? Check Sulfallate in the storage compatibility matrix →

10 · Questions

Sulfallate — frequently asked questions

What is the CAS number of Sulfallate?

The CAS number of Sulfallate is 95-06-7. Its EC number is 202-388-9.

What is the chemical formula of Sulfallate?

The molecular formula of Sulfallate is C8H14ClNS2 and its molecular weight is 223.8 g/mol.

What does a Sulfallate label have to show?

Under CLP Annex VI the label for Sulfallate carries the pictograms Health hazard, Exclamation mark and Environment and the signal word is Danger.

Is Sulfallate flammable?

CLP Annex VI assigns Sulfallate no flammability hazard class. That is not a statement that it cannot burn: the harmonised list only records the hazards that were assessed for it. The flash point reported for it is 93.33 °C (200 °F), above this value (CAMEO).

Is Sulfallate a carcinogen?

Yes. CLP Annex VI classifies Sulfallate as a category 1A or 1B carcinogen and assigns it H350: may cause cancer. IARC places it in Group 2B: possibly carcinogenic to humans.

What is the boiling point of Sulfallate?

The boiling point reported for Sulfallate is 129 °C (264.2 °F), range, midpoint shown (HSDB).

How should Sulfallate be stored?

PRECAUTIONS FOR "CARCINOGENS": Storage site should be as close as practical to lab in which carcinogens are to be used, so that only small quantities required for ... expt need to be carried. Carcinogens should be kept in only one section of cupboard, an explosion-proof refrigerator or freezer (depending on chemicophysical properties ...) that bears appropriate label. An inventory ... should be kept, showing quantity of carcinogen & date it was acquired ... Facilities for dispensing ... should be contiguous to storage area. /Chemical Carcinogens/ (Hazardous Substances Data Bank (HSDB))

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