Substance profile
Tolylfluanid
Tolylfluanid is colorless crystals and is odorless.
01 · Identification
What Tolylfluanid is
Tolylfluanid is colorless crystals and is odorless. Its molecular formula is C10H13Cl2FN2O2S2 and its molecular weight is 347.3 g/mol. It melts at 93 °C.
Under the GHS it carries the signal word Danger.
02 · Identifiers
Tolylfluanid identifiers and molecular data
Tolylfluanid CAS number and EC number
Tolylfluanid molecular formula and molecular weight
Other names for Tolylfluanid
- tolylfluanid (ISO)
- dichloro-N- [(dimethylamino)sulphonyl]fluoro-N-(p-tolyl)methanesulphenamide
- [containing ≥ 0.1 % (w/w) of particles with an aerodynamic diameter of below 50 µm]
03 · GHS classification
Tolylfluanid hazard classification
Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.
Tolylfluanid pictograms and signal word
Tolylfluanid hazard class and category
| Hazard class | Category | From code | Pictogram |
|---|---|---|---|
| Acute toxicity - inhalation GHS chapter 3.1 | Category 1 or 2 | H330 | GHS06 |
| Skin corrosion/irritation GHS chapter 3.2 | Category 2 | H315 | GHS07 |
| Serious eye damage/eye irritation GHS chapter 3.3 | Category 2A | H319 | GHS07 |
| Skin sensitisation GHS chapter 3.4 | Category 1 or 1A or 1B | H317 | GHS07 |
| Specific target organ toxicity - single exposure GHS chapter 3.8 | Category 3 | H335 | GHS07 |
| Specific target organ toxicity - repeated exposure GHS chapter 3.9 | Category 1 | H372 | GHS08 |
| Hazardous to the aquatic environment - acute GHS chapter 4.1 | Category 1 | H400 | GHS09 |
Where two values are shown with “or”, the hazard statement is shared by more than one category or by more than one class, and the code alone does not say which. H272, for example, belongs to oxidising liquids and to oxidising solids — the physical state decides. The binding answer for a specific entry is in the CLP Annex VI table itself.
Tolylfluanid hazard statements (H-codes)
| Code | Hazard statement |
|---|---|
| H330 | Fatal if inhaled. |
| H335 | May cause respiratory irritation. |
| H372 | Causes damage to organs <or state all organs affected, if known> through prolonged or repeated exposure <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>. |
| H315 | Causes skin irritation. |
| H319 | Causes serious eye irritation. |
| H317 | May cause an allergic skin reaction. |
| H400 | Very toxic to aquatic life. |
This page lists only the codes assigned to Tolylfluanid. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.
Safety Data Sheet
Getting an SDS for Tolylfluanid
A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of Tolylfluanid issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.
04 · Precautionary statements
Tolylfluanid precautionary statements
CLP Annex VI assigns 21 precautionary statements to Tolylfluanid. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.
Prevention
What to do before and during handling so the hazard never happens.
Response
What to do once exposure, spillage or fire has already happened.
Disposal
What has to happen to the contents and the empty container.
Reading the notation. … is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.
05 · Names in the regulation
Tolylfluanid name in 23 EU languages
CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.
| Language | Name in CLP Annex VI Part 3 |
|---|---|
| Bulgarian български | толилфлуанид (ISO) N -[(диметиламино)сулфонил]- N -( p -толил)флуородихлорометансулфенамид |
| Spanish español | Tolilfluanid (ISO) dicloro- N -[(dimetilamino)sulfonil]fluoro- N -( p -tolil)metanosulfenamida |
| Czech čeština | tolylfluanid (ISO) N -[(dichlorfluormethyl)sulfanyl]- N',N' -dimethyl- N -(4- methylfenyl)sulfonamid |
| Danish dansk | This edition prints the paired entry’s qualifier here. The Danish edition prints "< 0,1 % (w/w) of respirable particles", the qualifier of the paired entry 613-116-01-4. Every other edition prints "≥ 0,1 %" for this entry. The Danish edition also drops the square brackets that mark the qualifier. Regulation (EU) 2018/669, OJ L 115, 4.5.2018, p. 467 tolylfluanid (ISO) dichlor-N-[(dimethylamino)sulfonyl]fluor- N -( p -tolyl)methansulfenamid indeholdende < 0,1 % (w/w) partikler med en aerodynamisk diameter på mindre end 50 μm |
| German Deutsch | Tolylfluanid (ISO) Dichlor- N -[(dimethylamino)sulphonyl]fluor- N -( p -tolyl)methansulfonamid |
| Estonian eesti | tolüülfluaniid (ISO) dikloro- N -[(dimetüülamino)sulfonüül]fluoro- N -( p -tolüül)metaansulfeenamiid |
| Greek ελληνικά | tolylfluanid (τολυλοφλουανίδη) (ISO) διχλωρο- N -[(διμεθυλαμινο)σουλφονυλο]φθορο- N -( p -τολυλο)μεθανοσουλφεναμίδιο |
| English English | tolylfluanid (ISO) dichloro- N -[(dimethylamino)sulphonyl]fluoro- N -( p -tolyl)methanesulphenamide |
| French français | tolylfluanide (ISO) dichloro- N -[(diméthylamino)sulfonyl]fluoro- N -( p -tolyl)méthanesulfénamide |
| Croatian hrvatski | tolilfluanid (ISO) diklor- N -[(dimetilamino)sulfonil]fluor- N -( p -tolil)metansulfenamid |
| Italian italiano | tolilfluanide (ISO) dicloro- N -[(dimetilammino)solfonil]fluoro- N -( p -tolil)metansolfenammide |
| Latvian latviešu | tolilfluanīds (ISO) dihlor- N -[(dimetilamino)sulfonil]fluor- N -( p -tolil)metānsulfenamīds |
| Lithuanian lietuvių | tolilfluanidas (ISO) dichlor-N-[(dimetilamino)sulphonil]fluor-N-(p-tolil)metansulfenamidas |
| Hungarian magyar | tolilfluanid (ISO) diklór- N -[(dimetilamino)szulfonil]fluor- N -( p -tolil)metánszulfénamid |
| Maltese Malti | tolilfluwanid (ISO) dikloro- N -[(dimetilammino)sulfonil]fluworo- N -( p -tolil)metanesulfenammid |
| Dutch Nederlands | tolylfluanide (ISO) dichloor- N -[(dimethylamino)sulfonyl]fluor- N -( p -tolyl)methaansulfenamide |
| Polish polski | tolilofluanid (ISO) dichloro- N -[(dimetyloamino)sulfonylo]fluoro-N-( p -tolilo)metanosulfenoamid |
| Portuguese português | tolilfluanida (ISO) dicloro- N -[(dimetilamino)sulfonil]fluoro- N -( p -tolil)metanossulfenamida |
| Romanian română | tolilfluanid (ISO) dicloro- N -[(dimetilamino)sulfonil]fluoro- N -( p -tolil)-metansulfenamidă |
| Slovak slovenčina | tolylfluanid (ISO) N -[(dimetylamino)sulfonyl]fluórdichlór- N -( para -tolyl)metánsulfénamid |
| Slovenian slovenščina | tolilfluanid (ISO) dikloro- N -[(dimetilamino)sulfonil]fluoro- N -( p -tolil)metansulfenamid |
| Finnish suomi | tolyylifluanidi (ISO) dikloori- N -[(dimetyyliamino)sulfonyyli]fluori- N -( p -tolyyli)metaanisulfenamidi |
| Swedish svenska | tolylfluanid (ISO) diklor- N -[(dimetylamino)sulfonyl]fluor- N -( p -tolyl)metansulfenamid |
One or more lines above are flagged. In those language editions the Regulation as published in the Official Journal prints something that the rest of the same row contradicts — a name belonging to a different entry, or the qualifier of a paired entry. Each flag cites the amending act and the Official Journal page, so the wording can be checked at source. The lines are reproduced as printed, because Art. 18(2) points at Annex VI and not at our reading of it; the note beside each one says what the row’s own EC and CAS numbers identify.
All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.
06 · Label elements
Tolylfluanid GHS label elements
Everything CLP Annex VI fixes for Tolylfluanid, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.
Danger
Tolylfluanid
- Fatal if inhaled.
- May cause respiratory irritation.
- Causes damage to organs <or state all organs affected, if known> through prolonged or repeated exposure <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
- Causes skin irritation.
- Causes serious eye irritation.
- May cause an allergic skin reaction.
- Very toxic to aquatic life.
- Do not breathe dust/fume/gas/mist/vapours/spray.
- Avoid breathing dust/fume/gas/mist/vapours/spray.
- Wash … thoroughly after handling.
- Do not eat, drink or smoke when using this product.
- Use only outdoors or in a well-ventilated area.
- Contaminated work clothing should not be allowed out of the workplace.
- Avoid release to the environment.
- Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/…
- IF ON SKIN:
- IF INHALED:
- IF IN EYES:
- Immediately call a POISON CENTER/doctor/…
- Get medical advice/attention.
- Get medical advice/attention if you feel unwell.
- If skin irritation occurs:
- If skin irritation or rash occurs:
- If eye irritation persists:
- Remove contact lenses, if present and easy to do. Continue rinsing.
- Wash with plenty of water/…
- Collect spillage.
- Dispose of contents/container to …
Supplier name, address and telephone number· Product identifier·Nominal quantity
Need this as an actual label? Open Tolylfluanid in the GHS label constructor →
07 · Health hazards
Tolylfluanid health hazards and exposure limits
Tolylfluanid hazard summary
Likely to be carcinogenic to humans; Target organs are bones & teeth, liver, and thyroid; [Reference #1] Irritating to the skin and has sensitizing properties; Target organs after acute exposure are liver, kidney, and thyroid gland; Causes severe respiratory irritation after inhalation of particles < 50 microns; Not genotoxic; Not carcinogenic; No evidence of reproductive or CNS toxicity; [Reference #2] A skin, eye, and respiratory tract irritant; May cause skin sensitization; [eChemPortal: ESIS] An irritant; [MSDSonline]
Source: Haz-Map, Information on Hazardous Chemicals and Occupational Diseases
Tolylfluanid carcinogenicity classification
Cancer Classification: Likely to be Carcinogenic to Humans
Source: Hazardous Substances Data Bank (HSDB)
An IARC group and a CLP classification answer different questions. IARC judges whether the evidence for cancer in humans is strong enough; CLP Annex VI is the legally binding EU classification. A substance can carry one and not the other.
08 · Physical and chemical properties
Tolylfluanid properties
Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.
Tolylfluanid boiling point
| Property | Value | Conditions | Source |
|---|---|---|---|
| Boiling point | Decomposes on distillation | decomposes | HSDB |
Tolylfluanid melting point
| Property | Value | Conditions | Source |
|---|---|---|---|
| Melting point | 93 °C (199.4 °F) | HSDB |
Tolylfluanid density
| Property | Value | Conditions | Source |
|---|---|---|---|
| Density | 1.52 g/cm³ | HSDB |
Tolylfluanid solubility
| Property | Value | Conditions | Source |
|---|---|---|---|
| Solubility | Solubility in heptane 54, dichloromethane >250, isopropanol 22, xylene 190 (all in g/L, 20 °C) | at 20 °C | HSDB |
| In water, 0.9 mg/L at 20 °C | at 20 °C | HSDB |
Tolylfluanid vapor pressure
| Property | Value | Conditions | Source |
|---|---|---|---|
| Vapor pressure | 0.0000015 mmHg | at 20 °C | HSDB |
| 0.0000015 mmHg | Haz-Map |
Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.
09 · Source notes
Further notes on Tolylfluanid
These are descriptions rather than measured values, so they are kept out of the table above and quoted here with the source that reported them.
Solubility
Solubility in toluene: 0.9 g/mL (20 °C), 1.06 g/mL (25 °C), 1.2 g/mL (30 °C); hexane: 0.03 g/mL (20 °C), 0.05 g/mL (25 °C), 0.05 g/mL (30 °C); miscible in all proportions with acetone, ethanol, ethyl acetate, methylene chloride.
Source: HSDB
10 · Handling and storage
Tolylfluanid storage and handling
Tolylfluanid incompatible materials
Incompatible with liquid insecticides and with alkaline substances (e.g. Bordeaux mixture, lime sulfur).
Source: Hazardous Substances Data Bank (HSDB)
Planning storage for a mix of chemicals? Check Tolylfluanid in the storage compatibility matrix →
11 · Questions
Tolylfluanid — frequently asked questions
What is the CAS number of Tolylfluanid?
The CAS number of Tolylfluanid is 731-27-1. Its EC number is 211-986-9.
What is the chemical formula of Tolylfluanid?
The molecular formula of Tolylfluanid is C10H13Cl2FN2O2S2 and its molecular weight is 347.3 g/mol.
What does a Tolylfluanid label have to show?
Under CLP Annex VI the label for Tolylfluanid carries the pictograms Skull and crossbones, Health hazard and Environment and the signal word is Danger.
Is Tolylfluanid flammable?
CLP Annex VI assigns Tolylfluanid no flammability hazard class. That is not a statement that it cannot burn: the harmonised list only records the hazards that were assessed for it.
Is Tolylfluanid a carcinogen?
CLP Annex VI records no harmonised carcinogenicity classification for Tolylfluanid. Annex VI is a list of agreed classifications, not a list of substances found safe, so this is an absence of a classification rather than a clean bill of health.
What is the boiling point of Tolylfluanid?
The boiling point reported for Tolylfluanid is Decomposes on distillation, decomposes (HSDB).
What is the melting point of Tolylfluanid?
The melting point reported for Tolylfluanid is 93 °C (199.4 °F) (HSDB).
Nearby
Substances next to Tolylfluanid
Keep going: substances starting with T, or search the whole database by name, CAS number, pictogram or signal word.