Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

Sodium Chromate

Sodium Chromate is yellow orthorhombic crystals and is odorless.

CAS 7775-11-3 Danger

01 · Identification

What Sodium Chromate is

Sodium Chromate is yellow orthorhombic crystals and is odorless. It melts at 794 °C.

Under the GHS it carries the signal word Danger. It is classed as carcinogens.

02 · Identifiers

Sodium Chromate identifiers and molecular data

Sodium Chromate CAS number and EC number

CAS number7775-11-3
EC number231-889-5
Index number (CLP Annex VI)024-018-00-3

Sodium Chromate molecular formula and molecular weight

Chemical class Carcinogens

03 · GHS classification

Sodium Chromate hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

Sodium Chromate pictograms and signal word

Signal wordDanger

Sodium Chromate hazard class and category

GHS hazard classes Sodium Chromate falls into
Hazard class Category From code Pictogram
Acute toxicity - oral GHS chapter 3.1 Category 3 H301 GHS06
Acute toxicity - dermal GHS chapter 3.1 Category 4 H312 GHS07
Acute toxicity - inhalation GHS chapter 3.1 Category 1 or 2 H330 GHS06
Skin corrosion/irritation GHS chapter 3.2 Category 1A or 1B or 1C H314 GHS05
Respiratory sensitisation GHS chapter 3.4 Category 1 or 1A or 1B H334 GHS08
Skin sensitisation GHS chapter 3.4 Category 1 or 1A or 1B H317 GHS07
Germ cell mutagenicity GHS chapter 3.5 Category 1A or 1B H340 GHS08
Carcinogenicity GHS chapter 3.6 Category 1A or 1B H350 GHS08
Specific target organ toxicity - repeated exposure GHS chapter 3.9 Category 1 H372 GHS08
Hazardous to the aquatic environment - acute GHS chapter 4.1 Category 1 H400 GHS09
Hazardous to the aquatic environment - chronic GHS chapter 4.1 Category 1 H410 GHS09

Where two values are shown with “or”, the hazard statement is shared by more than one category or by more than one class, and the code alone does not say which. H272, for example, belongs to oxidising liquids and to oxidising solids — the physical state decides. The binding answer for a specific entry is in the CLP Annex VI table itself.

Sodium Chromate hazard statements (H-codes)

Hazard statements assigned to Sodium Chromate
CodeHazard statement
H350 May cause cancer <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
H340 May cause genetic defects <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
H360FD May damage fertility. May damage the unborn child.
H330 Fatal if inhaled.
H301 Toxic if swallowed.
H312 Harmful in contact with skin.
H372 Causes damage to organs <or state all organs affected, if known> through prolonged or repeated exposure <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
H314 Causes severe skin burns and eye damage.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H317 May cause an allergic skin reaction.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.

This page lists only the codes assigned to Sodium Chromate. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for Sodium Chromate

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of Sodium Chromate issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

04 · Precautionary statements

Sodium Chromate precautionary statements

CLP Annex VI assigns 22 precautionary statements to Sodium Chromate. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Disposal

What has to happen to the contents and the empty container.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

Sodium Chromate name in 23 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български натриев хромат
Spanish español Cromato de sodio
Czech čeština chroman sodný
Danish dansk natriumchromat
German Deutsch Natriumchromat
Estonian eesti naatriumkromaat
Greek ελληνικά χρωμικό νάτριο
English English sodium chromate
French français chromate de sodium
Croatian hrvatski natrijev kromat
Italian italiano cromato di sodio
Latvian latviešu nātrija hromāts
Lithuanian lietuvių natrio chromatas
Hungarian magyar nátrium-kromát
Maltese Malti kromat tas-sodju
Dutch Nederlands natriumchromaat
Polish polski chromian(VI) sodu chromian(VI) disodu
Portuguese português cromato de sódio
Romanian română cromat de sodiu
Slovak slovenčina chróman sodný
Slovenian slovenščina natrijev kromat
Finnish suomi natriumkromaatti
Swedish svenska natriumkromat

All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

Sodium Chromate GHS label elements

Everything CLP Annex VI fixes for Sodium Chromate, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS06 Skull and crossbones pictogramGHS08 Health hazard pictogramGHS05 Corrosion pictogramGHS09 Environment pictogram

Danger

Sodium Chromate

  • May cause cancer <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
  • May cause genetic defects <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
  • May damage fertility. May damage the unborn child.
  • Fatal if inhaled.
  • Toxic if swallowed.
  • Harmful in contact with skin.
  • Causes damage to organs <or state all organs affected, if known> through prolonged or repeated exposure <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
  • Causes severe skin burns and eye damage.
  • May cause allergy or asthma symptoms or breathing difficulties if inhaled.
  • May cause an allergic skin reaction.
  • Very toxic to aquatic life.
  • Very toxic to aquatic life with long lasting effects.
  • Obtain special instructions before use.
  • Do not breathe dust/fume/gas/mist/vapours/spray.
  • Avoid breathing dust/fume/gas/mist/vapours/spray.
  • Do not eat, drink or smoke when using this product.
  • Use only outdoors or in a well-ventilated area.
  • Contaminated work clothing should not be allowed out of the workplace.
  • Avoid release to the environment.
  • Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/
  • IF SWALLOWED:
  • IF ON SKIN:
  • IF INHALED:
  • IF exposed or concerned:
  • Immediately call a POISON CENTER/doctor/
  • Call a POISON CENTER/doctor/ if you feel unwell.
  • Get medical advice/attention.
  • Get medical advice/attention if you feel unwell.
  • Rinse mouth.
  • Do NOT induce vomiting.
  • If skin irritation or rash occurs:
  • Wash with plenty of water/
  • Collect spillage.
  • Dispose of contents/container to

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open Sodium Chromate in the GHS label constructor →

07 · Health hazards

Sodium Chromate health hazards and exposure limits

Sodium Chromate hazard summary

A corrosive substance that can cause injury to the skin, eyes, and respiratory tract; Can be absorbed through skin; May cause skin sensitization and asthma after prolonged contact; May cause kidney and liver injury; May cause perforated nasal septum; [ICSC] Can cause burns; Very toxic by inhalation; May cause skin and respiratory sensitization after prolonged contact; [eChemPortal: ESIS] See Chromium and linked occupational diseases.

Source: Haz-Map, Information on Hazardous Chemicals and Occupational Diseases

Sodium Chromate carcinogenicity classification

Evaluation: There is sufficient evidence in humans for the carcinogenicity of chromium(VI) compounds. Chromium(VI) compounds cause cancer of the lung. Also positive associations have been observed between exposure to Chromium(IV) compounds and cancer of the nose and nasal sinuses. There is sufficient evidence in experimental animals for the carcinogenicity of chromium(VI) compounds. Chromium(VI) compounds are carcinogenic to humans (Group 1). /Chromium(VI) compounds/

Source: Hazardous Substances Data Bank (HSDB)

Chromium Hexavalent Compounds: known to be human carcinogens. /Chromium hexavalent compound/

Source: Hazardous Substances Data Bank (HSDB)

An IARC group and a CLP classification answer different questions. IARC judges whether the evidence for cancer in humans is strong enough; CLP Annex VI is the legally binding EU classification. A substance can carry one and not the other.

Sodium Chromate occupational exposure limits

US occupational exposure limits reported for Sodium Chromate. PEL is enforceable (OSHA), REL is a recommendation (NIOSH), IDLH is the concentration at which escape becomes impossible without injury.
Limit Value Source
PEL 0.005 [mg/m3], as Cr(VI) Haz-Map, Information on Hazardous Chemicals and Occupational Diseases
IDLH 15 mg Cr(VI)/m3 ; A potential occupational carcinogen. (NIOSH, 2024) CAMEO Chemicals
IDLH 250 mg/cu m (as Cr(II)). /Chromium(II) compounds (as Cr)/ Hazardous Substances Data Bank (HSDB)
IDLH 25 mg/cu m (as Cr(III)). /Chromium(III) compounds (as Cr)/ Hazardous Substances Data Bank (HSDB)

These are United States values. The European Union sets its own indicative and binding limits, and the figure that applies at a given workplace is the one in the local regulation — not the one shown here.

08 · Physical and chemical properties

Sodium Chromate properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

Sodium Chromate melting point

Property Value Conditions Source
Melting point 794 °C (1461.2 °F) HSDB
762 °C (1403.6 °F) ICSC

Sodium Chromate density

Property Value Conditions Source
Density 2.7 g/cm³ ICSC
2.723 g/cm³ at 25 °C HSDB

Sodium Chromate solubility

Property Value Conditions Source
Solubility In water, 44.3 wt% at 20 °C at 20 °C HSDB
87.6 g/100 g water at 25 °C at 25 °C HSDB
3.44 g/L methanol at 25 °C at 25 °C HSDB

Sodium Chromate corrosivity

Property Value Conditions Source
Corrosivity Corrosive because of oxidizing potency. Chromate salts HSDB

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

09 · Handling and storage

Sodium Chromate storage and handling

Sodium Chromate safe storage

Provision to contain effluent from fire extinguishing. Separated from combustible substances, reducing agents and food and feedstuffs. Dry. Well closed. Store in an area without drain or sewer access.

Source: ILO-WHO International Chemical Safety Cards (ICSCs)

Sodium Chromate storage conditions

Keep container tightly closed in a dry and well-ventilated place. Hygroscopic. Storage class (TRGS 510): Non-combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials.

Source: Hazardous Substances Data Bank (HSDB)

Sodium Chromate incompatible materials

Incompatible materials: Strong reducing agents

Source: Hazardous Substances Data Bank (HSDB)

Sodium Chromate reactivity

SODIUM CHROMATE is a strong oxidizing agent. Incompatible with strong acids. (NTP, 1992). Contact with combustible materials may lead to fires. Toxic chromium oxide fumes may form in fire (USCG, 1999).

Source: CAMEO Chemicals

Planning storage for a mix of chemicals? Check Sodium Chromate in the storage compatibility matrix →

10 · Questions

Sodium Chromate — frequently asked questions

What is the CAS number of Sodium Chromate?

The CAS number of Sodium Chromate is 7775-11-3. Its EC number is 231-889-5.

What does a Sodium Chromate label have to show?

Under CLP Annex VI the label for Sodium Chromate carries the pictograms Skull and crossbones, Health hazard, Corrosion and Environment and the signal word is Danger.

Is Sodium Chromate flammable?

CLP Annex VI assigns Sodium Chromate no flammability hazard class. That is not a statement that it cannot burn: the harmonised list only records the hazards that were assessed for it.

Is Sodium Chromate a carcinogen?

Yes. CLP Annex VI classifies Sodium Chromate as a category 1A or 1B carcinogen and assigns it H350: may cause cancer.

What is the exposure limit for Sodium Chromate?

The US occupational exposure limit reported for Sodium Chromate is 0.005 [mg/m3], as Cr(VI) (Haz-Map, Information on Hazardous Chemicals and Occupational Diseases). Limits differ by country: the EU sets its own indicative and binding values, and the figure that applies at a given workplace is the one in the local regulation.

What is the melting point of Sodium Chromate?

The melting point reported for Sodium Chromate is 794 °C (1461.2 °F) (HSDB).

How should Sodium Chromate be stored?

Keep container tightly closed in a dry and well-ventilated place. Hygroscopic. Storage class (TRGS 510): Non-combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials. (Hazardous Substances Data Bank (HSDB))

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