Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

Benz[e]acephenanthrylene

Benz[e]acephenanthrylene is needles from benzene.

CAS 205-99-2 C20H12 252.3 g/mol Danger

01 · Identification

What Benz[e]acephenanthrylene is

Benz[e]acephenanthrylene is needles from benzene. Its molecular formula is C20H12 and its molecular weight is 252.3 g/mol. It boils at 481 °C, melts at 168 °C.

Under the GHS it carries the signal word Danger. It is classed as carcinogens.

02 · Identifiers

Benz[e]acephenanthrylene identifiers and molecular data

Benz[e]acephenanthrylene CAS number and EC number

CAS number205-99-2
EC number205-911-9
Index number (CLP Annex VI)601-034-00-4

Benz[e]acephenanthrylene molecular formula and molecular weight

Molecular formulaC20H12
Molecular weight252.3 g/mol
Chemical class Carcinogens

03 · GHS classification

Benz[e]acephenanthrylene hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

Benz[e]acephenanthrylene pictograms and signal word

Signal wordDanger

Benz[e]acephenanthrylene hazard class and category

GHS hazard classes Benz[e]acephenanthrylene falls into
Hazard class Category From code Pictogram
Carcinogenicity GHS chapter 3.6 Category 1A or 1B H350 GHS08
Hazardous to the aquatic environment - acute GHS chapter 4.1 Category 1 H400 GHS09
Hazardous to the aquatic environment - chronic GHS chapter 4.1 Category 1 H410 GHS09

Where two values are shown with “or”, the hazard statement is shared by more than one category or by more than one class, and the code alone does not say which. H272, for example, belongs to oxidising liquids and to oxidising solids — the physical state decides. The binding answer for a specific entry is in the CLP Annex VI table itself.

Benz[e]acephenanthrylene hazard statements (H-codes)

Hazard statements assigned to Benz[e]acephenanthrylene
CodeHazard statement
H350 May cause cancer <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.

This page lists only the codes assigned to Benz[e]acephenanthrylene. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for Benz[e]acephenanthrylene

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of Benz[e]acephenanthryle… issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

04 · Precautionary statements

Benz[e]acephenanthrylene precautionary statements

CLP Annex VI assigns 7 precautionary statements to Benz[e]acephenanthrylene. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Response

What to do once exposure, spillage or fire has already happened.

Disposal

What has to happen to the contents and the empty container.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

Benz[e]acephenanthrylene name in 23 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български бенз[ e ]ацефенантрилен
Spanish español Benz[ e ]acefenantrileno
Czech čeština benzo[ e ]acefenanthrylen
Danish dansk benzo[ e ]acephenanthryleno
German Deutsch Benzo[ e ]acephenanthrylen Benzo[b]fluoranthen
Estonian eesti bens[ e ]atsefenantrüleen
Greek ελληνικά βενζο[ e ]ακεφαινανθρυλένιο
English English benz[ e ]acephenanthrylene
French français benz[ e ]acéphénanthrylène
Croatian hrvatski benz[ e ]acefenantrilen
Italian italiano benzo[e]acefenantrilene
Latvian latviešu benz[ e ]acefenantrilēns
Lithuanian lietuvių benz[ e ]acefenantrilenas
Hungarian magyar benz[ e ]acefenantrilén
Maltese Malti benż[ e ]aċefenantrilen
Dutch Nederlands benzo[ e ]acefenantryleen
Polish polski benzo[b]fluoranten benzo[e]acefenantrylen
Portuguese português benz[ e ]acefenantrileno
Romanian română benzo[ e ]acefenantrilen
Slovak slovenčina benzo[ e ]acefenantrylén
Slovenian slovenščina benz[ e ]acefenantrilen
Finnish suomi bentso[ e ]asefenantryleeni
Swedish svenska bens[ e ]acefenantrylen

All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

Benz[e]acephenanthrylene GHS label elements

Everything CLP Annex VI fixes for Benz[e]acephenanthrylene, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS08 Health hazard pictogramGHS09 Environment pictogram

Danger

Benz[e]acephenanthrylene

  • May cause cancer <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
  • Very toxic to aquatic life.
  • Very toxic to aquatic life with long lasting effects.
  • Obtain special instructions before use.
  • Avoid release to the environment.
  • Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/
  • IF exposed or concerned:
  • Get medical advice/attention.
  • Collect spillage.
  • Dispose of contents/container to

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open Benz[e]acephenanthrylene in the GHS label constructor →

07 · Health hazards

Benz[e]acephenanthrylene health hazards and exposure limits

Benz[e]acephenanthrylene hazard summary

May cause irritation; [MSDSonline] See POLYCYCLIC AROMATIC HYDROCARBONS.

Source: Haz-Map, Information on Hazardous Chemicals and Occupational Diseases

Benz[e]acephenanthrylene carcinogenicity classification

IARC classification Group 2B — Possibly carcinogenic to humans
IARC monographs Volume 92: (2010) Some Non-heterocyclic Polycyclic Aromatic Hydrocarbons and Some Related Exposures

CLASSIFICATION: B2; probable human carcinogen. BASIS FOR CLASSIFICATION: Based on no human data and sufficient data from animal bioassays. Benzo[b]fluoranthene produced tumors in mice after lung implantation, intraperitoneal (i.p.) or subcutaneous (s.c.) injection and skin painting.HUMAN CARCINOGENICITY DATA: None. ANIMAL CARCINOGENICITY DATA: Sufficient.

Source: Hazardous Substances Data Bank (HSDB)

No data are available in humans. Sufficient evidence of carcinogenicity in animals. OVERALL EVALUATION: Group 2B: The agent is possibly carcinogenic to humans.

Source: Hazardous Substances Data Bank (HSDB)

An IARC group and a CLP classification answer different questions. IARC judges whether the evidence for cancer in humans is strong enough; CLP Annex VI is the legally binding EU classification. A substance can carry one and not the other.

Benz[e]acephenanthrylene occupational exposure limits

US occupational exposure limits reported for Benz[e]acephenanthrylene. PEL is enforceable (OSHA), REL is a recommendation (NIOSH), IDLH is the concentration at which escape becomes impossible without injury.
Limit Value Source
IDLH NIOSH considers coal tar pitch volatiles to be potential occupational carcinogens. /Coal tar pitch volatiles/ Hazardous Substances Data Bank (HSDB)

These are United States values. The European Union sets its own indicative and binding limits, and the figure that applies at a given workplace is the one in the local regulation — not the one shown here.

08 · Physical and chemical properties

Benz[e]acephenanthrylene properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

Benz[e]acephenanthrylene boiling point

Property Value Conditions Source
Boiling point 481 °C (897.8 °F) ICSC

Benz[e]acephenanthrylene melting point

Property Value Conditions Source
Melting point 168.4 °C (335.1 °F) HSDB
168 °C (334.4 °F) ICSC

Benz[e]acephenanthrylene solubility

Property Value Conditions Source
Solubility In water, 0.0015 mg/L, temperature not specified HSDB
In water, 0.0012 mg/L, temperature not specified HSDB
Miscible with benzene HSDB

Benz[e]acephenanthrylene vapor pressure

Property Value Conditions Source
Vapor pressure 5e-7 mmHg at 20 °C HSDB
5e-7 mmHg Haz-Map

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

09 · Handling and storage

Benz[e]acephenanthrylene storage and handling

Benz[e]acephenanthrylene safe storage

Provision to contain effluent from fire extinguishing. Well closed.

Source: ILO-WHO International Chemical Safety Cards (ICSCs)

Benz[e]acephenanthrylene storage conditions

Keep container tightly closed in a dry and well-ventilated place. Storage class (TRGS 510): Non-combustible, acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects.[Sigma-Aldrich; Safety Data Sheet for Benzo

Source: Hazardous Substances Data Bank (HSDB)

Benz[e]acephenanthrylene incompatible materials

Incompatible materials: Strong oxidizing agents.[Sigma-Aldrich; Safety Data Sheet for Benzo

Source: Hazardous Substances Data Bank (HSDB)

Benz[e]acephenanthrylene reactivity

BENZO[B]FLUORANTHENE can react with strong oxidizing agents. May react with electrophiles, peroxides, nitrogen oxides and sulfur oxides (NTP, 1992)

Source: CAMEO Chemicals

Planning storage for a mix of chemicals? Check Benz[e]acephenanthrylene in the storage compatibility matrix →

10 · Questions

Benz[e]acephenanthrylene — frequently asked questions

What is the CAS number of Benz[e]acephenanthrylene?

The CAS number of Benz[e]acephenanthrylene is 205-99-2. Its EC number is 205-911-9.

What is the chemical formula of Benz[e]acephenanthrylene?

The molecular formula of Benz[e]acephenanthrylene is C20H12 and its molecular weight is 252.3 g/mol.

What does a Benz[e]acephenanthrylene label have to show?

Under CLP Annex VI the label for Benz[e]acephenanthrylene carries the pictograms Health hazard and Environment and the signal word is Danger.

Is Benz[e]acephenanthrylene flammable?

CLP Annex VI assigns Benz[e]acephenanthrylene no flammability hazard class. That is not a statement that it cannot burn: the harmonised list only records the hazards that were assessed for it.

Is Benz[e]acephenanthrylene a carcinogen?

Yes. CLP Annex VI classifies Benz[e]acephenanthrylene as a category 1A or 1B carcinogen and assigns it H350: may cause cancer. IARC places it in Group 2B: possibly carcinogenic to humans.

What is the boiling point of Benz[e]acephenanthrylene?

The boiling point reported for Benz[e]acephenanthrylene is 481 °C (897.8 °F) (ICSC).

What is the melting point of Benz[e]acephenanthrylene?

The melting point reported for Benz[e]acephenanthrylene is 168.4 °C (335.1 °F) (HSDB).

How should Benz[e]acephenanthrylene be stored?

Keep container tightly closed in a dry and well-ventilated place. Storage class (TRGS 510): Non-combustible, acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects.[Sigma-Aldrich; Safety Data Sheet for Benzo (Hazardous Substances Data Bank (HSDB))

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