Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

Trichlorfon

Trichlorfon is white crystals with an ethyl ether-like odor.

CAS 52-68-6 C4H8Cl3O4P 257.43 g/mol Warning

01 · Identification

What Trichlorfon is

Trichlorfon is white crystals with an ethyl ether-like odor. Its molecular formula is C4H8Cl3O4P and its molecular weight is 257.43 g/mol. It melts at 82.2 °C.

Under the GHS it carries the signal word Warning. It is classed as mutagens.

02 · Identifiers

Trichlorfon identifiers and molecular data

Trichlorfon CAS number and EC number

CAS number52-68-6
EC number200-149-3
Index number (CLP Annex VI)015-021-00-0

Trichlorfon molecular formula and molecular weight

Molecular formulaC4H8Cl3O4P
Molecular weight257.43 g/mol
Chemical class Mutagens

Other names for Trichlorfon

  • trichlorfon (ISO)
  • dimethyl 2,2,2-trichloro-1-hydroxyethylphosphonate

03 · GHS classification

Trichlorfon hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

Trichlorfon pictograms and signal word

Signal wordWarning

Trichlorfon hazard class and category

GHS hazard classes Trichlorfon falls into
Hazard class Category From code Pictogram
Acute toxicity - oral GHS chapter 3.1 Category 4 H302 GHS07
Skin sensitisation GHS chapter 3.4 Category 1 or 1A or 1B H317 GHS07
Hazardous to the aquatic environment - acute GHS chapter 4.1 Category 1 H400 GHS09
Hazardous to the aquatic environment - chronic GHS chapter 4.1 Category 1 H410 GHS09

Where two values are shown with “or”, the hazard statement is shared by more than one category or by more than one class, and the code alone does not say which. H272, for example, belongs to oxidising liquids and to oxidising solids — the physical state decides. The binding answer for a specific entry is in the CLP Annex VI table itself.

Trichlorfon hazard statements (H-codes)

Hazard statements assigned to Trichlorfon
CodeHazard statement
H302 Harmful if swallowed.
H317 May cause an allergic skin reaction.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.

This page lists only the codes assigned to Trichlorfon. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for Trichlorfon

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of Trichlorfon issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

04 · Precautionary statements

Trichlorfon precautionary statements

CLP Annex VI assigns 12 precautionary statements to Trichlorfon. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Disposal

What has to happen to the contents and the empty container.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

Trichlorfon name in 23 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български трихлорфон (ISO) диметилов 1-хидрокси-2,2,2-трихлороетилфосфонат
Spanish español Triclorfón (ISO) 2,2,2-tricloro-1-hidroxietilfosfonato de dimetilo
Czech čeština trichlorfon (ISO) dimethyl-(2,2,2-trichlor-1-hydroxyethyl)fosfonát
Danish dansk trichlorfon (ISO) dimethyl-2,2,2-trichlor-1-hydroxyethylphosphonat
German Deutsch Trichlorfon (ISO) Dimethyl-2,2,2-trichlor-1-hydroxyethylphosphonat
Estonian eesti triklorofoon (ISO) dimetüül-2,2,2-trikloro-1-hüdroksüetüülfosfonaat
Greek ελληνικά trichlorfon (τριχλωρφόν) (ISO) 2,2,2-τριχλωρο-1-υδροξυαιθυλοφωσφονικός διμεθυλεστέρας
English English trichlorfon (ISO) dimethyl 2,2,2-trichloro-1-hydroxyethylphosphonate
French français trichlorfon (ISO) 2,2,2-trichloro-1-hydroxyéthylphosphonate de diméthyle
Croatian hrvatski triklorfon (ISO) dimetil-2,2,2-triklor-1-hidroksietil-fosfonat
Italian italiano triclorfon (ISO) 2,2,2-tricloro-1-idrossietilfosfonato di dimetile
Latvian latviešu trihlorfons (ISO) dimetil-2,2,2-trihlor-1-hidroksietilfosfonāts
Lithuanian lietuvių trichlorfonas (ISO) dimetil-2,2,2-trichlor-1-hidroksietilfosfonatas
Hungarian magyar triklórfon (ISO) dimetil-2,2,2-triklór-1-hidroxietilfoszfonát
Maltese Malti triklorfon (ISO) 2,2,2-trikloro-1-idrossietilfosfonat tad-dimetil
Dutch Nederlands trichloorfon (ISO) dimethyl-2,2,2-trichloor-1-hydroxyethylfosfonaat
Polish polski trichlorfon (ISO) 2,2,2-trichloro-1-hydroksyetylofosfonian dimetylu
Portuguese português triclorfão (ISO) 2,2,2-tricloro-1-hidroxietilfosfonato de dimetilo
Romanian română triclorfon (ISO) 2,2,2-tricloro-1-hidroxietilfosfonat de dimetil
Slovak slovenčina trichlorfón (ISO) dimetyl-1-hydroxy-2,2,2-trichlóretylfosfonát
Slovenian slovenščina triklorfon (ISO) dimetil 2,2,2-trikloro-1-hidroksietilfosfonat
Finnish suomi trikloorifoni (ISO) dimetyyli-2,2,2-trikloori-1-hydroksietyylifosfonaatti
Swedish svenska triklorfon (ISO) dimetyl-2,2,2-triklor-1-hydroxietylfosfonat

All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

Trichlorfon GHS label elements

Everything CLP Annex VI fixes for Trichlorfon, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS07 Exclamation mark pictogramGHS09 Environment pictogram

Warning

Trichlorfon

  • Harmful if swallowed.
  • May cause an allergic skin reaction.
  • Very toxic to aquatic life.
  • Very toxic to aquatic life with long lasting effects.
  • Avoid breathing dust/fume/gas/mist/vapours/spray.
  • Do not eat, drink or smoke when using this product.
  • Contaminated work clothing should not be allowed out of the workplace.
  • Avoid release to the environment.
  • Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/
  • IF SWALLOWED:
  • Call a POISON CENTER/doctor/ if you feel unwell.
  • Get medical advice/attention.
  • Rinse mouth.
  • If skin irritation or rash occurs:
  • Collect spillage.
  • Dispose of contents/container to

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open Trichlorfon in the GHS label constructor →

07 · Health hazards

Trichlorfon health hazards and exposure limits

Trichlorfon carcinogenicity classification

IARC classification Group 3 — Not classifiable as to its carcinogenicity to humans
IARC monographs Volume 30: (1983) Miscellaneous Pesticides

Cancer Classification: Likely to be Carcinogenic to Humans (High Doses); Not Likely to be Carcinogenic to Humans (Low Doses)

Source: Hazardous Substances Data Bank (HSDB)

No data are available in humans. Inadequate evidence of carcinogenicity in animals. OVERALL EVALUATION: Group 3: The agent is not classifiable as to its carcinogenicity to humans.

Source: Hazardous Substances Data Bank (HSDB)

An IARC group and a CLP classification answer different questions. IARC judges whether the evidence for cancer in humans is strong enough; CLP Annex VI is the legally binding EU classification. A substance can carry one and not the other.

08 · Physical and chemical properties

Trichlorfon properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

Trichlorfon boiling point

Property Value Conditions Source
Boiling point 100 °C (212 °F) at 0.1 mmHg (reduced pressure) HSDB

Trichlorfon melting point

Property Value Conditions Source
Melting point 82.2 °C (180 °F) HSDB
83.33 °C (182 °F) range, midpoint shown CAMEO
83.5 °C (182.3 °F) range, midpoint shown ICSC

Trichlorfon density

Property Value Conditions Source
Density 1.73 g/cm³ ICSC
1.73 g/cm³ at 20 °C HSDB

Trichlorfon solubility

Property Value Conditions Source
Solubility Soluble in benzene, ethanol; sparsely soluble in diethyl ether and petroleum ether HSDB
Solubility: 152 g/kg in benzene; 299 g/kg in dichloromethane; 200 g/kg in isopropanol; 30 g/kg in toluene HSDB
In water, 1.20X10+5 mg/L at 25 °C at 25 °C HSDB

Trichlorfon vapor pressure

Property Value Conditions Source
Vapor pressure 0.0000078 mmHg at 20 °C HSDB
0.0000078 mmHg Haz-Map

Trichlorfon corrosivity

Property Value Conditions Source
Corrosivity Corrosive to metals HSDB

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

09 · Fire and explosion

Trichlorfon fire and explosion behaviour

These are descriptions rather than measured values, so they are kept out of the table above and quoted here with the source that reported them.

Trichlorfon fire potential

This material may burn, but does not ignite readily.

Source: Hazardous Substances Data Bank (HSDB)

10 · Handling and storage

Trichlorfon storage and handling

Trichlorfon safe storage

Separated from strong bases and food and feedstuffs. Keep in a well-ventilated room.

Source: ILO-WHO International Chemical Safety Cards (ICSCs)

Trichlorfon storage conditions

Keep container tightly closed in a dry and well-ventilated place. Storage class (TRGS 510): Non Combustible Solids.

Source: Hazardous Substances Data Bank (HSDB)

Trichlorfon incompatible materials

Incompatible materials: Strong oxidizing agents.

Source: Hazardous Substances Data Bank (HSDB)

Trichlorfon reactivity

TRICHLORFON is incompatible with alkalis. It is corrosive to black iron and mild steel. It is corrosive to metals. It is subject to hydrolysis. (NTP, 1992)

Source: CAMEO Chemicals

Planning storage for a mix of chemicals? Check Trichlorfon in the storage compatibility matrix →

11 · Questions

Trichlorfon — frequently asked questions

What is the CAS number of Trichlorfon?

The CAS number of Trichlorfon is 52-68-6. Its EC number is 200-149-3.

What is the chemical formula of Trichlorfon?

The molecular formula of Trichlorfon is C4H8Cl3O4P and its molecular weight is 257.43 g/mol.

What does a Trichlorfon label have to show?

Under CLP Annex VI the label for Trichlorfon carries the pictograms Exclamation mark and Environment and the signal word is Warning.

Is Trichlorfon flammable?

CLP Annex VI assigns Trichlorfon no flammability hazard class. That is not a statement that it cannot burn: the harmonised list only records the hazards that were assessed for it.

Is Trichlorfon a carcinogen?

CLP Annex VI records no harmonised carcinogenicity classification for Trichlorfon. Annex VI is a list of agreed classifications, not a list of substances found safe, so this is an absence of a classification rather than a clean bill of health. IARC places it in Group 3: not classifiable as to its carcinogenicity to humans.

What is the boiling point of Trichlorfon?

The boiling point reported for Trichlorfon is 100 °C (212 °F), at 0.1 mmHg (reduced pressure) (HSDB).

What is the melting point of Trichlorfon?

The melting point reported for Trichlorfon is 82.2 °C (180 °F) (HSDB).

How should Trichlorfon be stored?

Keep container tightly closed in a dry and well-ventilated place. Storage class (TRGS 510): Non Combustible Solids. (Hazardous Substances Data Bank (HSDB))

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