Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

Nickel Dichloride

Nickel Dichloride is yellow scales; golden yellow with a none odor.

CAS 7718-54-9 Cl2Ni 129.6 g/mol Danger

01 · Identification

What Nickel Dichloride is

Nickel Dichloride is yellow scales; golden yellow with a none odor. Its molecular formula is Cl2Ni and its molecular weight is 129.6 g/mol. It boils at 973 °C, melts at 1001 °C.

Under the GHS it carries the signal word Danger. It is classed as carcinogens.

02 · Identifiers

Nickel Dichloride identifiers and molecular data

Nickel Dichloride CAS number and EC number

CAS number7718-54-9
EC number231-743-0
Index number (CLP Annex VI)028-011-00-6

Nickel Dichloride molecular formula and molecular weight

Molecular formulaCl2Ni
Molecular weight129.6 g/mol
Chemical class Carcinogens

03 · GHS classification

Nickel Dichloride hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

Nickel Dichloride pictograms and signal word

Signal wordDanger

Nickel Dichloride hazard class and category

GHS hazard classes Nickel Dichloride falls into
Hazard class Category From code Pictogram
Acute toxicity - oral GHS chapter 3.1 Category 3 H301 GHS06
Acute toxicity - inhalation GHS chapter 3.1 Category 3 H331 GHS06
Skin corrosion/irritation GHS chapter 3.2 Category 2 H315 GHS07
Respiratory sensitisation GHS chapter 3.4 Category 1 or 1A or 1B H334 GHS08
Skin sensitisation GHS chapter 3.4 Category 1 or 1A or 1B H317 GHS07
Germ cell mutagenicity GHS chapter 3.5 Category 2 H341 GHS08
Specific target organ toxicity - repeated exposure GHS chapter 3.9 Category 1 H372 GHS08
Hazardous to the aquatic environment - acute GHS chapter 4.1 Category 1 H400 GHS09
Hazardous to the aquatic environment - chronic GHS chapter 4.1 Category 1 H410 GHS09

Where two values are shown with “or”, the hazard statement is shared by more than one category or by more than one class, and the code alone does not say which. H272, for example, belongs to oxidising liquids and to oxidising solids — the physical state decides. The binding answer for a specific entry is in the CLP Annex VI table itself.

Nickel Dichloride hazard statements (H-codes)

Hazard statements assigned to Nickel Dichloride
CodeHazard statement
H350i May cause cancer by inhalation.
H341 Suspected of causing genetic defects <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
H360D May damage the unborn child.
H331 Toxic if inhaled.
H301 Toxic if swallowed.
H372 Causes damage to organs <or state all organs affected, if known> through prolonged or repeated exposure <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
H315 Causes skin irritation.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H317 May cause an allergic skin reaction.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.

This page lists only the codes assigned to Nickel Dichloride. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for Nickel Dichloride

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of Nickel Dichloride issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

04 · Precautionary statements

Nickel Dichloride precautionary statements

CLP Annex VI assigns 22 precautionary statements to Nickel Dichloride. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Disposal

What has to happen to the contents and the empty container.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

Nickel Dichloride name in 23 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български никелов дихлорид
Spanish español Dicloruro de níquel
Czech čeština chlorid nikelnatý
Danish dansk nikkeldichlorid
German Deutsch Nickeldichlorid Nickelchlorid
Estonian eesti nikkeldikloriid
Greek ελληνικά διχλωριούχο νικέλιο
English English nickel dichloride
French français dichlorure de nickel
Croatian hrvatski niklov diklorid
Italian italiano dicloruro di nichel
Latvian latviešu niķeļa dihlorīds
Lithuanian lietuvių nikelio dichloridas
Hungarian magyar nikkel-diklorid
Maltese Malti diklorur tan-nikil
Dutch Nederlands nikkeldichloride
Polish polski dichlorek niklu(II)
Portuguese português dicloreto de níquel
Romanian română diclorură de nichel
Slovak slovenčina chlorid nikelnatý
Slovenian slovenščina nikljev diklorid
Finnish suomi nikkelidikloridi
Swedish svenska nickeldiklorid

All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

Nickel Dichloride GHS label elements

Everything CLP Annex VI fixes for Nickel Dichloride, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS06 Skull and crossbones pictogramGHS08 Health hazard pictogramGHS09 Environment pictogram

Danger

Nickel Dichloride

  • May cause cancer by inhalation.
  • Suspected of causing genetic defects <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
  • May damage the unborn child.
  • Toxic if inhaled.
  • Toxic if swallowed.
  • Causes damage to organs <or state all organs affected, if known> through prolonged or repeated exposure <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
  • Causes skin irritation.
  • May cause allergy or asthma symptoms or breathing difficulties if inhaled.
  • May cause an allergic skin reaction.
  • Very toxic to aquatic life.
  • Very toxic to aquatic life with long lasting effects.
  • Obtain special instructions before use.
  • Do not breathe dust/fume/gas/mist/vapours/spray.
  • Avoid breathing dust/fume/gas/mist/vapours/spray.
  • Wash thoroughly after handling.
  • Do not eat, drink or smoke when using this product.
  • Use only outdoors or in a well-ventilated area.
  • Contaminated work clothing should not be allowed out of the workplace.
  • Avoid release to the environment.
  • Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/
  • IF SWALLOWED:
  • IF ON SKIN:
  • IF INHALED:
  • IF exposed or concerned:
  • Immediately call a POISON CENTER/doctor/
  • Get medical advice/attention.
  • Get medical advice/attention if you feel unwell.
  • Rinse mouth.
  • If skin irritation occurs:
  • If skin irritation or rash occurs:
  • Wash with plenty of water/
  • Collect spillage.
  • Dispose of contents/container to

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open Nickel Dichloride in the GHS label constructor →

07 · Health hazards

Nickel Dichloride health hazards and exposure limits

Nickel Dichloride hazard summary

Irritating to eyes, nose, and throat; [HSDB] Danger of skin and airway sensitization; [MAK] There is limited evidence in experimental animals that nickel chloride is carcinogenic. [IARC] See Nickel and linked occupational diseases.

Source: Haz-Map, Information on Hazardous Chemicals and Occupational Diseases

Nickel Dichloride occupational exposure limits

US occupational exposure limits reported for Nickel Dichloride. PEL is enforceable (OSHA), REL is a recommendation (NIOSH), IDLH is the concentration at which escape becomes impossible without injury.
Limit Value Source
PEL 1.0 [mg/m3], as Ni Haz-Map, Information on Hazardous Chemicals and Occupational Diseases
IDLH 10 mg Ni/m3 ; A potential occupational carcinogen. (NIOSH, 2024) CAMEO Chemicals
IDLH 10.0 [mg/m3], as Ni Haz-Map, Information on Hazardous Chemicals and Occupational Diseases
IDLH NIOSH considers nickel metal and other compounds (as Ni) to be a potential occupational carcinogen. /Nickel metal and other compounds (as Ni)/ Hazardous Substances Data Bank (HSDB)

These are United States values. The European Union sets its own indicative and binding limits, and the figure that applies at a given workplace is the one in the local regulation — not the one shown here.

08 · Physical and chemical properties

Nickel Dichloride properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

Nickel Dichloride boiling point

Property Value Conditions Source
Boiling point 973 °C (1783.4 °F) sublimes HSDB

Nickel Dichloride melting point

Property Value Conditions Source
Melting point 1001 °C (1833.8 °F) HSDB

Nickel Dichloride density

Property Value Conditions Source
Density 3.51 g/cm³ HSDB
3.51 g/cm³ at 25 °C DOE PAC
3.55 g/cm³ at 15 °C CAMEO

Nickel Dichloride solubility

Property Value Conditions Source
Solubility Green scales, sol in water, alcohol, and ammonium hydroxide Hexahydrate HSDB
Soluble in ethanol and ammonium hydroxide, insoluble in ammonia HSDB

Nickel Dichloride vapor pressure

Property Value Conditions Source
Vapor pressure 1 mmHg at 671 °C, solid HSDB

Nickel Dichloride lower explosive limit (LEL)

Property Value Conditions Source
Lower explosive limit (LEL) A MIXTURE OF POTASSIUM & ... PRODUCES A STRONG EXPLOSION ON IMPACT ... . NICKEL CHLORIDE HSDB

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

09 · Fire and explosion

Nickel Dichloride fire and explosion behaviour

These are descriptions rather than measured values, so they are kept out of the table above and quoted here with the source that reported them.

Nickel Dichloride fire potential

Nonflammable

Source: Hazardous Substances Data Bank (HSDB)

Solubility

Green, deliquescent crystals or crystal powder, monoclinic, structure reported to be trans-(NiCl2(H2O)4.2H2O, sol in about one part water, in alcohol /Hexahydrate/

Source: HSDB

10 · Handling and storage

Nickel Dichloride storage and handling

Nickel Dichloride storage conditions

Use ambient storage temp and open venting.

Source: Hazardous Substances Data Bank (HSDB)

Nickel Dichloride reactivity

NICKEL CHLORIDE is a yellow, crystalline material, mildly toxic, carcinogenic. On contact with strong acids or acid fumes it produces highly toxic and corrosive hydrogen chloride gas. When heated to decomposition it emits toxic chloride fumes [Lewis, 3rd ed., 1993, p. 915].

Source: CAMEO Chemicals

Planning storage for a mix of chemicals? Check Nickel Dichloride in the storage compatibility matrix →

11 · Questions

Nickel Dichloride — frequently asked questions

What is the CAS number of Nickel Dichloride?

The CAS number of Nickel Dichloride is 7718-54-9. Its EC number is 231-743-0.

What is the chemical formula of Nickel Dichloride?

The molecular formula of Nickel Dichloride is Cl2Ni and its molecular weight is 129.6 g/mol.

What does a Nickel Dichloride label have to show?

Under CLP Annex VI the label for Nickel Dichloride carries the pictograms Skull and crossbones, Health hazard and Environment and the signal word is Danger.

Is Nickel Dichloride flammable?

CLP Annex VI assigns Nickel Dichloride no flammability hazard class. That is not a statement that it cannot burn: the harmonised list only records the hazards that were assessed for it.

Is Nickel Dichloride a carcinogen?

Yes. CLP Annex VI classifies Nickel Dichloride as a category 1A or 1B carcinogen and assigns it H350i: may cause cancer by inhalation.

What is the exposure limit for Nickel Dichloride?

The US occupational exposure limit reported for Nickel Dichloride is 1.0 [mg/m3], as Ni (Haz-Map, Information on Hazardous Chemicals and Occupational Diseases). Limits differ by country: the EU sets its own indicative and binding values, and the figure that applies at a given workplace is the one in the local regulation.

What is the boiling point of Nickel Dichloride?

The boiling point reported for Nickel Dichloride is 973 °C (1783.4 °F), sublimes (HSDB).

What is the melting point of Nickel Dichloride?

The melting point reported for Nickel Dichloride is 1001 °C (1833.8 °F) (HSDB).

How should Nickel Dichloride be stored?

Use ambient storage temp and open venting. (Hazardous Substances Data Bank (HSDB))

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