Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

Nickel perchlorate

Nickel perchlorate is a substance with a harmonised classification under EU CLP.

CAS 13637-71-3 Danger

01 · Identification

What Nickel perchlorate is

Nickel perchlorate is a substance with a harmonised classification under EU CLP.

Under the GHS it carries the signal word Danger.

02 · Identifiers

Nickel perchlorate identifiers and molecular data

Nickel perchlorate CAS number and EC number

CAS number13637-71-3
EC number237-124-1
Index number (CLP Annex VI)028-016-00-3

Other names for Nickel perchlorate

  • nickel diperchlorate
  • perchloric acid, nickel(II) salt

03 · GHS classification

Nickel perchlorate hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

Nickel perchlorate pictograms and signal word

Signal wordDanger

Nickel perchlorate hazard class and category

GHS hazard classes Nickel perchlorate falls into
Hazard class Category From code Pictogram
Skin corrosion/irritation GHS chapter 3.2 Category 1A or 1B or 1C H314 GHS05
Respiratory sensitisation GHS chapter 3.4 Category 1 or 1A or 1B H334 GHS08
Skin sensitisation GHS chapter 3.4 Category 1 or 1A or 1B H317 GHS07
Germ cell mutagenicity GHS chapter 3.5 Category 2 H341 GHS08
Specific target organ toxicity - repeated exposure GHS chapter 3.9 Category 1 H372 GHS08
Hazardous to the aquatic environment - acute GHS chapter 4.1 Category 1 H400 GHS09
Hazardous to the aquatic environment - chronic GHS chapter 4.1 Category 1 H410 GHS09

Where two values are shown with “or”, the hazard statement is shared by more than one category or by more than one class, and the code alone does not say which. H272, for example, belongs to oxidising liquids and to oxidising solids — the physical state decides. The binding answer for a specific entry is in the CLP Annex VI table itself.

Nickel perchlorate hazard statements (H-codes)

Hazard statements assigned to Nickel perchlorate
CodeHazard statement
H350i May cause cancer by inhalation.
H341 Suspected of causing genetic defects <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
H360D May damage the unborn child.
H372 Causes damage to organs <or state all organs affected, if known> through prolonged or repeated exposure <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
H314 Causes severe skin burns and eye damage.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H317 May cause an allergic skin reaction.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.

This page lists only the codes assigned to Nickel perchlorate. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for Nickel perchlorate

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of Nickel perchlorate issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

04 · Precautionary statements

Nickel perchlorate precautionary statements

CLP Annex VI assigns 16 precautionary statements to Nickel perchlorate. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Disposal

What has to happen to the contents and the empty container.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

Nickel perchlorate name in 23 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български никелов диперхлорат никелова(II) сол на перхлорната киселина
Spanish español Diperclorato de níquel ácido perclórico, sal de níquel (II)
Czech čeština chloristan nikelnatý kyselina chloristá, nikelnatá sůl
Danish dansk nikkeldiperchlorat perchlorsyre, nikkel(II)salt
German Deutsch Nickeldiperchlorat Perchlorsäure, Nickel(II)-Salz
Estonian eesti nikkeldiperkloraat perkloorhappe nikkel(II)sool
Greek ελληνικά διυπερχλωρικό νικέλιο άλας υπερχλωρικού οξέος με νικέλιο(II)
English English nickel diperchlorate perchloric acid, nickel(II) salt
French français diperchlorate de nickel acide perchlorique, sel de nickel(II)
Croatian hrvatski niklov diperklorat perklorna kiselina, niklova(II) sol
Italian italiano diperclorato di nichel sale di nichel(II) dell’acido perclorico
Latvian latviešu niķeļa diperhlorāts perhlorskābe, niķeļa(II) sāls
Lithuanian lietuvių nikelio diperchloratas perchloro rūgšties nikelio (II) druska
Hungarian magyar nikkel-diperklorát perklórsav, nikkel(II) só
Maltese Malti diperklorat tan-nikil aċidu perkloriku, melħ tan-nikil(II)
Dutch Nederlands nikkeldiperchloraat perchloorzuur, nikkel(II)zout
Polish polski dichloran(VII) niklu sól niklu(II) kwasu chlorowego(VII)
Portuguese português diperclorato de níquel sal de níquel(II) do ácido perclórico
Romanian română diperclorat de nichel acid percloric, sare de nichel(II)
Slovak slovenčina chloristan nikelnatý nikelnatá soľ kyseliny chloristej
Slovenian slovenščina nikljev diperklorat perklorova kislina, nikljeva(II) sol
Finnish suomi nikkelidiperkloraatti perkloorihappo, nikkeli[II]-suola
Swedish svenska nickeldiperklorat perklorsyra, nickel(II)salt

All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

Nickel perchlorate GHS label elements

Everything CLP Annex VI fixes for Nickel perchlorate, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS05 Corrosion pictogramGHS08 Health hazard pictogramGHS09 Environment pictogram

Danger

Nickel perchlorate

  • May cause cancer by inhalation.
  • Suspected of causing genetic defects <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
  • May damage the unborn child.
  • Causes damage to organs <or state all organs affected, if known> through prolonged or repeated exposure <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
  • Causes severe skin burns and eye damage.
  • May cause allergy or asthma symptoms or breathing difficulties if inhaled.
  • May cause an allergic skin reaction.
  • Very toxic to aquatic life.
  • Very toxic to aquatic life with long lasting effects.
  • Obtain special instructions before use.
  • Do not breathe dust/fume/gas/mist/vapours/spray.
  • Avoid breathing dust/fume/gas/mist/vapours/spray.
  • Do not eat, drink or smoke when using this product.
  • Contaminated work clothing should not be allowed out of the workplace.
  • Avoid release to the environment.
  • Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/
  • IF SWALLOWED:
  • IF exposed or concerned:
  • Immediately call a POISON CENTER/doctor/
  • Get medical advice/attention.
  • Get medical advice/attention if you feel unwell.
  • Do NOT induce vomiting.
  • If skin irritation or rash occurs:
  • Collect spillage.
  • Dispose of contents/container to

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open Nickel perchlorate in the GHS label constructor →

07 · Health hazards

Nickel perchlorate health hazards and exposure limits

Nickel perchlorate occupational exposure limits

US occupational exposure limits reported for Nickel perchlorate. PEL is enforceable (OSHA), REL is a recommendation (NIOSH), IDLH is the concentration at which escape becomes impossible without injury.
Limit Value Source
PEL 1.0 [mg/m3], as Ni Haz-Map, Information on Hazardous Chemicals and Occupational Diseases
IDLH 10.0 [mg/m3], as Ni Haz-Map, Information on Hazardous Chemicals and Occupational Diseases
IDLH NIOSH considers nickel metal and other compounds (as Ni) to be a potential occupational carcinogen. /Nickel metal and other compounds (as Ni)/ Hazardous Substances Data Bank (HSDB)

These are United States values. The European Union sets its own indicative and binding limits, and the figure that applies at a given workplace is the one in the local regulation — not the one shown here.

08 · Physical and chemical properties

Nickel perchlorate properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

Nickel perchlorate solubility

Property Value Conditions Source
Solubility SOLUBILITIES: 222.5 G/100 CC WATER AT 0 °C, 273.7 G/100 CC WATER AT 45 °C, SOL IN ALCOHOL, ACETONE, CHLOROFORM at 0 °C, HEXAHYDRATE HSDB

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

09 · Transport

Nickel perchlorate UN number and transport classification

Transport classification is a separate system from the GHS classification above. It decides how a package is marked and how a load may be carried; it does not follow from the workplace label, and the workplace label does not follow from it. The entries below are linked by CAS number, never by name.

The same CAS number is shipped under more than one UN number. Which entry applies follows from the form and the concentration of the consignment — read the proper shipping name, not the CAS.

Nickel perchlorate under UN 1802 — shipping name, class and packing group

Europe · ADR 2025, Table A

Proper shipping name (3.1.2) Class Classification code PG Labels (column 5)
PERCHLORIC ACID with not more than 50 % acid, by mass 8 CO1 II
  • ADR label model 8 — Corrosive substance
  • ADR label model 5.1 — Oxidizing substance
8, 5.1

Source: ADR 2025, Table A of Chapter 3.2 · ECE/TRANS/352 Vol. I (UNECE). Class 8 is “Corrosive substances” (ADR 2.1.1.1).

Proper shipping name (column 2) Class or division PG Labels (column 6)
Perchloric acid with not more than 50 percent acid by mass 8 II
  • US DOT CORROSIVE label (§172.442)
  • US DOT OXIDIZER label (§172.426)
8, 5.1

Source: 49 CFR 172.101 Hazardous Materials Table · eCFR, revision 2026-08-03. Class 8 is “Corrosive material” (49 CFR 173.2).

Full UN 1802 entry — special provisions, packing instructions, quantity limits and the orange plate →

Nickel perchlorate under UN 1873 — shipping name, class and packing group

Europe · ADR 2025, Table A

Proper shipping name (3.1.2) Class Classification code PG Labels (column 5)
PERCHLORIC ACID with more than 50 % but not more than 72 % acid, by mass 5.1 OC1 I
  • ADR label model 5.1 — Oxidizing substance
  • ADR label model 8 — Corrosive substance
5.1, 8

Source: ADR 2025, Table A of Chapter 3.2 · ECE/TRANS/352 Vol. I (UNECE). Class 5.1 is “Oxidizing substances” (ADR 2.1.1.1).

Proper shipping name (column 2) Class or division PG Labels (column 6)
Perchloric acid with more than 50 percent but not more than 72 percent acid, by mass 5.1 I
  • US DOT OXIDIZER label (§172.426)
  • US DOT CORROSIVE label (§172.442)
5.1, 8

Source: 49 CFR 172.101 Hazardous Materials Table · eCFR, revision 2026-08-03. Class 5.1 is “Oxidizer” (49 CFR 173.2).

Full UN 1873 entry — special provisions, packing instructions, quantity limits and the orange plate →

10 · Questions

Nickel perchlorate — frequently asked questions

What is the CAS number of Nickel perchlorate?

The CAS number of Nickel perchlorate is 13637-71-3. Its EC number is 237-124-1.

What does a Nickel perchlorate label have to show?

Under CLP Annex VI the label for Nickel perchlorate carries the pictograms Corrosion, Health hazard and Environment and the signal word is Danger.

Is Nickel perchlorate flammable?

CLP Annex VI assigns Nickel perchlorate no flammability hazard class. That is not a statement that it cannot burn: the harmonised list only records the hazards that were assessed for it.

Is Nickel perchlorate a carcinogen?

Yes. CLP Annex VI classifies Nickel perchlorate as a category 1A or 1B carcinogen and assigns it H350i: may cause cancer by inhalation.

What is the exposure limit for Nickel perchlorate?

The US occupational exposure limit reported for Nickel perchlorate is 1.0 [mg/m3], as Ni (Haz-Map, Information on Hazardous Chemicals and Occupational Diseases). Limits differ by country: the EU sets its own indicative and binding values, and the figure that applies at a given workplace is the one in the local regulation.

Nearby

Substances next to Nickel perchlorate

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