Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

Cadmium

Cadmium is a silvery-white metal and is odorless.

CAS 7440-43-9 Cd 112.41 g/mol Danger

Cadmium Safety Data Sheet →

01 · Identification

What Cadmium is

Cadmium is a silvery-white metal and is odorless. Its molecular formula is Cd and its molecular weight is 112.41 g/mol. It boils at 767 °C, melts at 32.1 °C, is practically insoluble in water.

Under the GHS it carries the signal word Danger. It is classed as hazardous Air Pollutants (HAPs).

02 · Identifiers

Cadmium identifiers and molecular data

Cadmium CAS number and EC number

CAS number7440-43-9
EC number231-152-8
Index number (CLP Annex VI)048-011-00-X

Cadmium molecular formula and molecular weight

Molecular formulaCd
Molecular weight112.41 g/mol
Chemical class Hazardous Air Pollutants (HAPs)

Other names for Cadmium

  • C.I. 77180
  • Cadmium Dust (As Cd)
  • Cadmium Metal: Cadmium
  • cadmium (pyrophoric)

03 · GHS classification

Cadmium hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

Cadmium pictograms and signal word

Signal wordDanger

Cadmium hazard class and category

GHS hazard classes Cadmium falls into
Hazard class Category From code Pictogram
Pyrophoric liquids or Pyrophoric solids Category 1 H250 GHS02
Acute toxicity - inhalation GHS chapter 3.1 Category 1 or 2 H330 GHS06
Germ cell mutagenicity GHS chapter 3.5 Category 2 H341 GHS08
Carcinogenicity GHS chapter 3.6 Category 1A or 1B H350 GHS08
Specific target organ toxicity - repeated exposure GHS chapter 3.9 Category 1 H372 GHS08
Hazardous to the aquatic environment - acute GHS chapter 4.1 Category 1 H400 GHS09
Hazardous to the aquatic environment - chronic GHS chapter 4.1 Category 1 H410 GHS09

Where two values are shown with “or”, the hazard statement is shared by more than one category or by more than one class, and the code alone does not say which. H272, for example, belongs to oxidising liquids and to oxidising solids — the physical state decides. The binding answer for a specific entry is in the CLP Annex VI table itself.

Cadmium hazard statements (H-codes)

Hazard statements assigned to Cadmium
CodeHazard statement
H250 Catches fire spontaneously if exposed to air.
H350 May cause cancer <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
H341 Suspected of causing genetic defects <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
H361fd Suspected of damaging fertility. Suspected of damaging the unborn child.
H330 Fatal if inhaled.
H372 Causes damage to organs <or state all organs affected, if known> through prolonged or repeated exposure <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.

This page lists only the codes assigned to Cadmium. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for Cadmium

Our own Cadmium safety data sheet walks through all sixteen sections of the published data. What it is not is the document an inspector asks for: an SDS is issued for a product by its supplier, so the sheet covering the grade actually standing in your store exists only in that supplier’s version. Collecting those and keeping them current as suppliers revise them is a separate job.

04 · Precautionary statements

Cadmium precautionary statements

CLP Annex VI assigns 13 precautionary statements to Cadmium. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Disposal

What has to happen to the contents and the empty container.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

Cadmium name in 23 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български кадмий (пирофорен)
Spanish español Cadmio (pirofórico)
Czech čeština kadmium (pyroforické)
Danish dansk cadmium (ustabiliseret)
German Deutsch Cadmium (pyrophor)
Estonian eesti kaadmium (pürofoorne)
Greek ελληνικά κάδμιο (πυροφόρο)
English English cadmium (pyrophoric)
French français cadmium (pyrophorique)
Croatian hrvatski kadmij (piroforni)
Italian italiano cadmio (piroforico)
Latvian latviešu kadmijs (pirofors)
Lithuanian lietuvių kadmis (piroforas)
Hungarian magyar kadmium (piroforos)
Maltese Malti kadmju (piroforiku)
Dutch Nederlands cadmium (pyrofoor)
Polish polski kadm (piroforyczny)
Portuguese português cádmio (pirofórico)
Romanian română cadmiu (piroforic)
Slovak slovenčina kadmium (pyroforické)
Slovenian slovenščina kadmij (piroforen)
Finnish suomi kadmium (pyroforinen)
Swedish svenska kadmium (pyrofort)

All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

Cadmium GHS label elements

Everything CLP Annex VI fixes for Cadmium, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS02 Flame pictogramGHS06 Skull and crossbones pictogramGHS08 Health hazard pictogramGHS09 Environment pictogram

Danger

Cadmium

  • Catches fire spontaneously if exposed to air.
  • May cause cancer <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
  • Suspected of causing genetic defects <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
  • Suspected of damaging fertility. Suspected of damaging the unborn child.
  • Fatal if inhaled.
  • Causes damage to organs <or state all organs affected, if known> through prolonged or repeated exposure <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
  • Very toxic to aquatic life.
  • Very toxic to aquatic life with long lasting effects.
  • Obtain special instructions before use.
  • Do not breathe dust/fume/gas/mist/vapours/spray.
  • Do not eat, drink or smoke when using this product.
  • Use only outdoors or in a well-ventilated area.
  • Avoid release to the environment.
  • Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/
  • IF INHALED:
  • IF exposed or concerned:
  • Immediately call a POISON CENTER/doctor/
  • Get medical advice/attention.
  • Get medical advice/attention if you feel unwell.
  • Collect spillage.
  • Dispose of contents/container to

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open Cadmium in the GHS label constructor →

07 · Health hazards

Cadmium health hazards and exposure limits

Cadmium hazard summary

Cadmium is a natural element in the earth's crust. It is usually found as a mineral combined with other elements such as oxygen (cadmium oxide), chlorine (cadmium chloride), or sulfur (cadmium sulfate, cadmium sulfide). All soils and rocks, including coal and mineral fertilizers, contain some cadmium. Most cadmium used in the United States is extracted during the production of other metals like zinc, lead, and copper. Cadmium does not corrode easily and has many uses, including batteries, pigments, metal coatings, and plastics.

Source: Agency for Toxic Substances and Disease Registry (ATSDR)

Cadmium carcinogenicity classification

IARC classification Group 1 — Carcinogenic to humans
IARC monographs Volume 58: (1993) Beryllium, Cadmium, Mercury, and Exposures in the Glass Manufacturing Industry

Cancer Classification: Group B1 Probable Human Carcinogen

Source: Hazardous Substances Data Bank (HSDB)

CLASSIFICATION: B1; probable human carcinogen. BASIS FOR CLASSIFICATION: Limited evidence from occupational epidemiologic studies of cadmium is consistent across investigators and study populations. There is sufficient evidence of carcinogenicity in rats and mice by inhalation and intramuscular and subcutaneous injection. Seven studies in rats and mice wherein cadmium salts (acetate, sulfate, chloride) were administered orally have shown no evidence of carcinogenic response. HUMAN CARCINOGENICITY DATA: Limited.

Source: Hazardous Substances Data Bank (HSDB)

An IARC group and a CLP classification answer different questions. IARC judges whether the evidence for cancer in humans is strong enough; CLP Annex VI is the legally binding EU classification. A substance can carry one and not the other.

Cadmium occupational exposure limits

US occupational exposure limits reported for Cadmium. PEL is enforceable (OSHA), REL is a recommendation (NIOSH), IDLH is the concentration at which escape becomes impossible without injury.
Limit Value Source
PEL 0.005 [mg/m3], as Cd, see 29 CFR 1910.1027 Haz-Map, Information on Hazardous Chemicals and Occupational Diseases
PEL 5 µg/m³ [2.5 µg/m³ Action Level] Occupational Safety and Health Administration (OSHA)
PEL [1910.1027] TWA 0.005 mg/m3 [*Note: The PEL applies to all Cadmium compounds (as Cd).] The National Institute for Occupational Safety and Health (NIOSH)
REL Ca See Appendix A [*Note: The REL applies to all Cadmium compounds (as Cd).] The National Institute for Occupational Safety and Health (NIOSH)
IDLH 9 mg Cd/m3 ; A potential occupational carcinogen. (NIOSH, 2024) CAMEO Chemicals
IDLH 9.0 [mg/m3], as Cd Haz-Map, Information on Hazardous Chemicals and Occupational Diseases
IDLH 9 mg/m³ Occupational Safety and Health Administration (OSHA)

These are United States values. The European Union sets its own indicative and binding limits, and the figure that applies at a given workplace is the one in the local regulation — not the one shown here.

08 · Physical and chemical properties

Cadmium properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

Cadmium boiling point

Property Value Conditions Source
Boiling point 767 °C (1412.6 °F) HSDB
765 °C (1409 °F) NIOSH
765 °C (1409 °F) at 760 mmHg CAMEO

Cadmium melting point

Property Value Conditions Source
Melting point 32.07 °C (89.7 °F) HSDB
321.11 °C (610 °F) NIOSH
320.89 °C (609.6 °F) CAMEO

Cadmium density

Property Value Conditions Source
Density 8.65 g/cm³ metal NIOSH
8.642 g/cm³ CAMEO
8.69 g/cm³ at 25 °C HSDB

Cadmium solubility

Property Value Conditions Source
Solubility Insoluble in water HSDB
Insoluble NIOSH
Insoluble (NIOSH, 2024) CAMEO

Cadmium vapor pressure

Property Value Conditions Source
Vapor pressure 0.0000021 mmHg HSDB
0 mmHg approx NIOSH

Cadmium autoignition temperature

Property Value Conditions Source
Autoignition temperature 250 °C (482 °F) Cadmium metal dust HSDB
250 °C (482 °F) cadmium metal dust ICSC

Cadmium lower explosive limit (LEL)

Property Value Conditions Source
Lower explosive limit (LEL) The dust ignites spontaneously in air and is flammable and explosive when exposed to heat ... . HSDB
Metal: Noncombustible Solid in bulk form, but will burn in powder form. NIOSH

Cadmium corrosivity

Property Value Conditions Source
Corrosivity Corrosion resistance poor in industrial atmosphere HSDB

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

09 · Fire and explosion

Cadmium fire and explosion behaviour

These are descriptions rather than measured values, so they are kept out of the table above and quoted here with the source that reported them.

Cadmium fire potential

Powdered cadmium is flammable.

Source: Hazardous Substances Data Bank (HSDB)

10 · Handling and storage

Cadmium storage and handling

Cadmium reactive group

CAMEO Chemicals places Cadmium in the reactive group Metals, Elemental and Powder, Active. Compatibility with other chemicals is worked out from the group, not from the individual substance — which is why two substances you have never seen react can still be flagged as a pair that must be separated.

A reactive group is a CAMEO Chemicals (US NOAA) grouping, not a GHS hazard class: it has no code, no category and no legal force. It is what the storage compatibility matrix on this site computes from.

Cadmium safe storage

Fireproof. Dry. Keep under inert gas. Separated from ignition sources, oxidants, acids and food and feedstuffs.

Source: ILO-WHO International Chemical Safety Cards (ICSCs)

Cadmium storage conditions

Keep containers closed and protect against physical damage.

Source: Hazardous Substances Data Bank (HSDB)

Cadmium incompatible materials

The dust ignites spontaneously in air and is flammable and explosive when exposed to heat, flame, or by chemical reaction with oxidizing agents, metals, ammonia, zinc, selenium, and tellurium.

Source: Hazardous Substances Data Bank (HSDB)

Cadmium reactivity

A violent explosion occurred 30 minutes after placement of a CADMIUM rod into hydrazoic acid [Mellor 8 Supp. 2:50 1967]. Fused ammonium nitrate with powdered metal often produces a violent explosive reaction. Reactivity similar to zinc. May be incompatible with oxidants.

Source: CAMEO Chemicals

Planning storage for a mix of chemicals? Check Cadmium in the storage compatibility matrix →

11 · Questions

Cadmium — frequently asked questions

What is the CAS number of Cadmium?

The CAS number of Cadmium is 7440-43-9. Its EC number is 231-152-8.

What is the chemical formula of Cadmium?

The molecular formula of Cadmium is Cd and its molecular weight is 112.41 g/mol.

What does a Cadmium label have to show?

Under CLP Annex VI the label for Cadmium carries the pictograms Flame, Skull and crossbones, Health hazard and Environment and the signal word is Danger.

Is Cadmium flammable?

Yes. CLP Annex VI assigns Cadmium H250 — catches fire spontaneously if exposed to air.

Is Cadmium a carcinogen?

Yes. CLP Annex VI classifies Cadmium as a category 1A or 1B carcinogen and assigns it H350: may cause cancer. IARC places it in Group 1: carcinogenic to humans.

What is the exposure limit for Cadmium?

The US occupational exposure limit reported for Cadmium is 0.005 [mg/m3], as Cd, see 29 CFR 1910.1027 (Haz-Map, Information on Hazardous Chemicals and Occupational Diseases). Limits differ by country: the EU sets its own indicative and binding values, and the figure that applies at a given workplace is the one in the local regulation.

What is the boiling point of Cadmium?

The boiling point reported for Cadmium is 767 °C (1412.6 °F) (HSDB).

What is the melting point of Cadmium?

The melting point reported for Cadmium is 32.07 °C (89.7 °F) (HSDB).

How should Cadmium be stored?

Keep containers closed and protect against physical damage. (Hazardous Substances Data Bank (HSDB))

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