Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

Tebufenpyrad

Tebufenpyrad is an off-white solid with a slight aromatic odor.

CAS 119168-77-3 Danger

01 · Identification

What Tebufenpyrad is

Tebufenpyrad is an off-white solid with a slight aromatic odor. It melts at 65 °C.

Under the GHS it carries the signal word Danger.

02 · Identifiers

Tebufenpyrad identifiers and molecular data

Tebufenpyrad CAS number and EC number

CAS number119168-77-3
Index number (CLP Annex VI)616-210-00-6

Other names for Tebufenpyrad

  • tebufenpyrad (ISO)
  • N-(4-tertbutylbenzyl)-4-chloro-3-ethyl-1-methyl-1Hpyrazole-5- carboxamide

03 · GHS classification

Tebufenpyrad hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

Tebufenpyrad pictograms and signal word

Signal wordDanger

Tebufenpyrad hazard class and category

GHS hazard classes Tebufenpyrad falls into
Hazard class Category From code Pictogram
Acute toxicity - oral GHS chapter 3.1 Category 3 H301 GHS06
Acute toxicity - inhalation GHS chapter 3.1 Category 4 H332 GHS07
Skin sensitisation GHS chapter 3.4 Category 1 or 1A or 1B H317 GHS07
Specific target organ toxicity - repeated exposure GHS chapter 3.9 Category 2 H373 GHS08
Hazardous to the aquatic environment - acute GHS chapter 4.1 Category 1 H400 GHS09
Hazardous to the aquatic environment - chronic GHS chapter 4.1 Category 1 H410 GHS09

Where two values are shown with “or”, the hazard statement is shared by more than one category or by more than one class, and the code alone does not say which. H272, for example, belongs to oxidising liquids and to oxidising solids — the physical state decides. The binding answer for a specific entry is in the CLP Annex VI table itself.

Tebufenpyrad hazard statements (H-codes)

Hazard statements assigned to Tebufenpyrad
CodeHazard statement
H301 Toxic if swallowed.
H332 Harmful if inhaled.
H373 May cause damage to organs <or state all organs affected, if known> through prolonged or repeated exposure <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
H317 May cause an allergic skin reaction.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.

This page lists only the codes assigned to Tebufenpyrad. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for Tebufenpyrad

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of Tebufenpyrad issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

04 · Precautionary statements

Tebufenpyrad precautionary statements

CLP Annex VI assigns 17 precautionary statements to Tebufenpyrad. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Disposal

What has to happen to the contents and the empty container.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

Tebufenpyrad name in 23 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български тебуфенпирад (ISO) N -(4- трет -бутилбензил)-3-етил-1-метил-4-хлоро-1 H -пиразол-5-карбоксамид
Spanish español Tebufenpirad (ISO) N -(4- terc -butilbencil)-4-cloro-3-etil-1-metil-1 H -pirazol-5-carboxamida
Czech čeština tebufenpyrad (ISO) N -(4- terc -butylbenzyl)-4-chlor-3-ethyl-1-methyl-1 H -pyrazol-5-karboxamid
Danish dansk tebufenpyrad (ISO) N- (4- tert butylbenzyl)-4-chlor-3-ethyl-1-methyl-1 H -pyrazol-5-carboxamid
German Deutsch Tebufenpyrad (ISO) N -(4-tertbutylbenzyl)-4-chlor-3-ethyl-1-methyl-1 H -pyrazol-5-carboxamid
Estonian eesti tebufenpüraad (ISO) N -(4- tert -butüülbensüül)-4-kloro-3-etüül-1-metüül-1 H -pürasool-5-karboksamiid
Greek ελληνικά tebufenpyrad (τεβουφαινοπυράδη) (ISO) Ν -(4- tert -βουτυλοβενζυλο)-4-χλωρο-3-αιθυλο-1-μεθυλο-1 H - πυραζολο-5-καρβοξαμίδιο
English English tebufenpyrad (ISO) N -(4-tertbutylbenzyl)-4-chloro-3-ethyl-1-methyl-1 H -pyrazole-5-carboxamide
French français tébufenpyrade (ISO) N -(4-tertbutylbenzyl)-4-chloro3-éthyl-1-méthyl-1-pyrazole-5-carboxamide
Croatian hrvatski tebufenpirad (ISO) N -(4- tert -butilbenzil)-4-klor-3-etil-1-metil-1 H -pirazol-5-karboksamid
Italian italiano tebufenpirad (ISO) N-(4- terz -butilbenzil)-4-cloro3-etil-1-metil-1 H -pirazolo-5-carbossammide
Latvian latviešu tebufēnpirāds (ISO) N -(4- terc -butilbenzil)-4-hlor-3-etil-1-metil-1 H -pirazol-5-karboksamīds
Lithuanian lietuvių tebufenpiradas (ISO) N -(4-tretbutylbenzil)-4-chlor-3-etil-1-metil-1 H -pirazol-5-karboksamidas
Hungarian magyar tebufenpirad (ISO) N -(4- terc -butilbenzil)-4-klór-3-etil-1-metil-1 H -pirazol-5-karboxamid
Maltese Malti tebufenpirad (ISO) N -(4-tertbutilbenżil)-4-kloro-3-etil-1-metil-1 H -pirażol-5-karbossammid
Dutch Nederlands tebufenpyrad (ISO) N -(4- tert -butylbenzyl)-4-chloor-3-ethyl-1-methyl-1 H -pyrazool-5-carboxamide
Polish polski tebufenpyrad (ISO) N-(4-tert-butylobenzylo)-4-chloro-3-etylo-1-metylo-1H-pirazolo-5-karboksyamid
Portuguese português tebufenepirade (ISO) N -(4- terc -butilbenzil)-4-cloro-3-etil-1-metil-1 H -pirazolo-5-carboxamida
Romanian română tebufenpirad (ISO) N -(4-terț-butil-benzil)-4-cloro-3-etil-1-metil-1 H -pirazol-5-carboxamidă
Slovak slovenčina tebufenpyrad (ISO) N -(4- terc -butylbenzyl)-4-chlór-3-etyl-1-metyl-1 H -pyrazol-5-karboxamid
Slovenian slovenščina tebufenpirad (ISO) N -(4-tercbutilbenzil)-4-kloro-3-etil-1-metil-1 H -pirazol-5-karboksamid
Finnish suomi tebufenpyradi (ISO) N -(4-tert-butyylibentsyyli)-4-kloori-3-etyyli-1-metyyli-1 H -pyratsoli-5-karboksiamidi
Swedish svenska tebufenpyrad (ISO) N -(4-tertbutylbensyl)-4-klor-3-etyl-1-metyl-1 H -pyrazol-5-karboxamid

All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

Tebufenpyrad GHS label elements

Everything CLP Annex VI fixes for Tebufenpyrad, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS06 Skull and crossbones pictogramGHS08 Health hazard pictogramGHS09 Environment pictogram

Danger

Tebufenpyrad

  • Toxic if swallowed.
  • Harmful if inhaled.
  • May cause damage to organs <or state all organs affected, if known> through prolonged or repeated exposure <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
  • May cause an allergic skin reaction.
  • Very toxic to aquatic life.
  • Very toxic to aquatic life with long lasting effects.
  • Do not breathe dust/fume/gas/mist/vapours/spray.
  • Avoid breathing dust/fume/gas/mist/vapours/spray.
  • Do not eat, drink or smoke when using this product.
  • Use only outdoors or in a well-ventilated area.
  • Contaminated work clothing should not be allowed out of the workplace.
  • Avoid release to the environment.
  • Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/
  • IF SWALLOWED:
  • IF INHALED:
  • Immediately call a POISON CENTER/doctor/
  • Call a POISON CENTER/doctor/ if you feel unwell.
  • Get medical advice/attention.
  • Get medical advice/attention if you feel unwell.
  • Rinse mouth.
  • If skin irritation or rash occurs:
  • Collect spillage.
  • Dispose of contents/container to

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open Tebufenpyrad in the GHS label constructor →

07 · Health hazards

Tebufenpyrad health hazards and exposure limits

Tebufenpyrad hazard summary

May cause irritation; [MSDSonline]

Source: Haz-Map, Information on Hazardous Chemicals and Occupational Diseases

Tebufenpyrad carcinogenicity classification

Cancer Classification: Suggestive Evidence of Carcinogenicity, but Not Sufficient to Assess Human Carcinogenic Potential

Source: Hazardous Substances Data Bank (HSDB)

An IARC group and a CLP classification answer different questions. IARC judges whether the evidence for cancer in humans is strong enough; CLP Annex VI is the legally binding EU classification. A substance can carry one and not the other.

08 · Physical and chemical properties

Tebufenpyrad properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

Tebufenpyrad melting point

Property Value Conditions Source
Melting point 65 °C (149 °F) range, midpoint shown HSDB

Tebufenpyrad density

Property Value Conditions Source
Density 1.0214 g/cm³ HSDB
0.5 g/cm³ at 24.1 °C, Technical product HSDB

Tebufenpyrad solubility

Property Value Conditions Source
Solubility Solubility in water = 2.61 ppm at pH 5.9, 3.21 ppm at pH 4, 2.39 ppm at pH 7, and 2.32 ppm at pH 10 Technical product HSDB
In water, 2.61 mg/L at 25 °C at 25 °C HSDB
Solubility (mg/L at 25 °C): in hexane 255; toluene 772; dichloromethane 1044; acetone 819; methanol 818; acetonitrile 785 at 25 °C HSDB

Tebufenpyrad vapor pressure

Property Value Conditions Source
Vapor pressure 7.3e-8 mmHg below this value, at 20 °C HSDB

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

09 · Handling and storage

Tebufenpyrad storage and handling

Tebufenpyrad storage conditions

Store in cool, dark place.

Source: Hazardous Substances Data Bank (HSDB)

Planning storage for a mix of chemicals? Check Tebufenpyrad in the storage compatibility matrix →

10 · Questions

Tebufenpyrad — frequently asked questions

What is the CAS number of Tebufenpyrad?

The CAS number of Tebufenpyrad is 119168-77-3.

What does a Tebufenpyrad label have to show?

Under CLP Annex VI the label for Tebufenpyrad carries the pictograms Skull and crossbones, Health hazard and Environment and the signal word is Danger.

Is Tebufenpyrad flammable?

CLP Annex VI assigns Tebufenpyrad no flammability hazard class. That is not a statement that it cannot burn: the harmonised list only records the hazards that were assessed for it.

Is Tebufenpyrad a carcinogen?

CLP Annex VI records no harmonised carcinogenicity classification for Tebufenpyrad. Annex VI is a list of agreed classifications, not a list of substances found safe, so this is an absence of a classification rather than a clean bill of health.

What is the melting point of Tebufenpyrad?

The melting point reported for Tebufenpyrad is 65 °C (149 °F), range, midpoint shown (HSDB).

How should Tebufenpyrad be stored?

Store in cool, dark place. (Hazardous Substances Data Bank (HSDB))

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