Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

Furfuryl Alcohol

Furfuryl Alcohol is a colorless to yellow liquid with a faint burning odor.

CAS 98-00-0 Danger

01 · Identification

What Furfuryl Alcohol is

Furfuryl Alcohol is a colorless to yellow liquid with a faint burning odor. It boils at 171 °C, melts at -14.6 °C, is soluble in water.

Under the GHS it carries the signal word Danger. It is classed as flammable agents - 2nd degree.

02 · Identifiers

Furfuryl Alcohol identifiers and molecular data

Furfuryl Alcohol CAS number and EC number

CAS number98-00-0
EC number202-626-1
Index number (CLP Annex VI)603-018-00-2

Furfuryl Alcohol molecular formula and molecular weight

Chemical class Flammable agents - 2nd degree

03 · GHS classification

Furfuryl Alcohol hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

Furfuryl Alcohol pictograms and signal word

Signal wordDanger

Furfuryl Alcohol hazard class and category

GHS hazard classes Furfuryl Alcohol falls into
Hazard class Category From code Pictogram
Acute toxicity - oral GHS chapter 3.1 Category 4 H302 GHS07
Acute toxicity - dermal GHS chapter 3.1 Category 4 H312 GHS07
Acute toxicity - inhalation GHS chapter 3.1 Category 3 H331 GHS06
Serious eye damage/eye irritation GHS chapter 3.3 Category 2A H319 GHS07
Carcinogenicity GHS chapter 3.6 Category 2 H351 GHS08
Specific target organ toxicity - single exposure GHS chapter 3.8 Category 3 H335 GHS07
Specific target organ toxicity - repeated exposure GHS chapter 3.9 Category 2 H373 GHS08

Furfuryl Alcohol hazard statements (H-codes)

Hazard statements assigned to Furfuryl Alcohol
CodeHazard statement
H351 Suspected of causing cancer <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
H331 Toxic if inhaled.
H312 Harmful in contact with skin.
H302 Harmful if swallowed.
H335 May cause respiratory irritation.
H373 May cause damage to organs <or state all organs affected, if known> through prolonged or repeated exposure <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
H319 Causes serious eye irritation.

This page lists only the codes assigned to Furfuryl Alcohol. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for Furfuryl Alcohol

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of Furfuryl Alcohol issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

04 · Precautionary statements

Furfuryl Alcohol precautionary statements

CLP Annex VI assigns 19 precautionary statements to Furfuryl Alcohol. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

Furfuryl Alcohol name in 23 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български фурфурилов алкохол
Spanish español Alcohol furfurílico
Czech čeština furfurylalkohol (2-furyl)methanol
Danish dansk furfurylalkohol
German Deutsch Furfurylalkohol
Estonian eesti furfurüülalkohol
Greek ελληνικά φουρφουρυλική αλκοόλη
English English furfuryl alcohol
French français alcool furfurylique
Croatian hrvatski furfuril-alkohol
Italian italiano alcool furfurilico
Latvian latviešu furfurilspirts
Lithuanian lietuvių furfurilo alkoholis
Hungarian magyar furfuril-alkohol
Maltese Malti alkoħol tal-furfuril
Dutch Nederlands furfurylalcohol
Polish polski alkohol furfurylowy 2-furylometanol
Portuguese português álcool furfurílico
Romanian română alcool furfurilic
Slovak slovenčina furfurylalkohol
Slovenian slovenščina furfuril alkohol
Finnish suomi furfuryylialkoholi
Swedish svenska furfurylalkohol

All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

Furfuryl Alcohol GHS label elements

Everything CLP Annex VI fixes for Furfuryl Alcohol, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS06 Skull and crossbones pictogramGHS08 Health hazard pictogram

Danger

Furfuryl Alcohol

  • Suspected of causing cancer <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
  • Toxic if inhaled.
  • Harmful in contact with skin.
  • Harmful if swallowed.
  • May cause respiratory irritation.
  • May cause damage to organs <or state all organs affected, if known> through prolonged or repeated exposure <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
  • Causes serious eye irritation.
  • Obtain special instructions before use.
  • Do not breathe dust/fume/gas/mist/vapours/spray.
  • Wash thoroughly after handling.
  • Do not eat, drink or smoke when using this product.
  • Use only outdoors or in a well-ventilated area.
  • Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/
  • IF SWALLOWED:
  • IF ON SKIN:
  • IF INHALED:
  • IF IN EYES:
  • IF exposed or concerned:
  • Immediately call a POISON CENTER/doctor/
  • Call a POISON CENTER/doctor/ if you feel unwell.
  • Get medical advice/attention.
  • Get medical advice/attention if you feel unwell.
  • Rinse mouth.
  • If eye irritation persists:
  • Remove contact lenses, if present and easy to do. Continue rinsing.
  • Wash with plenty of water/

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open Furfuryl Alcohol in the GHS label constructor →

07 · Health hazards

Furfuryl Alcohol health hazards and exposure limits

Furfuryl Alcohol hazard summary

Asthma reported in a foundry mold making worker; [Malo] Furfuryl alcohol causes hypoactivity and respiratory tract lesions in high-dose inhalation studies of rats and mice. It causes liver damage in animals fed 1 mg/day for 60 days. Potential for sensitization, but insufficient data for DSEN or RSEN notations; [ACGIH] A skin, eye, and respiratory tract irritant; [ICSC] Causes lacrimation and defatting of skin; [ICSC]

Source: Haz-Map, Information on Hazardous Chemicals and Occupational Diseases

Furfuryl Alcohol carcinogenicity classification

IARC classification Group 2B — Possibly carcinogenic to humans
IARC monographs Volume 119: (2019) Some Chemicals That Cause Tumours of the Urinary Tract in Rodents

Under the conditions of these 2-year inhalation studies, there was some evidence of carcinogenic activity of furfuryl alcohol in male F344/N rats based on increased incidences of combined neoplasms of the nose. There was of equivocal evidence carcinogenic activity of furfuryl alcohol in female F344/N rats based on marginally increased incidences of neoplasms of the nose and renal tubule neoplasms. There was some evidence of carcinogenic activity of furfuryl alcohol in male B6C3F1 mice based on increased inci dences of renal tubule neoplasms. There was no evidence of carcinogenic activity of furfuryl alcohol in female B6C3F1 mice exposed to 2, 8, or 32 ppm.

Source: US National Toxicology Program · TR-482: Toxicology and Carcinogenesis Studies of Furfural Alcohol in F344/N Rats and B6C3F1 Mice (Inhalation Studies) (1999 )

An IARC group and a CLP classification answer different questions. IARC judges whether the evidence for cancer in humans is strong enough; CLP Annex VI is the legally binding EU classification. A substance can carry one and not the other.

Furfuryl Alcohol occupational exposure limits

US occupational exposure limits reported for Furfuryl Alcohol. PEL is enforceable (OSHA), REL is a recommendation (NIOSH), IDLH is the concentration at which escape becomes impossible without injury.
Limit Value Source
PEL 50.0 [ppm] Haz-Map, Information on Hazardous Chemicals and Occupational Diseases
PEL 50 ppm (200 mg/m³) Occupational Safety and Health Administration (OSHA)
PEL TWA 50 ppm (200 mg/m3) See Appendix G The National Institute for Occupational Safety and Health (NIOSH)
REL 10 ppm (40 mg/m³) Occupational Safety and Health Administration (OSHA)
REL 15 ppm (60 mg/m³) Occupational Safety and Health Administration (OSHA)
REL TWA 10 ppm (40 mg/m3) ST 15 ppm (60 mg/m3) [skin] The National Institute for Occupational Safety and Health (NIOSH)
IDLH 75 ppm (NIOSH, 2024) CAMEO Chemicals
IDLH 75.0 [ppm] Haz-Map, Information on Hazardous Chemicals and Occupational Diseases
IDLH 75 ppm Hazardous Substances Data Bank (HSDB)

These are United States values. The European Union sets its own indicative and binding limits, and the figure that applies at a given workplace is the one in the local regulation — not the one shown here.

08 · Physical and chemical properties

Furfuryl Alcohol properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

Furfuryl Alcohol boiling point

Property Value Conditions Source
Boiling point 171 °C (339.8 °F) HSDB
170 °C (338 °F) NIOSH
170 °C (338 °F) at 760 mmHg CAMEO

Furfuryl Alcohol melting point

Property Value Conditions Source
Melting point -14.6 °C (5.7 °F) HSDB
-14.44 °C (6 °F) NIOSH
-31.11 °C (-24 °F) CAMEO

Furfuryl Alcohol density

Property Value Conditions Source
Density 1.13 g/cm³ NIOSH
1.1296 g/cm³ at 20 °C HSDB
1.13 g/cm³ at 20 °C CAMEO

Furfuryl Alcohol solubility

Property Value Conditions Source
Solubility Soluble in chloroform; very soluble in ethanol, ethyl ether HSDB
Soluble in alcohol, benzene; very soluble in ether HSDB
Miscible with alcohol, ether, acetone, and ethyl acetate, and most organic solvents with the exception of paraffinic hydrocarbons HSDB

Furfuryl Alcohol vapor pressure

Property Value Conditions Source
Vapor pressure 0.4 mmHg at 20 °C CAMEO
0.3975 mmHg at 20 °C ICSC
0.6 mmHg at 25 °C NIOSH

Furfuryl Alcohol flash point

Property Value Conditions Source
Flash point 75 °C (167 °F) Open cup HSDB
65 °C (149 °F) NIOSH
75 °C (167 °F) CAMEO

Furfuryl Alcohol autoignition temperature

Property Value Conditions Source
Autoignition temperature 490 °C (914 °F) HSDB
391.11 °C (736 °F) CAMEO
390 °C (734 °F) ICSC

Furfuryl Alcohol lower explosive limit (LEL)

Property Value Conditions Source
Lower explosive limit (LEL) 1.8 % by volume HSDB

Furfuryl Alcohol upper explosive limit (UEL)

Property Value Conditions Source
Upper explosive limit (UEL) 16.3 % by volume HSDB

Furfuryl Alcohol vapor density

Property Value Conditions Source
Vapor density 3.37 (air = 1) HSDB
3.4 (air = 1) CAMEO

Furfuryl Alcohol odor threshold

Property Value Conditions Source
Odor threshold 50% response: 8 ppm HSDB
Odor Threshold Low: 8.0 [ppm] Haz-Map
Detection odor threshold from AIHA (mean = 8.0 ppm) Haz-Map

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

09 · Fire and explosion

Furfuryl Alcohol fire and explosion behaviour

These are descriptions rather than measured values, so they are kept out of the table above and quoted here with the source that reported them.

Furfuryl Alcohol fire potential

Moderate, when exposed to heat; can react with oxidizing materials.

Source: Hazardous Substances Data Bank (HSDB)

10 · Handling and storage

Furfuryl Alcohol storage and handling

Furfuryl Alcohol safe storage

Separated from strong oxidants, acids and food and feedstuffs. Well closed. Ventilation along the floor.

Source: ILO-WHO International Chemical Safety Cards (ICSCs)

Furfuryl Alcohol storage conditions

... SHOULD BE STORED IN A COOL, WELL VENTILATED PLACE, OUT OF THE DIRECT RAYS OF THE SUN, AWAY FROM AREAS OF HIGH FIRE HAZARD ... .

Source: Hazardous Substances Data Bank (HSDB)

Furfuryl Alcohol incompatible materials

Strong oxidizers & acids [Note: Contact with organic acids may lead to polymerization].

Source: Hazardous Substances Data Bank (HSDB)

Furfuryl Alcohol reactivity

Acetyl bromide reacts violently with alcohols or water, [Merck 11th ed., 1989]. Mixtures of alcohols with concentrated sulfuric acid and strong hydrogen peroxide can cause explosions. Example: An explosion will occur if dimethylbenzylcarbinol is added to 90% hydrogen peroxide then acidified with concentrated sulfuric acid. Mixtures of ethyl alcohol with concentrated hydrogen peroxide form powerful explosives. Mixtures of hydrogen peroxide and 1-phenyl-2-methyl propyl alcohol tend to explode if acidified with 70% sulfuric acid, [Chem. Eng. News 45(43):73(1967); J, Org. Chem. 28:1893(1963)].

Source: CAMEO Chemicals

Planning storage for a mix of chemicals? Check Furfuryl Alcohol in the storage compatibility matrix →

11 · Transport

Furfuryl Alcohol UN number and transport classification

Transport classification is a separate system from the GHS classification above. It decides how a package is marked and how a load may be carried; it does not follow from the workplace label, and the workplace label does not follow from it. The entries below are linked by CAS number, never by name.

Furfuryl Alcohol under UN 2874 — shipping name, class and packing group

Europe · ADR 2025, Table A

Proper shipping name (3.1.2) Class Classification code PG Labels (column 5)
FURFURYL ALCOHOL 6.1 T1 III
  • ADR label model 6.1 — Toxic substance
6.1

Source: ADR 2025, Table A of Chapter 3.2 · ECE/TRANS/352 Vol. I (UNECE). Class 6.1 is “Toxic substances” (ADR 2.1.1.1).

Proper shipping name (column 2) Class or division PG Labels (column 6)
Furfuryl alcohol 6.1 III
  • US DOT POISON label (§172.430)
6.1

Source: 49 CFR 172.101 Hazardous Materials Table · eCFR, revision 2026-08-03. Class 6.1 is “Poisonous materials” (49 CFR 173.2).

Full UN 2874 entry — special provisions, packing instructions, quantity limits and the orange plate →

12 · Questions

Furfuryl Alcohol — frequently asked questions

What is the CAS number of Furfuryl Alcohol?

The CAS number of Furfuryl Alcohol is 98-00-0. Its EC number is 202-626-1.

What does a Furfuryl Alcohol label have to show?

Under CLP Annex VI the label for Furfuryl Alcohol carries the pictograms Skull and crossbones and Health hazard and the signal word is Danger.

Is Furfuryl Alcohol flammable?

CLP Annex VI assigns Furfuryl Alcohol no flammability hazard class. That is not a statement that it cannot burn: the harmonised list only records the hazards that were assessed for it. The flash point reported for it is 75 °C (167 °F), Open cup (HSDB).

Is Furfuryl Alcohol a carcinogen?

CLP Annex VI assigns Furfuryl Alcohol H351 — suspected of causing cancer. That is category 2: the evidence points that way but is not conclusive. IARC places it in Group 2B: possibly carcinogenic to humans.

What is the exposure limit for Furfuryl Alcohol?

The US occupational exposure limit reported for Furfuryl Alcohol is 50.0 [ppm] (Haz-Map, Information on Hazardous Chemicals and Occupational Diseases). Limits differ by country: the EU sets its own indicative and binding values, and the figure that applies at a given workplace is the one in the local regulation.

What is the boiling point of Furfuryl Alcohol?

The boiling point reported for Furfuryl Alcohol is 171 °C (339.8 °F) (HSDB).

What is the melting point of Furfuryl Alcohol?

The melting point reported for Furfuryl Alcohol is -14.6 °C (5.7 °F) (HSDB).

How should Furfuryl Alcohol be stored?

... SHOULD BE STORED IN A COOL, WELL VENTILATED PLACE, OUT OF THE DIRECT RAYS OF THE SUN, AWAY FROM AREAS OF HIGH FIRE HAZARD ... . (Hazardous Substances Data Bank (HSDB))

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