Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

Triazophos

Triazophos is a yellowish-brown oil.

CAS 24017-47-8 C12H16N3O3PS 313.31 g/mol Danger

01 · Identification

What Triazophos is

Triazophos is a yellowish-brown oil. Its molecular formula is C12H16N3O3PS and its molecular weight is 313.31 g/mol. It boils at 350 °C, melts at 5 °C, is soluble in water.

Under the GHS it carries the signal word Danger.

02 · Identifiers

Triazophos identifiers and molecular data

Triazophos CAS number and EC number

CAS number24017-47-8
EC number245-986-5
Index number (CLP Annex VI)015-140-00-8

Triazophos molecular formula and molecular weight

Molecular formulaC12H16N3O3PS
Molecular weight313.31 g/mol

Other names for Triazophos

  • triazophos (ISO)
  • O,O-diethyl-O-1-phenyl-1H-1,2,4-triazol-3-yl phosphorothioate

03 · GHS classification

Triazophos hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

Triazophos pictograms and signal word

Signal wordDanger

Triazophos hazard class and category

GHS hazard classes Triazophos falls into
Hazard class Category From code Pictogram
Acute toxicity - oral GHS chapter 3.1 Category 3 H301 GHS06
Acute toxicity - dermal GHS chapter 3.1 Category 4 H312 GHS07
Acute toxicity - inhalation GHS chapter 3.1 Category 3 H331 GHS06
Hazardous to the aquatic environment - acute GHS chapter 4.1 Category 1 H400 GHS09
Hazardous to the aquatic environment - chronic GHS chapter 4.1 Category 1 H410 GHS09

Triazophos hazard statements (H-codes)

Hazard statements assigned to Triazophos
CodeHazard statement
H331 Toxic if inhaled.
H301 Toxic if swallowed.
H312 Harmful in contact with skin.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.

This page lists only the codes assigned to Triazophos. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for Triazophos

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of Triazophos issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

04 · Precautionary statements

Triazophos precautionary statements

CLP Annex VI assigns 14 precautionary statements to Triazophos. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Disposal

What has to happen to the contents and the empty container.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

Triazophos name in 23 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български триазофос (ISO) O, O -диетил- O -1-фенил-1 H -1,2,4-триазол-3-илов фосфоротиоат
Spanish español Triazofós (ISO) fosforotioato de O, O -dietilo y O -1-fenil-1 H -1,2,4-triazol-3-ilo
Czech čeština triazofos (ISO) O, O -diethyl- O -(1-fenyl-1 H -1,2,4-triazol-3-yl)-fosforothioát
Danish dansk triazophos (ISO) O, O- diethyl- O- 1-phenyl-1 H- 1,2,4-triazol-3-ylthiophosphat
German Deutsch Triazophos (ISO) O, O -Diethyl- O -(1-phenyl-1 H -1,2,4-triazol-3-yl)phosphorothioat
Estonian eesti triasofoss (ISO) O , O -dietüül- O -1-fenüül-1 H -1,2,4-triasool-3-üülfosforotioaat
Greek ελληνικά triazophos (τριαζωφός) (ISO) θειοφωσφορικό O, O -διαιθυλο- O -1-φαινυλο-1 H -1,2,4-τριαζολ-3-ύλιο
English English triazophos (ISO) O, O -diethyl- O -1-phenyl-1 H -1,2,4-triazol-3-yl phosphorothioate
French français triazophos (ISO) phosphorothioate de O, O -diéthyl- O -1-phényl-1 H -1,2,4-triazol-3-yle
Croatian hrvatski triazofos (ISO) O, O -dietil- O -1-fenil-1 H -1,2,4-triazol-3-il-fosforotioat
Italian italiano triazofos (ISO) ditiofosfato di O , O -dietile e O -1-fenil-1H-1,2,4-triazol-3-ile
Latvian latviešu triazofoss (ISO) O, O -dietil- O -1-fenil-1 H -1,2,4-triazol-3-ilfosfortioāts
Lithuanian lietuvių triazofosas (ISO) O, O -dietil- O -1-fenil-1 H -1,2,4-triazol-3-iltiofosfatas
Hungarian magyar triazofosz (ISO) O, O -dietil- O -1-fenil-1 H -1,2,4-triazol-3-il-tiofoszfát
Maltese Malti triażofos (ISO) fosforotijoat ta’ O, O-dietil-O-1-fenil-1H-1,2,4-triażol-3-il
Dutch Nederlands triazofos (ISO) O , O -diëthyl- O -1-fenyl-1 H -1,2,4-triazool-3-ylthiofosfaat
Polish polski triazofos (ISO) tiofosforan O, O-dietylu-O-1-fenylo-1H-1,2,4-triazol-3-ilu
Portuguese português triazofos (ISO) tiofostato de O , O -dietilo e de O -1-fenil-1 H -1,2,4-triazol-3-ilo
Romanian română triazofos (ISO) tiofosfat de O, O -dietil și de O -1-fenil-1 H -1,2,4- triazol-3-il
Slovak slovenčina triazofos (ISO) O, O -dietyl- O -(1-fenyl-1 H -1,2,4-triazol-3-yl)-fosforotioát
Slovenian slovenščina triazofos (ISO) O, O -dietil- O -1-fenil-1 H -1,2,4-triazol-3-il fosforotioat
Finnish suomi triatsofossi (ISO) O , O -dietyyli- O -1-fenyyli-1 H -1,2,4-triatsol-3-yylifosforotioaatti
Swedish svenska triazofos (ISO) O, O -dietyl- O -1-fenyl-1 H -1,2,4-triazol-3-ylfosfortioat

All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

Triazophos GHS label elements

Everything CLP Annex VI fixes for Triazophos, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS06 Skull and crossbones pictogramGHS09 Environment pictogram

Danger

Triazophos

  • Toxic if inhaled.
  • Toxic if swallowed.
  • Harmful in contact with skin.
  • Very toxic to aquatic life.
  • Very toxic to aquatic life with long lasting effects.
  • Do not breathe dust/fume/gas/mist/vapours/spray.
  • Do not eat, drink or smoke when using this product.
  • Use only outdoors or in a well-ventilated area.
  • Avoid release to the environment.
  • Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/
  • IF SWALLOWED:
  • IF ON SKIN:
  • IF INHALED:
  • Immediately call a POISON CENTER/doctor/
  • Call a POISON CENTER/doctor/ if you feel unwell.
  • Rinse mouth.
  • Wash with plenty of water/
  • Collect spillage.
  • Dispose of contents/container to

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open Triazophos in the GHS label constructor →

07 · Health hazards

Triazophos health hazards and exposure limits

Triazophos hazard summary

A cholinesterase inhibitor; Can be absorbed through skin; [CAMEO] The average of two baseline respective cholinesterase activity determinations three days apart, with no exposures to enzyme inhibiting pesticides for at least 30 days, is recommended for each worker prior to exposure to cholinesterase inhibitors because of large inter-individual differences in published baseline values. To be established at least once a year. Removal from workplace exposures is recommended until the cholinesterase activity returns to within 20% of baseline. [TLVs and BEIs]

Source: Haz-Map, Information on Hazardous Chemicals and Occupational Diseases

08 · Physical and chemical properties

Triazophos properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

Triazophos boiling point

Property Value Conditions Source
Boiling point 350 °C (662 °F) at 760 mmHg DOE PAC
Decomposes on distillation decomposes HSDB
Decomposes before boiling (EPA, 1998) decomposes CAMEO

Triazophos melting point

Property Value Conditions Source
Melting point 5 °C (41 °F) HSDB
2.5 °C (36.5 °F) range, midpoint shown CAMEO

Triazophos density

Property Value Conditions Source
Density 1.2514 g/cm³ at 20 °C HSDB
1.247 g/cm³ at 20 °C CAMEO
1.25 g/cm³ at 20 °C DOE PAC

Triazophos solubility

Property Value Conditions Source
Solubility Soluble in organic solvents HSDB
In water, 39 mg/L at 20 °C at 20 °C HSDB
In water, 24.7 mg/L at 20 °C at 20 °C HSDB

Triazophos vapor pressure

Property Value Conditions Source
Vapor pressure 0.00001 mmHg CAMEO
0.00001 mmHg at 25 °C DOE PAC
0.0000029 mmHg at 30 °C HSDB

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

09 · Handling and storage

Triazophos storage and handling

Triazophos reactivity

Organophosphates, such as TRIAZOFOS, are susceptible to formation of highly toxic and flammable phosphine gas in the presence of strong reducing agents such as hydrides. Partial oxidation by oxidizing agents may result in the release of toxic phosphorus oxides.

Source: CAMEO Chemicals

Planning storage for a mix of chemicals? Check Triazophos in the storage compatibility matrix →

10 · Questions

Triazophos — frequently asked questions

What is the CAS number of Triazophos?

The CAS number of Triazophos is 24017-47-8. Its EC number is 245-986-5.

What is the chemical formula of Triazophos?

The molecular formula of Triazophos is C12H16N3O3PS and its molecular weight is 313.31 g/mol.

What does a Triazophos label have to show?

Under CLP Annex VI the label for Triazophos carries the pictograms Skull and crossbones and Environment and the signal word is Danger.

Is Triazophos flammable?

CLP Annex VI assigns Triazophos no flammability hazard class. That is not a statement that it cannot burn: the harmonised list only records the hazards that were assessed for it.

Is Triazophos a carcinogen?

CLP Annex VI records no harmonised carcinogenicity classification for Triazophos. Annex VI is a list of agreed classifications, not a list of substances found safe, so this is an absence of a classification rather than a clean bill of health.

What is the boiling point of Triazophos?

The boiling point reported for Triazophos is 350 °C (662 °F), at 760 mmHg (DOE PAC).

What is the melting point of Triazophos?

The melting point reported for Triazophos is 5 °C (41 °F) (HSDB).

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