Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

Toluene-2,4-diammonium sulphate

Toluene-2,4-diammonium sulphate is a chemical substance with the molecular formula C7H12N2O4S.

CAS 65321-67-7 C7H12N2O4S 220.25 g/mol Danger

01 · Identification

What Toluene-2,4-diammonium… is

Toluene-2,4-diammonium sulphate is a chemical substance with the molecular formula C7H12N2O4S. Its molecular formula is C7H12N2O4S and its molecular weight is 220.25 g/mol.

Under the GHS it carries the signal word Danger.

02 · Identifiers

Toluene-2,4-diammonium… identifiers and molecular data

Toluene-2,4-diammonium… CAS number and EC number

CAS number65321-67-7
EC number265-697-8
Index number (CLP Annex VI)612-126-00-9

Toluene-2,4-diammonium… molecular formula and molecular weight

Molecular formulaC7H12N2O4S
Molecular weight220.25 g/mol

Other names for Toluene-2,4-diammonium…

  • 4-methyl-m-phenylenediamine sulfate

03 · GHS classification

Toluene-2,4-diammonium… hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

Toluene-2,4-diammonium… pictograms and signal word

Signal wordDanger

Toluene-2,4-diammonium… hazard class and category

GHS hazard classes Toluene-2,4-diammonium… falls into
Hazard class Category From code Pictogram
Acute toxicity - oral GHS chapter 3.1 Category 3 H301 GHS06
Acute toxicity - dermal GHS chapter 3.1 Category 4 H312 GHS07
Serious eye damage/eye irritation GHS chapter 3.3 Category 2A H319 GHS07
Skin sensitisation GHS chapter 3.4 Category 1 or 1A or 1B H317 GHS07
Carcinogenicity GHS chapter 3.6 Category 1A or 1B H350 GHS08
Hazardous to the aquatic environment - chronic GHS chapter 4.1 Category 2 H411 GHS09

Where two values are shown with “or”, the hazard statement is shared by more than one category or by more than one class, and the code alone does not say which. H272, for example, belongs to oxidising liquids and to oxidising solids — the physical state decides. The binding answer for a specific entry is in the CLP Annex VI table itself.

Toluene-2,4-diammonium… hazard statements (H-codes)

Hazard statements assigned to Toluene-2,4-diammonium…
CodeHazard statement
H350 May cause cancer <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
H301 Toxic if swallowed.
H312 Harmful in contact with skin.
H319 Causes serious eye irritation.
H317 May cause an allergic skin reaction.
H411 Toxic to aquatic life with long lasting effects.

This page lists only the codes assigned to Toluene-2,4-diammonium…. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for Toluene-2,4-diammonium…

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of Toluene-2,4-diammonium… issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

04 · Precautionary statements

Toluene-2,4-diammonium… precautionary statements

CLP Annex VI assigns 21 precautionary statements to Toluene-2,4-diammonium…. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Disposal

What has to happen to the contents and the empty container.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

Toluene-2,4-diammonium… name in 23 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български толуен-2,4-диамониев сулфат 4-метил- m -фенилендиаминсулфат
Spanish español Sulfato de tolueno-2,4-diamonio sulfato de 4-metil- m -fenilendiamina
Czech čeština 4-methylbenzen-1,3-diamin-sulfát 4-methyl-1,3-fenylendiamin-sulfát
Danish dansk toluen-2,4-diammoniumsulfat 4-methyl- m -phenylendiamin sulfat
German Deutsch Toluol-2,4-diammoniumsulfat 4-Methyl-m-phenylendiaminsulfatToluylen-2,4-diaminsulfat
Estonian eesti tolueen-2,4-diammooniumsulfaat 4-metüül- m -fenüleendiamiinsulfaat
Greek ελληνικά θειικό τολουολο-2,4-διαμμώνιο θειική 4-μεθυλο- m -φαινυλενοδιαμίνη
English English toluene-2,4-diammonium sulphate 4-methyl-m-phenylenediamine sulfate
French français sulfate de toluène-2,4-diammonium sulfate de 4-méthyl-m-phénylènediamine
Croatian hrvatski toluen-2,4-diamonij-sulfat 4-metil- m -fenilendiamin sulfat
Italian italiano solfato di toluen-2,4-diammonio 4-metil-m-fenilendiamina solfato
Latvian latviešu toluola-2,4-diamonija sulfāts 4-metil-m-fenilēndiamīna sulfāts
Lithuanian lietuvių toluen-2,4-diamonio sulfatas 4-metil-m-fenilendiamino sulfatas
Hungarian magyar toluol-2,4-diammónium-szulfát 4-metil-m-feniléndiamin-szulfát
Maltese Malti sulfat tat-toluwen-2,4-dammonju sulfat ta’ 4-metil-m-fenilenediammina
Dutch Nederlands tolueen-2,4-diammoniumsulfaat 4-methyl- m -fenyleendiaminesulfaat
Polish polski siarczan(VI) tolueno-2,4-diamoniowy siarczan(VI) 4-metylo- m -fenylenodiaminysiarczan(VI) 4-metylo-1,3-fenylenodiaminy
Portuguese português sulfato de tolueno-2,4-diamónio sulfato de 4-metil- m -fenilenodiamina
Romanian română sulfat de toluen-2,4-diamoniu sulfat de 4-metil-m-fenilendiamină
Slovak slovenčina 4-metylbenzén-1,3-diamónium-sulfát 4-metyl-1,3-fenyléndiamónium-sulfát
Slovenian slovenščina toluen 2,4-diamonijev sulfat 4-metil-m-fenilendiamin sulfat
Finnish suomi tolueeni-2,4-diammoniumsulfaatti 4-metyyli-m-fenyleenidiamiinisulfaatti
Swedish svenska toluen-2,4-diammonium sulfat 4-metyl-m-fenylendiaminsulfat

All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

Toluene-2,4-diammonium… GHS label elements

Everything CLP Annex VI fixes for Toluene-2,4-diammonium…, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS06 Skull and crossbones pictogramGHS08 Health hazard pictogramGHS09 Environment pictogram

Danger

Toluene-2,4-diammonium…

  • May cause cancer <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
  • Toxic if swallowed.
  • Harmful in contact with skin.
  • Causes serious eye irritation.
  • May cause an allergic skin reaction.
  • Toxic to aquatic life with long lasting effects.
  • Obtain special instructions before use.
  • Avoid breathing dust/fume/gas/mist/vapours/spray.
  • Wash thoroughly after handling.
  • Do not eat, drink or smoke when using this product.
  • Contaminated work clothing should not be allowed out of the workplace.
  • Avoid release to the environment.
  • Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/
  • IF SWALLOWED:
  • IF ON SKIN:
  • IF IN EYES:
  • IF exposed or concerned:
  • Immediately call a POISON CENTER/doctor/
  • Call a POISON CENTER/doctor/ if you feel unwell.
  • Get medical advice/attention.
  • Rinse mouth.
  • If skin irritation or rash occurs:
  • If eye irritation persists:
  • Remove contact lenses, if present and easy to do. Continue rinsing.
  • Wash with plenty of water/
  • Collect spillage.
  • Dispose of contents/container to

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open Toluene-2,4-diammonium… in the GHS label constructor →

07 · Questions

Toluene-2,4-diammonium… — frequently asked questions

What is the CAS number of Toluene-2,4-diammonium…?

The CAS number of Toluene-2,4-diammonium… is 65321-67-7. Its EC number is 265-697-8.

What is the chemical formula of Toluene-2,4-diammonium…?

The molecular formula of Toluene-2,4-diammonium… is C7H12N2O4S and its molecular weight is 220.25 g/mol.

What does a Toluene-2,4-diammonium… label have to show?

Under CLP Annex VI the label for Toluene-2,4-diammonium… carries the pictograms Skull and crossbones, Health hazard and Environment and the signal word is Danger.

Is Toluene-2,4-diammonium… flammable?

CLP Annex VI assigns Toluene-2,4-diammonium… no flammability hazard class. That is not a statement that it cannot burn: the harmonised list only records the hazards that were assessed for it.

Is Toluene-2,4-diammonium… a carcinogen?

Yes. CLP Annex VI classifies Toluene-2,4-diammonium… as a category 1A or 1B carcinogen and assigns it H350: may cause cancer.

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