Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

Zinc Diethyldithiocarbamate

Zinc Diethyldithiocarbamate is a white powder.

CAS 14324-55-1 C10H20N2S4Zn 361.9 g/mol Warning

01 · Identification

What Zinc Diethyldithiocarbamate is

Zinc Diethyldithiocarbamate is a white powder. Its molecular formula is C10H20N2S4Zn and its molecular weight is 361.9 g/mol. It melts at 174 °C.

Under the GHS it carries the signal word Warning.

02 · Identifiers

Zinc Diethyldithiocarbamate identifiers and molecular data

Zinc Diethyldithiocarbamate CAS number and EC number

CAS number14324-55-1
EC number238-270-9
Index number (CLP Annex VI)006-082-00-4

Zinc Diethyldithiocarbamate molecular formula and molecular weight

Molecular formulaC10H20N2S4Zn
Molecular weight361.9 g/mol

Other names for Zinc Diethyldithiocarbamate

  • zinc bis(diethyldithiocarbamate)

03 · GHS classification

Zinc Diethyldithiocarbamate hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

Zinc Diethyldithiocarbamate pictograms and signal word

Signal wordWarning

Zinc Diethyldithiocarbamate hazard class and category

GHS hazard classes Zinc Diethyldithiocarbamat… falls into
Hazard class Category From code Pictogram
Acute toxicity - oral GHS chapter 3.1 Category 4 H302 GHS07
Skin corrosion/irritation GHS chapter 3.2 Category 2 H315 GHS07
Serious eye damage/eye irritation GHS chapter 3.3 Category 2A H319 GHS07
Skin sensitisation GHS chapter 3.4 Category 1 or 1A or 1B H317 GHS07
Specific target organ toxicity - single exposure GHS chapter 3.8 Category 3 H335 GHS07
Hazardous to the aquatic environment - acute GHS chapter 4.1 Category 1 H400 GHS09
Hazardous to the aquatic environment - chronic GHS chapter 4.1 Category 1 H410 GHS09

Where two values are shown with “or”, the hazard statement is shared by more than one category or by more than one class, and the code alone does not say which. H272, for example, belongs to oxidising liquids and to oxidising solids — the physical state decides. The binding answer for a specific entry is in the CLP Annex VI table itself.

Zinc Diethyldithiocarbamate hazard statements (H-codes)

Hazard statements assigned to Zinc Diethyldithiocarbamat…
CodeHazard statement
H302 Harmful if swallowed.
H335 May cause respiratory irritation.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H317 May cause an allergic skin reaction.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.

This page lists only the codes assigned to Zinc Diethyldithiocarbamat…. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for Zinc Diethyldithiocarbamat…

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of Zinc Diethyldithiocarb… issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

04 · Precautionary statements

Zinc Diethyldithiocarbamate precautionary statements

CLP Annex VI assigns 19 precautionary statements to Zinc Diethyldithiocarbamat…. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Disposal

What has to happen to the contents and the empty container.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

Zinc Diethyldithiocarbamate name in 23 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български цинков бис(диетилдитиокарбамат)
Spanish español Bis(dietilditiocarbamato) de cinc
Czech čeština bis( N, N -diethyldithiokarbamát) zinečnatý
Danish dansk zinkbis(diethyldithiocarbamat)
German Deutsch Zinkbis(diethyldithiocarbamat)
Estonian eesti tsinkbis(dietüülditiokarbamaat)
Greek ελληνικά δις(διαιθυλοδιθειoκαρβαμιδικός) ψευδάργυρος
English English zinc bis(diethyldithiocarbamate)
French français bis(diéthyldithiocarbamate) de zinc
Croatian hrvatski cinkov bis(dietil-ditiokarbamat)
Italian italiano bis(dietilditiocarbammato) di zinco
Latvian latviešu cinka bis(dietilditiokarbamāts)
Lithuanian lietuvių bis(dietilditiokarbamato) cinkas
Hungarian magyar cink-bisz(dietilditiokarbamát)
Maltese Malti This edition prints another entry’s name here. The Maltese edition prints the dibutyl name of the preceding entry (006-081-00-9). The EC and CAS numbers in the same row, 238-270-9 and 14324-55-1, are the diethyl compound and are correct. Regulation (EU) 2018/669, OJ L 115, 4.5.2018, p. 21 bis(dibutilditijokarbamat) taż-żingu
Dutch Nederlands zinkbis(diëthyldithiocarbamaat)
Polish polski bis(dietyloditiokarbaminian) cynku bis(dietyloditiokarbamian) cynku
Portuguese português bis(dietilditiocarbamato) de zinco
Romanian română bis(dietilditiocarbamat) de zinc
Slovak slovenčina zinkium-bis(dietylditiokarbamát)
Slovenian slovenščina cinkov bis(dietilditiokarbamat)
Finnish suomi sinkkibis(dietyyliditiokarbamaatti)
Swedish svenska zinkbis(dietylditiokarbamat)

One or more lines above are flagged. In those language editions the Regulation as published in the Official Journal prints something that the rest of the same row contradicts — a name belonging to a different entry, or the qualifier of a paired entry. Each flag cites the amending act and the Official Journal page, so the wording can be checked at source. The lines are reproduced as printed, because Art. 18(2) points at Annex VI and not at our reading of it; the note beside each one says what the row’s own EC and CAS numbers identify.

All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

Zinc Diethyldithiocarbamate GHS label elements

Everything CLP Annex VI fixes for Zinc Diethyldithiocarbamat…, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS07 Exclamation mark pictogramGHS09 Environment pictogram

Warning

Zinc Diethyldithiocarbamate

  • Harmful if swallowed.
  • May cause respiratory irritation.
  • Causes skin irritation.
  • Causes serious eye irritation.
  • May cause an allergic skin reaction.
  • Very toxic to aquatic life.
  • Very toxic to aquatic life with long lasting effects.
  • Avoid breathing dust/fume/gas/mist/vapours/spray.
  • Wash thoroughly after handling.
  • Do not eat, drink or smoke when using this product.
  • Contaminated work clothing should not be allowed out of the workplace.
  • Avoid release to the environment.
  • Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/
  • IF SWALLOWED:
  • IF ON SKIN:
  • IF IN EYES:
  • Call a POISON CENTER/doctor/ if you feel unwell.
  • Get medical advice/attention.
  • Rinse mouth.
  • If skin irritation occurs:
  • If skin irritation or rash occurs:
  • If eye irritation persists:
  • Remove contact lenses, if present and easy to do. Continue rinsing.
  • Wash with plenty of water/
  • Collect spillage.
  • Dispose of contents/container to

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open Zinc Diethyldithiocarbamat… in the GHS label constructor →

07 · Health hazards

Zinc Diethyldithiocarbamate health hazards and exposure limits

Zinc Diethyldithiocarbamate hazard summary

A strong eye and mucous membrane irritant; [Hawley] A skin and eye irritant; May cause skin sensitization; [eChemPortal: ERMA] A skin, eye, and respiratory tract irritant; May cause skin sensitization; [eChemPortal: ESIS] An irritant; May cause skin sensitization; [MSDSonline] Several of the dialkyldithiocarbamates are known skin sensitizers; See Carba mix.

Source: Haz-Map, Information on Hazardous Chemicals and Occupational Diseases

08 · Physical and chemical properties

Zinc Diethyldithiocarbamate properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

Zinc Diethyldithiocarbamate melting point

Property Value Conditions Source
Melting point 174 °C (345.2 °F) range, midpoint shown HSDB

Zinc Diethyldithiocarbamate density

Property Value Conditions Source
Density 1.47 g/cm³ at 20 °C HSDB

Zinc Diethyldithiocarbamate solubility

Property Value Conditions Source
Solubility Sol in carbon disulfide, benzene, chloroform; insol in water HSDB

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

09 · Questions

Zinc Diethyldithiocarbamate — frequently asked questions

What is the CAS number of Zinc Diethyldithiocarbamate?

The CAS number of Zinc Diethyldithiocarbamate is 14324-55-1. Its EC number is 238-270-9.

What is the chemical formula of Zinc Diethyldithiocarbamate?

The molecular formula of Zinc Diethyldithiocarbamate is C10H20N2S4Zn and its molecular weight is 361.9 g/mol.

What does a Zinc Diethyldithiocarbamate label have to show?

Under CLP Annex VI the label for Zinc Diethyldithiocarbamate carries the pictograms Exclamation mark and Environment and the signal word is Warning.

Is Zinc Diethyldithiocarbamate flammable?

CLP Annex VI assigns Zinc Diethyldithiocarbamate no flammability hazard class. That is not a statement that it cannot burn: the harmonised list only records the hazards that were assessed for it.

Is Zinc Diethyldithiocarbamate a carcinogen?

CLP Annex VI records no harmonised carcinogenicity classification for Zinc Diethyldithiocarbamate. Annex VI is a list of agreed classifications, not a list of substances found safe, so this is an absence of a classification rather than a clean bill of health.

What is the melting point of Zinc Diethyldithiocarbamate?

The melting point reported for Zinc Diethyldithiocarbamate is 174 °C (345.2 °F), range, midpoint shown (HSDB).

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