Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

Nickel sulfamate

Nickel sulfamate: liquid; Liquid; Other Solid.

CAS 13770-89-3 H4N2NiO6S2 250.87 g/mol Danger

01 · Identification

What Nickel sulfamate is

Nickel sulfamate: liquid; Liquid; Other Solid. Its molecular formula is H4N2NiO6S2 and its molecular weight is 250.87 g/mol.

Under the GHS it carries the signal word Danger.

02 · Identifiers

Nickel sulfamate identifiers and molecular data

Nickel sulfamate CAS number and EC number

CAS number13770-89-3
EC number237-396-1
Index number (CLP Annex VI)028-018-00-4

Nickel sulfamate molecular formula and molecular weight

Molecular formulaH4N2NiO6S2
Molecular weight250.87 g/mol

Other names for Nickel sulfamate

  • nickel bis(sulfamidate)

03 · GHS classification

Nickel sulfamate hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

Nickel sulfamate pictograms and signal word

Signal wordDanger

Nickel sulfamate hazard class and category

GHS hazard classes Nickel sulfamate falls into
Hazard class Category From code Pictogram
Acute toxicity - oral GHS chapter 3.1 Category 4 H302 GHS07
Respiratory sensitisation GHS chapter 3.4 Category 1 or 1A or 1B H334 GHS08
Skin sensitisation GHS chapter 3.4 Category 1 or 1A or 1B H317 GHS07
Germ cell mutagenicity GHS chapter 3.5 Category 2 H341 GHS08
Specific target organ toxicity - repeated exposure GHS chapter 3.9 Category 1 H372 GHS08
Hazardous to the aquatic environment - acute GHS chapter 4.1 Category 1 H400 GHS09
Hazardous to the aquatic environment - chronic GHS chapter 4.1 Category 1 H410 GHS09

Where two values are shown with “or”, the hazard statement is shared by more than one category or by more than one class, and the code alone does not say which. H272, for example, belongs to oxidising liquids and to oxidising solids — the physical state decides. The binding answer for a specific entry is in the CLP Annex VI table itself.

Nickel sulfamate hazard statements (H-codes)

Hazard statements assigned to Nickel sulfamate
CodeHazard statement
H350i May cause cancer by inhalation.
H341 Suspected of causing genetic defects <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
H360D May damage the unborn child.
H302 Harmful if swallowed.
H372 Causes damage to organs <or state all organs affected, if known> through prolonged or repeated exposure <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H317 May cause an allergic skin reaction.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.

This page lists only the codes assigned to Nickel sulfamate. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for Nickel sulfamate

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of Nickel sulfamate issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

04 · Precautionary statements

Nickel sulfamate precautionary statements

CLP Annex VI assigns 16 precautionary statements to Nickel sulfamate. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Disposal

What has to happen to the contents and the empty container.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

Nickel sulfamate name in 23 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български никелов бис(сулфамидат) никелов сулфамат
Spanish español Bis(sulfamidato) de níquel sulfamato de níquel
Czech čeština nikl-bis(sulfamidát) nikl-sulfamát
Danish dansk nikkelbis(sulfamidat) nikkelsulfamat
German Deutsch Nickel-bis(sulfamidat) Nickelsulfamat
Estonian eesti nikkelbis(sulfamidaat) nikkelsulfamaat
Greek ελληνικά δις(σουλφαμιδικό) νικέλιο σουλφαμικό νικέλιο
English English nickel bis(sulfamidate) nickel sulfamate
French français bis(sulfamidate) de nickel sulfamate de nickel
Croatian hrvatski niklov bis(sulfamidat) niklov sulfamat
Italian italiano bis(solfamidato) di nichel solfammato di nichel
Latvian latviešu niķeļa bis(sulfamidāts) niķeļa sulfamāts
Lithuanian lietuvių nikelio disulfamidatas nikelio sulfamatas
Hungarian magyar nikkel-bisz(szulfamidát) nikkel-szulfamát
Maltese Malti bis(sulfammidat) tan-nikil sulfamat tan-nikil
Dutch Nederlands nikkelbis(sulfamidaat) nikkelsulfamaat
Polish polski bis(sulfamidian) niklu amidosulfonian niklu
Portuguese português Bis(sulfamidato) de níquel sulfamato de níquel
Romanian română bis(sulfamidat) de nichel sulfamat de nichel
Slovak slovenčina bis(amidosíran) nikelnatý nikélium-bis(sulfamát)
Slovenian slovenščina nikljev bis(sulfamidat) nikljev sulfamat
Finnish suomi Nikkelibis(sulfamidaatti) nikkelisulfamaatti
Swedish svenska nickelbis(sulfamidat) nickelsulfamat

All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

Nickel sulfamate GHS label elements

Everything CLP Annex VI fixes for Nickel sulfamate, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS07 Exclamation mark pictogramGHS08 Health hazard pictogramGHS09 Environment pictogram

Danger

Nickel sulfamate

  • May cause cancer by inhalation.
  • Suspected of causing genetic defects <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
  • May damage the unborn child.
  • Harmful if swallowed.
  • Causes damage to organs <or state all organs affected, if known> through prolonged or repeated exposure <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
  • May cause allergy or asthma symptoms or breathing difficulties if inhaled.
  • May cause an allergic skin reaction.
  • Very toxic to aquatic life.
  • Very toxic to aquatic life with long lasting effects.
  • Obtain special instructions before use.
  • Do not breathe dust/fume/gas/mist/vapours/spray.
  • Avoid breathing dust/fume/gas/mist/vapours/spray.
  • Do not eat, drink or smoke when using this product.
  • Contaminated work clothing should not be allowed out of the workplace.
  • Avoid release to the environment.
  • Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/
  • IF SWALLOWED:
  • IF exposed or concerned:
  • Call a POISON CENTER/doctor/ if you feel unwell.
  • Get medical advice/attention.
  • Get medical advice/attention if you feel unwell.
  • Rinse mouth.
  • If skin irritation or rash occurs:
  • Collect spillage.
  • Dispose of contents/container to

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open Nickel sulfamate in the GHS label constructor →

07 · Health hazards

Nickel sulfamate health hazards and exposure limits

Nickel sulfamate hazard summary

Harmful if swallowed; May cause skin sensitization; Chronic inhalation of nickel compounds in high concentrations is linked to lung cancer and nasal sinus cancer. [MSDSonline] See Nickel and linked occupational diseases.

Source: Haz-Map, Information on Hazardous Chemicals and Occupational Diseases

Nickel sulfamate occupational exposure limits

US occupational exposure limits reported for Nickel sulfamate. PEL is enforceable (OSHA), REL is a recommendation (NIOSH), IDLH is the concentration at which escape becomes impossible without injury.
Limit Value Source
PEL 1.0 [mg/m3], as Ni Haz-Map, Information on Hazardous Chemicals and Occupational Diseases
IDLH 10.0 [mg/m3], as Ni Haz-Map, Information on Hazardous Chemicals and Occupational Diseases

These are United States values. The European Union sets its own indicative and binding limits, and the figure that applies at a given workplace is the one in the local regulation — not the one shown here.

08 · Questions

Nickel sulfamate — frequently asked questions

What is the CAS number of Nickel sulfamate?

The CAS number of Nickel sulfamate is 13770-89-3. Its EC number is 237-396-1.

What is the chemical formula of Nickel sulfamate?

The molecular formula of Nickel sulfamate is H4N2NiO6S2 and its molecular weight is 250.87 g/mol.

What does a Nickel sulfamate label have to show?

Under CLP Annex VI the label for Nickel sulfamate carries the pictograms Exclamation mark, Health hazard and Environment and the signal word is Danger.

Is Nickel sulfamate flammable?

CLP Annex VI assigns Nickel sulfamate no flammability hazard class. That is not a statement that it cannot burn: the harmonised list only records the hazards that were assessed for it.

Is Nickel sulfamate a carcinogen?

Yes. CLP Annex VI classifies Nickel sulfamate as a category 1A or 1B carcinogen and assigns it H350i: may cause cancer by inhalation.

What is the exposure limit for Nickel sulfamate?

The US occupational exposure limit reported for Nickel sulfamate is 1.0 [mg/m3], as Ni (Haz-Map, Information on Hazardous Chemicals and Occupational Diseases). Limits differ by country: the EU sets its own indicative and binding values, and the figure that applies at a given workplace is the one in the local regulation.

Nearby

Substances next to Nickel sulfamate

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