Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

Tert-butyl cumene peroxide

Tert-butyl cumene peroxide: CBI; Liquid.

CAS 3457-61-2 C13H20O2 208.3 g/mol Warning

01 · Identification

What Tert-butyl cumene peroxide is

Tert-butyl cumene peroxide: CBI; Liquid. Its molecular formula is C13H20O2 and its molecular weight is 208.3 g/mol.

Under the GHS it carries the signal word Warning.

02 · Identifiers

Tert-butyl cumene peroxide identifiers and molecular data

Tert-butyl cumene peroxide CAS number and EC number

CAS number3457-61-2
EC number222-389-8
Index number (CLP Annex VI)617-007-00-5

Tert-butyl cumene peroxide molecular formula and molecular weight

Molecular formulaC13H20O2
Molecular weight208.3 g/mol

Other names for Tert-butyl cumene peroxide

  • tert-butyl α,α-dimethylbenzyl peroxide

03 · GHS classification

Tert-butyl cumene peroxide hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

Tert-butyl cumene peroxide pictograms and signal word

Signal wordWarning

Tert-butyl cumene peroxide hazard class and category

GHS hazard classes Tert-butyl cumene peroxide falls into
Hazard class Category From code Pictogram
Organic peroxides or Self-reactive substances and mixtures Category Type C and D or Type E and F H242 GHS02
Skin corrosion/irritation GHS chapter 3.2 Category 2 H315 GHS07
Hazardous to the aquatic environment - chronic GHS chapter 4.1 Category 2 H411 GHS09

Where two values are shown with “or”, the hazard statement is shared by more than one category or by more than one class, and the code alone does not say which. H272, for example, belongs to oxidising liquids and to oxidising solids — the physical state decides. The binding answer for a specific entry is in the CLP Annex VI table itself.

Tert-butyl cumene peroxide hazard statements (H-codes)

Hazard statements assigned to Tert-butyl cumene peroxide
CodeHazard statement
H242 Heating may cause a fire.
H315 Causes skin irritation.
H411 Toxic to aquatic life with long lasting effects.

This page lists only the codes assigned to Tert-butyl cumene peroxide. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for Tert-butyl cumene peroxide

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of Tert-butyl cumene… issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

04 · Precautionary statements

Tert-butyl cumene peroxide precautionary statements

CLP Annex VI assigns 9 precautionary statements to Tert-butyl cumene peroxide. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Disposal

What has to happen to the contents and the empty container.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

Tert-butyl cumene peroxide name in 23 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български трет -бутил-α, α-диметилбензилпероксид
Spanish español Peróxido de terc -butilo y α, α-dimetilbencilo
Czech čeština terc -butyl(2-fenylpropan-2-yl)peroxid
Danish dansk tert -butyl-α, α-dimethylbenzylperoxid
German Deutsch tert -Butyl-α, α-dimethylbenzylperoxid
Estonian eesti tert -butüül-α, α-dimetüülbensüülperoksiid
Greek ελληνικά tert -βουτυλο-α, α-διμεθυλοβενζυλοϋπεροξείδιο
English English tert -butyl α, α-dimethylbenzyl peroxide
French français peroxyde de tert -butyl α, α-diméthylbenzyle
Croatian hrvatski tert -butil α , α -dimetilbenzil peroksid
Italian italiano perossido di terz -butile e α, α-dimetilbenzile
Latvian latviešu terc -butil-α, α-dimetilbenzilperoksīds
Lithuanian lietuvių tret -butil-α, α-dimetilbenzilperoksidas
Hungarian magyar terc -butil-α, α-dimetilbenzil-peroxid
Maltese Malti perossidu ta' terz -butil α, α-dimetilbenżil
Dutch Nederlands tert -butyl-α, α-dimethylbenzylperoxide
Polish polski nadtlenek tert -butylo-α, α-dimetylobenzylu
Portuguese português peróxido de terc -butilo e de α, α-dimetilbenzilo
Romanian română peroxid de terț -butil și de α, α-dimetilbenzil
Slovak slovenčina 2-( terc -butylperoxy)-2-fenylpropán
Slovenian slovenščina terc -butil α, α-dimetilbenzil peroksid
Finnish suomi tert -butyyli-α, α-dimetyylibentsyyli-peroksidi
Swedish svenska tert -butyl-α, α-dimetylbensylperoxid

All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

Tert-butyl cumene peroxide GHS label elements

Everything CLP Annex VI fixes for Tert-butyl cumene peroxide, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS02 Flame pictogramGHS07 Exclamation mark pictogramGHS09 Environment pictogram

Warning

Tert-butyl cumene peroxide

  • Heating may cause a fire.
  • Causes skin irritation.
  • Toxic to aquatic life with long lasting effects.
  • Wash thoroughly after handling.
  • Avoid release to the environment.
  • Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/
  • IF ON SKIN:
  • Get medical advice/attention.
  • If skin irritation occurs:
  • Wash with plenty of water/
  • Collect spillage.
  • Dispose of contents/container to

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open Tert-butyl cumene peroxide in the GHS label constructor →

07 · Questions

Tert-butyl cumene peroxide — frequently asked questions

What is the CAS number of Tert-butyl cumene peroxide?

The CAS number of Tert-butyl cumene peroxide is 3457-61-2. Its EC number is 222-389-8.

What is the chemical formula of Tert-butyl cumene peroxide?

The molecular formula of Tert-butyl cumene peroxide is C13H20O2 and its molecular weight is 208.3 g/mol.

What does a Tert-butyl cumene peroxide label have to show?

Under CLP Annex VI the label for Tert-butyl cumene peroxide carries the pictograms Flame, Exclamation mark and Environment and the signal word is Warning.

Is Tert-butyl cumene peroxide flammable?

Yes. CLP Annex VI assigns Tert-butyl cumene peroxide H242 — heating may cause a fire.

Is Tert-butyl cumene peroxide a carcinogen?

CLP Annex VI records no harmonised carcinogenicity classification for Tert-butyl cumene peroxide. Annex VI is a list of agreed classifications, not a list of substances found safe, so this is an absence of a classification rather than a clean bill of health.

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